journal article·2018-05-01Open access

Emission properties of Zinc Gallate nanophosphors

Mun Keun LEE, Shinhoo KANG

Abstract

Nano-sized ZnGa2O4, ZnGa2O4:Cr and ZnGa2O4:Ti phosphors were synthesized by low-temperature combustion method and the luminescent properties were studied in comparison with those from conventional solid-state reaction. The combustion reaction resulted in a single-phase spinel structure and the particles were 5–10 nm in size. Of all samples, undoped nano ZnGa2O4 exhibited an intrinsic blue emission and Ti-doped nano ZnGa2O4 had a tendency of white emission whereas Cr-doped nano ZnGa2O4 showed red emissions. Titanium ions in spinel structure was found to exist as in Ti3+ and Ti4+, but favouring trivalent state. The oxidation state of Cr ions was confirmed as 3+ in nano ZnGa2O4.
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Research context

OpenAlex topics: Quantum Dots Synthesis And Properties · Nanocluster Synthesis and Applications · Chalcogenide Semiconductor Thin Films

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Affiliations

Department of Materials Science and Engineering, Seoul National University

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