journal article·2017Open access

Formation and photoluminescence of zirconia dendrites in borosilicate glass-ceramics

Yasuhiro NOBUTA, Yoshihiro TAKAHASHI, Takamichi MIYAZAKI, Nobuaki TERAKADO, Noriko ONOUE, Tsuyoshi SHINOZAKI, Takumi FUJIWARA

Abstract

We prepared a borosilicate glass, in which the ZrO2 phase is singly crystallizable, i.e., 15Na2O–15ZrO2–30B2O3–40SiO2 glass, and investigated the texture and morphology of the resulting glass-ceramics. ZrO2 dendrites with a tetragonal system (high-temperature phase) were developed as initial phase, and the tetragonal phase was transformed to the monoclinic phase (low-temperature phase) by elongation of the heat-treatment time, and finally the needle-/rod-like crystals on a scale of few hundred nanometers were obtained. The glass-ceramics with monoclinic ZrO2 showed photoluminescence around 480 nm by excitation in the ultraviolet region. The effect of TiO2-addition on the photoluminescent property was also considered.
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Research context

OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Nuclear materials and radiation effects

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Applied Physics, Tohoku University

Department of Instrumental Analysis, Tohoku University

Department of Cardiovascular Medicine, National Hospital Organization, Sendai Medical Center

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