journal article·2019-10

Facile preparation and optical properties of Te/Pb-free Y3Al5O12:Ce3+ phosphor-in-glass via a screen-printing route for high-power WLEDs

Libin Xia, Yuanying Yue, Xueli Yang, Yuan Deng, Chengyue Li, Yijun Zhuang, Ruixiang Wang, Weixiong You, Tongxiang Liang

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Abstract

Abstract The applications in high-power fields of white light-emitting diodes (WLEDs) are restricted due to their poor thermal stability. Transparent Y3Al5O12:Ce3+ phosphor-in-glass (YAG-PiG) provides an efficient way to resolve this problem. In this work, novel transparent Te/Pb-free YAG-PiGs are successfully prepared via a facile screen-printing route. It is revealed that 5 mol% Eu2O3 optimizes the concentration in substrate glass. Slight erosion of YAG particles occurs in the as-prepared samples. With increasing YAG concentration and film thickness, the intensities of photoluminescence spectra of YAG-PiGs increase. The energy transfer from Eu3+ to Ce3+ is greatly suppressed. Superior thermal stability and high quantum efficiency are obtained. The optimal optical performance values in terms of a luminous efficiency of 117.2 lm/W, a correlated color temperature of 5859 K and a color rendering index of 77.2 are achieved in YAG-PiGs. All of the results reveal that the as-prepared YAG-PiGs are promising candidates for high-power WLEDs.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Glass properties and applications · Quantum Dots Synthesis And Properties

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References (30)

Show source-provided references
1. Excitation powder dependent optical temperature behavior of Er3+ doped transparent Sr0.69La0.31F2.31 glass ceramics10.1364/OE.24.017792 ↗
2. Synthesis and photoluminescence properties of novel highly thermal-stable red-emitting Na3Sc2(PO4)3:Eu3+ phosphors for UV-excited white-light-emitting diodes10.1016/j.jallcom.2017.12.316 ↗
3. EBSD and EDX analyses of a multiphase glass-ceramic obtained by crystallizing an yttrium aluminosilicate glass10.1021/am401953j ↗
4. Luminescence characteristics of YAG glass-ceramic phosphor for white LED10.1109/JSTQE.2008.920285 ↗
5. Preparation of Ce-doped (Y,Gd)3Al5O12 nanoceramics by sintering and crystallization of glass microspheres10.1016/j.materresbull.2015.02.021 ↗
6. Synthesis and luminescence properties of Ce:Y3Al5O12 glass ceramic by spontaneous crystallization10.1016/j.matlet.2015.03.023 ↗
7. Erosion mechanism of YAG:Ce3+ phosphor in bismuth borate glasses10.1016/j.ceramint.2017.09.109 ↗
8. A new-generation color converter for high-power white LED: transparent Ce3+:YAG phosphor-in-glass10.1002/lpor.201300140 ↗
9. Novel synthesis and optical characterization of phosphor-converted WLED employing Ce:YAG-doped glass10.1016/j.jallcom.2015.12.239 ↗
10. Erosion behavior and luminescence properties of Y3Al5O12:Ce3+-embedded calcium bismuth borate glass-ceramics for WLEDs10.1111/jace.16062 ↗
11. Facile preparation and ultrastable performance of single-component white-light-Emitting phosphor-in-Glass used for high-power warm white LEDs10.1021/acsami.5b09739 ↗
12. All-Inorganic Light Convertor Based on Phosphor-in-Glass Engineering for Next-Generation Modular High-Brightness White LEDs/LDs10.1021/acsphotonics.7b00049 ↗
13. Preparation and luminescent performances of transparent screen-printed Ce 3+:Y3Al5O12 phosphors-in-glass thick films for remote white LEDs10.1016/j.jallcom.2017.05.270 ↗
14. Stable and efficient all-inorganic color converter based on phosphor in tellurite glass for next-generation laser-excited white lighting10.1016/j.jeurceramsoc.2018.08.014 ↗
15. Transparent Ce3+:Y3Al5O12 glass ceramic for organic-resin-free white-light-emitting diodes10.1016/j.ceramint.2014.06.073 ↗
16. Stable and chromaticity-tunable phosphor-in-glass inorganic color converter for high-power warm white light-emitting diode10.1016/j.jeurceramsoc.2016.01.019 ↗
17. Preparation and luminescence properties of Eu3+ -doped calcium bismuth borate red-light-emitting glasses for WLEDs10.1016/j.jnoncrysol.2017.09.049 ↗
18. Preparation and luminescence properties of calcium bismuth borate red-light glass doped with high concentration Eu3+
19. Structural and optical characteristics of Eu3+ ions in sodium-lead-zinc-lithium-borate glass system10.1016/j.molstruc.2016.05.048 ↗
20. Enhanced luminescence behaviour of Eu3+ doped heavy metal oxide telluroborate glasses for Laser and LED applications10.1016/j.physb.2017.01.008 ↗
21. Structural and optical investigations of Eu3+ ions in lead containing alkali fluoroborate glasses10.1016/j.optmat.2012.01.027 ↗
22. Chromaticity-tunable phosphor-in-glass for long-lifetime high-power warm w-LEDs10.1039/C5TC01057H ↗
23. Structure analysis and optical properties of europium doped calcium bismuth borate glasses for WLED
24. Facile synthesis of a thermally stable Ce3+:Y3Al5O12 phosphor-in-glass for white LEDs10.1039/C5CE01365H ↗
25. A thermally stable warm WLED obtained by screen-printing a red phosphor layer on the LuAG:Ce3+ PiG substrate10.1016/j.cej.2016.08.008 ↗
26. Recent advances in solid-state LED phosphors with thermally stable luminescence10.1016/j.jre.2018.11.001 ↗
27. Facile preparation and luminescence performance of transparent YAG:Ce phosphor-in-tellurate-glass inorganic color converter for white-light-emitting diodes10.1016/j.jnoncrysol.2017.11.043 ↗
28. Facile fabrication and luminescence characteristics of Ce:YAG phosphor glass thick films coated on a glass substrate for white LEDs10.1016/j.ceramint.2016.06.065 ↗
29. Facile synthesis of YAG:Ce3+ thick films for phosphor converted white light emitting diodes10.1016/j.jeurceramsoc.2015.05.017 ↗
30. Advances in transparent glass–ceramic phosphors for white light-emitting diodes—a review10.1016/j.jeurceramsoc.2014.10.002 ↗