journal article·2009Open access

Structure and morphology of aminopropyltriethoxysilane-modified TiO2 nano-particles derived from sol-gel processing of tetraethylorthotitanate

Song CHEN, Akiyoshi OSAKA, Satoshi HAYAKAWA, Yuki SHIROSAKI, Eiji FUJII, Koji KAWABATA, Kanji TSURU

Journal of the Ceramic Society of Japan· Volume 117· Issue 1364

Abstract

Amino-modified TiO2 particles were derived from precursor mixtures of tetraethylorthotitanate and aminopropyltriethoxysilane (APTES) that both were dissolved in ethanol/water solution. Size, morphology, crystalline structures, and formation mechanism of the particles were discussed in terms of the APTES amount and the pH value in the solution. The addition of APTES resulted in amorphous amino-modified TiO2 particles. The low crystallinity in the final particles was attributed to the polar amino groups.
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Research context

OpenAlex topics: Silicone and Siloxane Chemistry · Polyoxometalates: Synthesis and Applications · TiO2 Photocatalysis and Solar Cells

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Graduate School of Natural Science and Technology, Okayama University

Industrial Technology Center of Okayama Prefecture

References (27)

Show source-provided references
1. 10.1016/j.jconrel.2003.11.01910.1016/j.jconrel.2003.11.019 ↗
2. 2) L. Wang, W. J. Zhao and W. H. Tan, Nano. Res., 1, 99-115 (2008).10.1007/s12274-008-8018-3 ↗
3. 3) D. M. Reffitt, N. Ogston, R. Jugdaohsingh, H. F. J. Cheung, B. A. J. Evans, R. P. H. Thompson, J. J. Powell and G. N. Hampson, Bone, 32, 127-135 (2003).10.1016/S8756-3282(02)00950-X ↗
4. 10.1002/1097-4636(200105)55:2<151::AID-JBM1001>3.0.CO;2-D10.1002/1097-4636(200105)55:2<151::AID-JBM1001>3.0.CO;2-D ↗
5. 5) T. Shozui, K. Tsuru, S. Hayakawa and A. Osaka, Key Eng. Mat., 361-363, 601-604 (2008).10.4028/www.scientific.net/KEM.361-363.601 ↗
6. 6) T. Asano, K. Tsuru, S. Hayakawa and A. Osaka, Acta Biomater., 4, 1067-1072 (2008).10.1016/j.actbio.2008.02.024 ↗
7. 7) S. Areva, H. Paldan, T. Peltola, T. Närhi, M. Jokinen and M. Lindén, J. Biomed. Mater. Res. A, 70, 169-178 (2004).10.1002/jbm.a.20120 ↗
8. 8) H. Paldan, S. Areva, T. Tirri, T. Peltola, T. C. Lindholm, L. Lassila, L. J. Pelliniemi, R.-P. Happonen and T. O. Närhi, J. Mater. Sci. Mater. Med., 19, 1283-1290 (2008).10.1007/s10856-007-3234-z ↗
9. 9) V. Aäritalo, S. Areva, M. Jokinen, M. Lindén and T. Peltola, J. Mater. Sci. Mater. Med., 18, 1863-1873 (2007).10.1007/s10856-007-3062-1 ↗
10. 10) S. Areva, V. Aäritalo, S. Tuusa, M. Jokinen, M. Lindén and T. Peltola, J. Mater. Sci. Mater. Med., 18, 1633-1642 (2007).10.1007/s10856-007-3064-z ↗
11. 11) V. Muhonen, S. Kujala, A. Vuotikka, V. Ääritalo, T. Peltola, S. Areva, T. Närhi and J. Tuukkanen, Acta Biomater., 5, 785-793 (2009).10.1016/j.actbio.2008.08.023 ↗
12. 10.1016/j.matlet.2006.02.01710.1016/j.matlet.2006.02.017 ↗
13. 1994 · 167 · 29
14. 10.1006/jcat.1994.134910.1006/jcat.1994.1349 ↗
15. 10.1007/BF0066037310.1007/BF00660373 ↗
16. 16) A. Leaustic, F. Babonneau and J. Livage, Chem. Mater., 1, 240-247 (1989).10.1021/cm00002a015 ↗
17. 10.1016/j.cattod.2003.10.01210.1016/j.cattod.2003.10.012 ↗
18. 10.1016/S0025-5408(03)00027-810.1016/S0025-5408(03)00027-8 ↗
19. OTTENBRITE R M · 2000 · 83 · 321410.1111/j.1151-2916.2000.tb01709.x ↗
20. 10.1246/cl.2008.117010.1246/cl.2008.1170 ↗
21. 21) T. Ikemoto, K. Uematsu, N. Mizutani and M. Kato, J. Ceram. Soc. Japan, 93, 261-266 (1985).10.2109/jcersj1950.93.1077_261 ↗
22. 22) T. Sugimoto and T. Kojima, J. Phys. Chem., 112, 18760-18771 (2008).10.1021/jp8029506 ↗
23. 10.1016/j.apcata.2008.05.03110.1016/j.apcata.2008.05.031 ↗
24. 10.1021/cm970314u10.1021/cm970314u ↗
25. 10.1006/jcat.1994.127710.1006/jcat.1994.1277 ↗
26. 10.1021/cr60234a00210.1021/cr60234a002 ↗
27. 27) J. Schmets et al., "Atlas of Electrochemical Equlibria in Aqueous Solutions," Ed. by M. Pourbaix, Pergamon Press, Oxford (1966) Section 8.1.