Revolutionary carbon quantum dot supported-Co catalyst for record-breaking hydrogen production rate
Source abstract
Abstract
In this study, we introduce a groundbreaking approach in the field of hydrogen production by synthesizing and characterizing a carbon quantum dot supported-Co (Co-B_CQDs) catalyst. Our results demonstrate that this state-of-the-art catalyst exhibits exceptional performance in the hydrolysis of KBH4, resulting in a record-breaking hydrogen production rate of 23,019.97 mL*gcat(-1)*min(-1) and a remarkably low activation energy of 19.36 kJ/mol. This is the first time that this type of catalyst has been used to achieve such outstanding results. The study highlights the remarkable potential of carbon quantum dots as a support material for dispersing metal catalysts, which opens up new avenues for research in the field of hydrogen production. The synthesized catalyst was extensively characterized using various analytical techniques such as X-ray diffraction (XRD), ultraviolet and visible light (UV-Vis), photoluminescence (PL), and inductively coupled plasma optical emission spectrometry (ICP-OES) measurements, which further confirmed its superior performance.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Hydrogen Storage and Materials · Catalysis and Hydrodesulfurization Studies · Nanomaterials for catalytic reactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (39)
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1. Owusu, P.A., Asumadu-Sarkodie, S.: A review of renewable energy sources, sustainability issues and climate change mitigation. Cogent Eng. 3(1), 1167990 (2016)10.1080/23311916.2016.1167990 ↗
2. AL-bonsrulah, H.A., Veeman, D., Reddy, M.: Computational fluid dynamics study of a steam reformer unit performance to produce hydrogen fuel for PEM fuel cell applications. In Recent Advances in Renewable Energy Systems: Select Proceedings of ICOME 2021. Springer. 1–18 (2022)10.1007/978-981-19-1581-9_1 ↗
3. Lepage, T., Kammoun, M., Schmetz, Q., Richel, A.: Biomass-to-hydrogen: A review of main routes production, processes evaluation and techno-economical assessment. Biomass Bioenergy. 144, 105920 (2021)10.1016/j.biombioe.2020.105920 ↗
4. De Crisci, A.G., Moniri, A., Xu, Y.: Hydrogen from hydrogen sulfide: towards a more sustainable hydrogen economy. Int J Hydrogen Energy 44(3), 1299–1327 (2019)10.1016/j.ijhydene.2018.10.035 ↗
5. Kabeyi, M.J.B., Olanrewaju, O.A.: Biogas production and applications in the sustainable energy transition. J. Energy. 2022, 1–43 (2022)10.1155/2022/8750221 ↗
6. Mahant, B., Linga, P., Kumar, R.: Hydrogen economy and role of Hythane as a bridging solution: a perspective review. Energy Fuels 35(19), 15424–15454 (2021)10.1021/acs.energyfuels.1c02404 ↗
7. Ekinci, A., Horoz, S., Baytar, O., Şahin, Ö.: Hydrogen generation by hydrolysis of NaBH4 with efficient Co-La-WB catalyst For PEM fuel cells. J. Optoelectron. Biomed. Mater. 12(2), 25–32 (2020)10.15251/JOBM.2020.122.25 ↗
8. Olabi, A., et al.: Large-scale hydrogen production and storage technologies: current status and future directions. Int. J. Hydrogen Energy 46(45), 23498–23528 (2021)10.1016/j.ijhydene.2020.10.110 ↗
9. Karakaş, D.E., Mustafa, K., Sabit, H.: Efficient hydrogen generation from the NaBH4 methanolysis by waste material: Banana peel. Carbon Lett. 32(6), 1593–1601 (2022)10.1007/s42823-022-00391-1 ↗
10. Liu, M., et al.: Recent advances in noble metal catalysts for hydrogen production from ammonia borane. Catalysts 10(7), 788 (2020)10.3390/catal10070788 ↗
11. Keskin, M.S., Şahin, Ö., Horoz, S.: Efficiency of TiO2-supported Ni-Mo-Ru--B catalyst for hydrogen production from potassium borohydride hydrolysis. J. Aust. Ceram. Soc. 58(3), 973–979 (2022)10.1007/s41779-022-00755-w ↗
12. Zhou, H., et al.: Improved hydrogen storage properties of LiBH 4 confined with activated charcoal by ball milling. Rare Met 38, 321–326 (2019)10.1007/s12598-018-1067-1 ↗
13. Liuzhang, O., Kang, C., Jun, J., Xu-Sheng, Y., Min, Z.: Hydrogen storage in light-metal based systems: A review. J. Alloys Compd. 829, 154597 (2020)10.1016/j.jallcom.2020.154597 ↗
14. Grochala, W., Edwards, P.P.: Thermal decomposition of the non-interstitial hydrides for the storage and production of hydrogen. Chem. Rev. 104(3), 1283–1316 (2004)10.1021/cr030691s ↗
15. Charvin, P., et al.: Hydrogen production by three-step solar thermochemical cycles using hydroxides and metal oxide systems. Energy Fuels 21(5), 2919–2928 (2007)10.1021/ef0701485 ↗
16. Sellami, M.H., Loudiyi, K.: Electrolytes behavior during hydrogen production by solar energy. Renew Sustain Energy Rev 70, 1331–1335 (2017)10.1016/j.rser.2016.12.034 ↗
17. Wang, L., et al.: Pitaya pulp structural cobalt–carbon composite for efficient hydrogen generation from borohydride hydrolysis. J Alloy Compd 808, 151774 (2019)10.1016/j.jallcom.2019.151774 ↗
18. Xu, D., et al.: Catalytic behavior of carbon supported Ni–B, Co–B and Co–Ni–B in hydrogen generation by hydrolysis of KBH4. Fuel Process Technol 92(8), 1606–1610 (2011)10.1016/j.fuproc.2011.04.006 ↗
19. Onat, E., Çevik, S., Şahin, Ö., Horoz, S., İzgi, M.S.: Investigation of high catalytic activity catalyst for high hydrogen production rate: Co-Ru@ MOF. J. Austr. Ceram. Soc. 57, 1389–1395 (2021)10.1007/s41779-021-00643-9 ↗
20. Özhan, A., et al.: Preparation and characterization of activated carbon from pine cone by microwave-induced ZnCl 2 activation and its effects on the adsorption of methylene blue. Cellulose 21, 2457–2467 (2014)10.1007/s10570-014-0299-y ↗
21. Saka, C., Balbay, A.: Fast and effective hydrogen production from ethanolysis and hydrolysis reactions of potassium borohydride using phosphoric acid. Int J Hydrogen Energy 43(43), 19976–19983 (2018)10.1016/j.ijhydene.2018.09.048 ↗
22. Onat, E., Şahin, Ö., İzgi, M.S., Horoz, S.: An efficient synergistic Co@ CQDs catalyst for hydrogen production from the hydrolysis of NH 3 BH 3. J. Mater. Sci. Mater. Electron. 32, 27251–27259 (2021)10.1007/s10854-021-07094-9 ↗
23. Chen, B., et al.: Large scale synthesis of photoluminescent carbon nanodots and their application for bioimaging. Nanoscale 5(5), 1967–1971 (2013)10.1039/c2nr32675b ↗
24. Zanchetta, C., Patton, B., Guella, G., Miotello, A.: An integrated apparatus for production and measurement of molecular hydrogen. Meas. Sci. Technol. 18(5), N21 (2007)10.1088/0957-0233/18/5/N02 ↗
25. Pandiyan, S., et al.: Biocompatible carbon quantum dots derived from sugarcane industrial wastes for effective nonlinear optical behavior and antimicrobial activity applications. ACS Omega 5(47), 30363–30372 (2020)10.1021/acsomega.0c03290 ↗
26. Amoozadeh, P., et al.: UV-curable hybrid hydrogels of carbon quantum dots: synthesis, characterizations and investigation of properties and rheological behavior. Polym-Plast Technol Mater 61(18), 2063–2072 (2022)
27. Colusso, E., Cicerchia, L., Rigon, M., Gomes, V., Martucci, A.: Photoluminescence properties of silk--carbon quantum dots composites. J. Sol-Gel Sci. Technol. 107(1), 170–177 (2023)10.1007/s10971-022-05742-y ↗
28. Novaes, C.G., et al.: A review of multivariate designs applied to the optimization of methods based on inductively coupled plasma optical emission spectrometry (ICP OES). Microchem J 128, 331–346 (2016)10.1016/j.microc.2016.05.015 ↗
29. Burkhardt, E.R., Matos, K.: Boron reagents in process chemistry: excellent tools for selective reductions. Chem Rev 106(7), 2617–2650 (2006)10.1021/cr0406918 ↗
30. Balbay, A., Saka, C.: Semi-methanolysis reaction of potassium borohydride with phosphoric acid for effective hydrogen production. Int J Hydrogen Energy 43(46), 21299–21306 (2018)10.1016/j.ijhydene.2018.09.167 ↗
31. Tiri, R.N.E., et al.: Biosynthesis of Ag–Pt bimetallic nanoparticles using propolis extract: antibacterial effects and catalytic activity on NaBH4 hydrolysis. Environ Res 206, 112622 (2022)10.1016/j.envres.2021.112622 ↗
32. Zhang, Y., et al.: Study on preparation and performance of Ru-Fe/GO catalyst for sodium borohydride alcoholysis to produce hydrogen. Fullerenes Nanotubes Carbon Nanostruct 28(10), 786–793 (2020)10.1080/1536383X.2020.1760849 ↗
33. Karakaş, D.E., Mustafa, K., Horoz, S.: Catalytic activites of a biomaterial (sumac) catalyst in sodium borohyride methanolysis reactions. J Mol Struct 1273, 134276 (2023)10.1016/j.molstruc.2022.134276 ↗
34. Keskin, M.S., et al.: Potasyum Borhidrit Hidroliz Reaksiyonu Için Ni-Bp Katalizörünün Kinetik Özellikleri. Bitlis Eren Üniv Fen Bilimleri Derg 9(2), 599–608 (2020)10.17798/bitlisfen.623941 ↗
35. Ozdemir, O.K.: Analysis of kinetic properties for the hydrolysis reaction of NaBH4 and environmental effects in the hydrogen production of activated Co-Ti (II)-B alloy catalysts. J. Fac. Eng. Archit. Gazi Univ. 34(3), (2019)
36. Ekinci, A., Şahin, Ö., Horoz, S.: Kinetics of catalytic hydrolysis of NaBH 4 solution: Ni-La-B catalyst. J. Aust. Ceram. Soc. 1–9 (2021)10.1007/s41779-021-00673-3 ↗
37. İzgi, M.S., et al.: CeO2 supported multimetallic nano materials as an efficient catalyst for hydrogen generation from the hydrolysis of NaBH4. Int. J. Hydrogen Energy 45(60), 34857–34866 (2020)10.1016/j.ijhydene.2020.04.034 ↗
38. Çakanyildirim, Ç., Gökçeoğlu, G.: NaBH4 hidrolizi için Al2O3 destekli çok bileşenli nanokatalizör sentezi ve kinetik değerlendirmesi. Politeknik Derg.1–1. (n.d.)
39. Abdurrahman Karabulut, M., İzgi, S., Demir, H., Şahin, Ö., Horoz, S.: Optimizing hydrogen production from alkali hydrides using supported metal catalysts. Ionics. 29(5), 1975–1982 (2023)10.1007/s11581-023-04962-8 ↗