journal article·2017-03

Room-temperature self-healing tough nanocomposite hydrogel crosslinked by zirconium hydroxide nanoparticles

Haoyang Jiang, Gongzheng Zhang, Xianqi Feng, Huanqing Liu, Feibo Li, Muqun Wang, Huanjun Li

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Abstract

Abstract Tough hydrogels with excellent self-healing properties at room temperature are of great importance for their potential applications in biomedical fields. Here, we demonstrate a design of novel zirconium hydroxide crosslinking nanocomposite hydrogel that combine high toughness (compressive strength of 36.6 MPa and tensile strength of 404.3 KPa) and self-healing efficiency (86%) at ambient condition. The Zr-NC gel was synthesized by the random copolymerization of 2-acrylamido-2-methyl propane sulfonic acid (AMPS) and acrylamide (AM) through a facile preparation. The designed hydrogen-bonding network can be tuned through changing the molar ratio and zirconium hydroxide. This novel Zr-NC gel will open an avenue for the healable artificial cartilage and tissue engineering.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Hydrogels: synthesis, properties, applications · Advanced Polymer Synthesis and Characterization · Advanced Sensor and Energy Harvesting Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (51)

Show source-provided references
1. Hydrogels for tissue engineering10.1021/cr000108x ↗
2. Highly stretchable and tough hydrogels10.1038/nature11409 ↗
3. A modular and supramolecular approach to bioactive scaffolds for tissue engineering10.1038/nmat1418 ↗
4. High-water-content moldable hydrogels by mixing clay and a dendritic molecular binder10.1038/nature08693 ↗
5. Hydrogels in biology and medicine: from molecular principles to bionanotechnology10.1002/adma.200501612 ↗
6. Nanocomposite hydrogels: a unique organic-inorganic network structure with extraordinary mechanical, optical, and swelling/de-swelling properties10.1002/1521-4095(20020816)14:16<1120::AID-ADMA1120>3.0.CO;2-9 ↗
7. Effects of clay content on the properties of nanocomposite hydrogels composed of poly(N-isopropylacrylamide) and clay10.1021/ma021301r ↗
8. Double-network hydrogels with extremely high mechanical strength10.1002/adma.200304907 ↗
9. The polyrotaxane gel:a topological gel by figure-of-eight cross-links10.1002/1521-4095(200104)13:7<485::AID-ADMA485>3.0.CO;2-T ↗
10. A novel hydrogel with high mechanical strength: a macromolecular microsphere composite hydrogel10.1002/adma.200602533 ↗
11. Interactions affecting the mechanical properties of macromolecular microsphere composite hydrogels10.1021/jp4069587 ↗
12. Dipole-dipole and H-Bonding interactions significantly enhance the multifaceted mechanical properties of thermoresponsive shape memory hydrogels10.1002/adfm.201401989 ↗
13. Physical hydrogels composed of polyampholytes demonstrate high toughness and viscoelasticity10.1038/nmat3713 ↗
14. Oppositely charged polyelectrolytes form tough, self-healing, and rebuildable hydrogels10.1002/adma.201500140 ↗
15. Stimuli-responsive nanocomposite gels10.1007/s00396-010-2373-9 ↗
16. Anisotropic hydrogel based on bilayers: color, strength, toughness, and fatigue resistance10.1039/c2sm25670c ↗
17. Novel nanocomposite hydrogels consisting of layered double hydroxide with ultrahigh tensibility and hierarchical porous structure at low inorganic content10.1002/adma.201400179 ↗
18. An anisotropic hydrogel with electrostatic repulsion between cofacially aligned nanosheets10.1038/nature14060 ↗
19. Spontaneous formation of characteristic layered morphologies in porous nanocomposites prepared from nanocomposite hydrogels10.1021/cm048093x ↗
20. Characteristic sliding frictional behavior on the surface of nanocomposite hydrogels consisting of organic-inorganic network structure10.1002/macp.200500105 ↗
21. Control of the coil-to-globule transition and ultrahigh mechanical properties of PNIPA in nanocomposite hydrogels10.1002/anie.200502004 ↗
22. Mechanical properties and structure of polymer-clay nanocomposite gels with high clay content10.1021/ma052468y ↗
23. Large strain and fracture properties of poly(dimethylacrylamide)/silica hybrid hydrogels10.1021/ma901937r ↗
24. Highly extensible, tough, and elastomeric nanocomposite hydrogels from poly(ethylene glycol) and hydroxyapatite nanoparticles10.1021/bm200027z ↗
25. Tough and highly stretchable graphene oxide/polyacrylamide nanocomposite hydrogels10.1039/c2jm32541a ↗
26. Nanocomposite hydrogels with high strength cross-linked by titania10.1039/c3ra41350k ↗
27. High strength nanocomposite hydrogel bilayer with bidirectional bending and shape switching behaviors for soft actuators10.1039/C4RA14545C ↗
28. Ionic self-assembly of ultrahard ZrO2/polymer nanocomposite thin films10.1002/(SICI)1521-4095(199810)10:14<1087::AID-ADMA1087>3.0.CO;2-O ↗
29. Surface mechanical properties of transparent poly(methyl methacrylate)/zirconia nanocomposites prepared by in situ bulk polymerization10.1016/j.polymer.2009.03.028 ↗
30. Self-healing glass fiber/epoxy composites with polypropylene tubes containing self-pressurized epoxy and mercaptan healing agents10.1016/j.compscitech.2016.09.020 ↗
31. Stabilization of catechol–boronic ester bonds for underwater self-healing and recycling of lipophilic bulk polymer in wider pH range10.1039/C6TA05121A ↗
32. Molecularly engineered dual-crosslinked hydrogel with ultrahigh mechanical strength, toughness, and good self-recovery10.1002/adma.201405022 ↗
33. Intrinsic self-healing of covalent polymers through bond reconnection towards strength restoration10.1039/c3py00005b ↗
34. Preparation of self-healing organic–inorganic nanocomposites with the reactions between methacrylated polyhedral oligomeric silsesquioxanes and furfurylamine10.1016/j.compscitech.2015.09.005 ↗
35. A facile and fast approach to mechanically stable and rapid self-healing waterproof fabrics10.1016/j.compscitech.2016.01.021 ↗
36. Fabrication of self-healing and hydrophilic coatings from liquid-like graphene@ SiO2 hybrids10.1016/j.compscitech.2016.10.012 ↗
37. Robust, self-healing, superhydrophobic coatings highlighted by a novel branched thiol-ene fluorinated siloxane nanocomposites10.1016/j.compscitech.2016.10.023 ↗
38. Self-healable, super tough graphene oxide-poly(acrylic acid) nanocomposite hydrogels facilitated by dual cross-linking effects through dynamic ionic interactions10.1039/C5TB00075K ↗
39. Self-healable, tough and highly stretchable ionic nanocomposite physical hydrogels10.1039/C5SM00493D ↗
40. A mechanically strong, highly stable, thermoplastic, and self-healable supramolecular polymer hydrogel10.1002/adma.201500534 ↗
41. Self-healing poly (acrylic acid) hydrogels with shape memory behavior of high mechanical strength10.1021/ma5015116 ↗
42. Self-healing in tough graphene oxide composite hydrogels10.1002/marc.201300242 ↗
43. Self-healing in nanocomposite hydrogels10.1002/marc.201100248 ↗
44. Fast self-healing of graphene oxide-hectorite clay-poly (N, N-dimethylacrylamide) hybrid hydrogels realized by near-infrared irradiation10.1021/am507100m ↗
45. Novel antifouling self-healing poly (carboxybetaine methacrylamide-co-HEMA) nanocomposite hydrogels with superior mechanical properties10.1039/c3tb20704h ↗
46. A self-healing polymeric material: from gel to plastic10.1039/c4ta02079k ↗
47. Self-healable, tough, and ultrastretchable nanocomposite hydrogels based on reversible polyacrylamide/montmorillonite adsorption10.1021/acsami.5b00704 ↗
48. One-pot synthesis of highly mechanical and recoverable double network hydrogels using thermoreversible sol-gel polysaccharide10.1002/adma.201300817 ↗
49. Preparation of in situ-forming poly (5-methyl-5-allyloxycarbonyl-1, 3-dioxan-2-one)-poly (ethylene glycol) hydrogels with tuneable swelling, mechanical strength and degradability10.1039/C2TB00148A ↗
50. A rapid and efficient self-healing thermo-reversible elastomer crosslinked with graphene oxide10.1002/adma.201302962 ↗
51. Zwitterionic fusion in hydrogels and spontaneous and time-independent self-healing under physiological conditions10.1016/j.biomaterials.2014.01.077 ↗