DataVXJournal of the Ceramic Society of JapanPaper
journal article·2013Open access

pH localization: a case study during electrophoretic deposition of ternary MAX phase carbide-Ti3SiC2

Mrinalini MISHRA, Yoshio SAKKA, Tetsuo UCHIKOSHI, Laxmidhar BESRA

Journal of the Ceramic Society of Japan· Volume 121· Issue 1412
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Source abstract

Abstract

The pH localization phenomenon during electrophoretic deposition (EPD) of the MAX phase-Titanium silicon carbide (Ti3SiC2), from suspension in aqueous and mixed (water-ethanol) solvent was experimentally verified in presence of a cationic dispersant, polyethyleneimine (PEI). The local pHs at the electrodes were dependent on solid loadings of the suspensions; pH localization was pronounced at lower solid loading. Higher solid loading resulted in thicker deposits, shielding the electrode surface and hindering direct interaction of the electrode with the particles, thereby suppressing the change in local pH. Comparison of local pH at cathode during EPD from aqueous and mixed solvent revealed a delay in the attainment of isoelectric point (IEP) at the vicinity of electrode and slower deposition rate for mixed solvent. A necessity of concurrence between the IEP of the material and the local pH at the deposition electrode for a given system was established for the formation of good deposits.
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Research context

Energy storageMaterials processing

OpenAlex topics: Electrophoretic Deposition in Materials Science · Advanced Photocatalysis Techniques · MXene and MAX Phase Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Institute for Materials Science

University of Tsukuba

Institute of Minerals and Materials Technology

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