Novel Br− ion conducting solid electrolyte based on LaOBr
Source abstract
Abstract
Highly Br ion conducting solid electrolytes were developed by replacing La 3+ ion site in LaOBr with lower valent Sr 2+ and Ca 2+ ions to form Br ion vacancies for Br ion conduction with suppressing the sample decomposition. By doping two kinds of divalent cations simultaneously into LaOBr lattice, high amount of Br ion vacancy was successfully introduced compared to the previously reported La 0.9 Sr 0.1 OBr 0.9 . Among the samples prepared, the highest Br ion conductivity was obtained for the La 0.85 Sr 0.10 Ca 0.05 OBr 0.85 solid, which was ca. 5 times higher than that of La 0.9 Sr 0.1 OBr 0.9 .
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Ammonia Synthesis and Nitrogen Reduction · Inorganic Chemistry and Materials · Advanced Battery Materials and Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Applied Chemistry, Faculty of Engineering, Osaka University
References (19)
Show source-provided references
1. 1 R. D. Shannon, Acta Crystallogr. A, 32, 751–767 (1976).10.1107/S0567739476001551 ↗
2. 2 K. Eguchi, T. Setoguchi, T. Inoue and H. Arai, Solid State Ionics, 52, 165–172 (1992).10.1016/0167-2738(92)90102-U ↗
3. 3 T. Ishihara, H. Matsuda and Y. Takita, J. Am. Chem. Soc., 116, 3801–3803 (1994).10.1021/ja00088a016 ↗
4. 4 J. B. Goodenough, J. E. Ruiz-Biaz and Y. S. Zhen, Solid State Ionics, 44, 21–31 (1990).10.1016/0167-2738(90)90039-T ↗
5. 5 A. Sher, R. Solomon, K. Lee and M. W. Muller, Phys. Rev., 144, 593–604 (1966).10.1103/PhysRev.144.593 ↗
6. 6 A. Roos, A. F. Aalders, J. Schoonman, A. F. M. Arts and H. W. De Wijn, Solid State Ionics, 5, 633–635 (1981).10.1016/0167-2738(81)90334-9 ↗
7. 7 D. Leroy, J. Lucas, M. Poulain and D. Ravine, Mater. Res. Bull., 13, 1125–1133 (1978).10.1016/0025-5408(78)90199-X ↗
8. 8 C. E. Derrington and M. O’Keeffe, Solid State Commun., 15, 1175–1177 (1974).10.1016/0038-1098(74)90045-3 ↗
9. 9 N. Imanaka, K. Okamoto and G. Adachi, Angew. Chem. Int. Edit., 41, 3890–3892 (2002).10.1002/1521-3773(20021018)41:20<3890::AID-ANIE3890>3.0.CO;2-M ↗
10. 10 J. Mizusaki, K. Arai and K. Fueki, Solid State Ionics, 11, 203–211 (1983).10.1016/0167-2738(83)90025-5 ↗
11. 11 H. Aono and E. Sugimoto, Chem. Lett., 24, 79 (1995).10.1246/cl.1995.79 ↗
12. 12 L. M. Knowles, J. Am. Chem. Soc., 72, 4817–4818 (1950).10.1021/ja01166a513 ↗
13. 13 M. Zhang, Z. Zheng, Q. Fu, Z. Chen, J. He, S. Zhang, L. Yan, Y. Hu and W. Luo, CrystEngComm, 19, 6797–6801 (2017).10.1039/C7CE01709J ↗
14. 14 A. Seidell, “Solubilities of Inorganic and Organic compounds—2nd edition”, D. Van Nostrand Company, New York (1919) pp. 349–366.
15. 15 I. Y. Zaitseva, I. S. Kovaleva and V. A. Fedorov, Russ. J. Inorg. Chem., 52, 1968–1970 (2007).10.1134/S0036023607120248 ↗
16. 16 N. Imanaka and Y. Kato, Chem. Commun., 1270–1271 (2003).10.1039/b300691c ↗
17. 17 J. Hölsa, M. Leskelä and L. Niinistf, Thermochim. Acta, 35, 79–83 (1980).10.1016/0040-6031(80)85024-6 ↗
18. 18 Y. D. Eagleman, E. Bournet-Courchesne and S. E. Derenzo, J. Lumin., 131, 669–675 (2011).10.1016/j.jlumin.2010.11.013 ↗
19. 19 N. Imanaka, Y. Kobayashi, K. Fujiwara, T. Asano, Y. Okazaki and G. Adachi, Chem. Mater., 10, 2006–2012 (1998).10.1021/cm980157e ↗