In Situ Processing of Nano Crystalline Oxide Particles/Polymer Hybrid
Source abstract
Abstract
Nano sized crystalline particles/polymer hybrids were synthesized form designed metal-organic precursors. The newly developed method is composed of the synthesis of organic matrix by polymerization and the in situ nucleation and growth of crystalline oxide particles in the organic matrix below 100°C. The design of metal-organic precursor modified with polymerizable ligand and the selection of reaction conditions does influence the size and crystallinity of ceramic particles in organic matrix. The nano-sized magnetic particle/polymer hybrid exhibits the interesting feature of superparamagnetism and quantum size effect. The crystalline particles of BaTiO3/, PbTiO3/, and KNbO3/polymer hybrids behave to be dielectric and show the typical electro-rheological behavior.
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Research context
OpenAlex topics: Multiferroics and related materials · Ferroelectric and Piezoelectric Materials · Polymer Nanocomposites and Properties
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References (21)
Show source-provided references
1. B.K. Coltrain, C. Sanchez, D.W. Schaefer, and G.L. Wilkes, (eds.), Better Ceramics Through Chemistry, VII, Inorganic/Organic Hybrid Materials, Mater. Res. Soc. Symp. Proc., 435 (Mater. Res. Soc., Pittsburgh, 1996).
2. H. Schmidt, in Better Ceramics Through Chemistry, edited by C.J. Brinker, D.E. Clark, and D.R. Ulrich, Mater. Res. Soc. Symp. Proc., 32 (Elsevier, New York, 1984), p. 927.
3. H. Schmidt, J. Non-Cryst. Solid 73, 681 (1985).10.1016/0022-3093(85)90388-6 ↗
4. G.L. Wilkes, B. Orler, and H.-H. Huang, Polym. Prep. 26, 300 (1985).
5. H. Schmidt, in Chemical Processing of Advanced Materials, edited by L.L. Hench and J.K. West (John Wiley & Sons, New York, 1992), p. 727.
6. C. Sanchez and M. Inn, J. Non-Cryst. Solids 147/148, 1 (1992).10.1016/S0022-3093(05)80584-8 ↗
7. S.W. Charles and J. Popplewell, Ferromagnetic Materials, Vol. 2, edited by E.P. Wohlfarth (North-Holland, Amsterdam, 1980), p. 509.
8. L. Zhang, G.C. Papaefthymiou, and J.Y. Ying, J. Appl. Phys. 81, 6892 (1997).10.1063/1.365233 ↗
9. T. Yogo, T. Nakamura, K. Kikuta, W. Sakamoto, and S. Hirano, J. Mater. Res. 11, 475 (1996).10.1557/JMR.1996.0057 ↗
10. T. Yogo, T. Nakamura, W. Sakamoto, and S. Hirano, J. Mater. Res. 14, 2855 (1999).10.1557/JMR.1999.0381 ↗
11. T. Yogo, T. Nakamura, W. Sakamoto, and S. Hirano, J. Mater. Res. 15, 2114 (2000).10.1557/JMR.2000.0304 ↗
12. T. Yogo, K. Kikuta, S. Yamada, and S. Hirano, J. Sol-Gel Sci. Tech. 2, 175 (1994).10.1007/BF00486236 ↗
13. S. Hirano, T. Yogo, K. Kikuta, and S. Yamada, Ceram. Trans. 68, 131 (1996).
14. T. Yogo, H. Ukai, W. Sakamoto, and S. Hirano, J. Mater. Res. 14, 3275 (1999).10.1557/JMR.1999.0443 ↗
15. H.A. Tayim and M. Sabri, Inorg. Nucl. Chem. Lett. 9, 753 (1973).10.1016/0020-1650(73)80232-6 ↗
16. A.E. Berkowitz, W.J. Schulle, and P.J. Flanders, J. Appl. Phys. 39, 1261 (1968).10.1063/1.1656256 ↗
17. D.J. Dunlop, J. Geophys. Res. 78, 1780 (1973).10.1029/JB078i011p01780 ↗
18. A.H. Morrish, The Physical Principles of Magnetism (John Wiley & Sons, New York, 1965), p. 360.
19. P. Mulet, Solid State Comm. 14, 1119 (1974).10.1016/0038-1098(74)90286-5 ↗
20. T. Furukawa, K. Fujino, and E. Fukuda, Jpn. J. Appl. Phys. 15, 2119 (1976).10.1143/JJAP.15.2119 ↗
21. T. Yamada, T. Ueda, and T. Kitayama, J. Appl. Phys. 53, 4328 (1982).10.1063/1.331211 ↗