journal article·1984-04-01

Voltammetric and XPS Analysis of Metal‐Complexed Polytyramine Films : Geometry‐Dependent Electron Transfer Therein

Minh‐Chau Pham, Pierre‐Camille Lacaze, Jacques‐Emile Dubois

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Abstract

Electrodes coated with redox polymers are prepared by coordinating various metal ions with ligands from polytyramine films. The nature of the cation determines the geometry of the metal‐polymer complex and hence the voltammetric behavior of the coatings. Electron transfer between adjacent pairs of redox centers inside the film can occur with a four‐coordinate structure, but not with a penta‐ or hexacoordinate structure.
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Research context

OpenAlex topics: Conducting polymers and applications · Electrochemical Analysis and Applications · Analytical Chemistry and Sensors

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Affiliations

Institut de Topologie et de Dynamique des Systémes de l'Université Paris VII , associé au CNRS, 75005 Paris, France

References

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