journal article·1988-01-01Open access

Partial Molar Properties of MgCl2 in MgCl2 ‐ KCl ‐ CaCl2 Melts

J. Zhu, I. Karakaya, W. T. Thompson

Abstract

To further the understanding of electrolytes of value in industrial magnesium electrolysis, the reversible emf for the formation of in fused salts containing and was studied. The data made possible the calculation of thermodynamic solution properties which were used with other data to construct features of the ternary phase diagram. The multiple discrete complex anion (MDCA) model was tested against the thermodynamic findings from the present study. Reasonable agreement was obtained between the experimental properties and the values calculated from the model.
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Research context

OpenAlex topics: Thermal Expansion and Ionic Conductivity · Solid-state spectroscopy and crystallography · Inorganic Fluorides and Related Compounds

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Affiliations

Department of Chemistry, Central South University of Technology, Changsha, China

Queen's University, Department of Metallurgical Engineering, Kingston, Ontario, K7L 3N6 Canada

Royal Military College of Canada, Chemistry and Chemical Engineering, Kingston, Ontario, K7K 5L0 Canada

References

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