journal article·2012Open access

Hydrothermal synthesis and electrochemical properties of FeNbO4 nanospheres

Hyun-Woo SHIM, In-Sun CHO, Kug Sun HONG, Ah-Hyeon LIM, Dong-Wan KIM

Journal of the Ceramic Society of Japan· Volume 120· Issue 1398

Abstract

Iron niobate (FeNbO4) nanospheres of an orthorhombic structure were synthesized using a hydrothermal (HT) process at 250°C, and were characterized using X-ray diffraction, field-emission scanning electron microscopy, high-resolution transmission electron microscopy, and Brunauer–Emmett–Teller (BET) measurements. The FeNbO4 nanospheres obtained through the HT reaction revealed a uniform size with an average diameter of 5–10 nm, and a larger specific surface area (82.72 m2 g−1) than that of bulk FeNbO4 powder (2.51 m2 g−1) prepared by a solid-state reaction. In addition, the electrochemical properties of the FeNbO4 powders versus Li were evaluated using cyclic voltammetry and galvanostatic charge/discharge cycling. Importantly, the FeNbO4 nanospheres delivered a reversible capacity of over 200 mAh g−1 after 20 cycles, and provided an enhanced rate capability compared to the bulk material.
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Research context

OpenAlex topics: Advancements in Battery Materials · Ferroelectric and Piezoelectric Materials · Multiferroics and related materials

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Affiliations

Department of Materials Science & Engineering, Ajou University

Department of Materials Science & Engineering, College of Engineering, Seoul National University

References (15)

Show source-provided references
1. 1) A. S. Arico, P. Bruce, B. Scrosati, J. M. Tarascon and W. V. Schalkwijk, Nat. Mater., 4, 366–371 (2005).10.1038/nmat1368 ↗
2. 2) J. Maier, Nat. Mater., 4, 805–815 (2005).10.1038/nmat1513 ↗
3. 3) K. I. Gnanasekar, V. Jayaraman, E. Prabhu, T. Gnanasekaran and G. Periaswami, Sens. Actuators, B, 55, 170–174 (1999).10.1016/S0925-4005(99)00051-9 ↗
4. 4) D. H. Dawson and D. E. Williams, J. Mater. Chem., 6, 409–414 (1996).10.1039/jm9960600409 ↗
5. 5) H. Leiva, K. Sieber, B. Khazai, K. Dwight and A. Wold, J. Solid State Chem., 44, 113–118 (1982).10.1016/0022-4596(82)90407-8 ↗
6. 6) B. Khazai, R. Kershaw, K. Dwight and A. Wold, J. Solid State Chem., 39, 395–400 (1981).10.1016/0022-4596(81)90275-9 ↗
7. 7) H. Ehrenberg, G. Wltschek, R. Theissmann, H. Weitzel, H. Fuess and F. Trouw, J. Magn. Magn. Mater., 218, 261–265 (2000).10.1016/S0304-8853(00)00395-4 ↗
8. 8) E. Schmidbauer and J. Schneider, J. Solid State Chem., 134, 253–264 (1997).10.1006/jssc.1997.7551 ↗
9. 9) I. S. Cho, S. W. Lee, J. H. Noh, G. K. Choi, H. S. Jung, D. W. Kim and K. S. Hong, J. Phys. Chem. C, 112, 18393–18398 (2008).10.1021/jp807006g ↗
10. 10) J. T. Han, D. Q. Liu, S. H. Song, Y. S. Kim and J. B. Goodenough, Chem. Mater., 21, 4753–4755 (2009).10.1021/cm9024149 ↗
11. 11) M. F. Hassan, M. M. Rahman, Z. P. Guo, Z. X. Chen and H. K. Liu, Electrochim. Acta, 55, 5006–5013 (2010).10.1016/j.electacta.2010.04.006 ↗
12. 12) Y. D. Ko, J. G. Kang, J. G. Park, S. J. Lee and D. W. Kim, Nanotechnology, 20, 455701 (2009).10.1088/0957-4484/20/45/455701 ↗
13. 13) D. W. Kim, Y. D. Ko, J. G. Park and B. K. Kim, Angew. Chem., Int. Ed., 46, 6654–6657 (2007).10.1002/anie.200701628 ↗
14. 14) P. Poizot, S. Laruelle, S. Grugeon, L. Dupont and J. M. Tarascon, Nature, 407, 496–499 (2000).10.1038/35035045 ↗
15. 15) E. Schmidbauer and J. Schneider, J. Solid State Chem., 134, 253–264 (1997).10.1006/jssc.1997.7551 ↗