The influence of polyvinylpyrrolidone on thick and optical properties of BaTiO3:Er3+ thin films prepared by sol–gel method
Source abstract
Abstract
Erbium (Er3+) 0.5% mol doped barium titanate (BaTiO3) thin films were elaborated via sol–gel method and dip-coating technique using titanium alkoxide and barium pentanedionate. Two syntheses were performed [with and without polyvinylpyrrolidone (PVP)] in order to obtain thick films. The BaTiO3:Er3+ thin films prepared from the sol with PVP were elaborated with 1 layer and those without PVP and were elaborated with 17 layers. In both cases, the films were deposited on silica quartz substrates. Both BaTiO3:Er3+ films presented a cubic phase, as determined by X-ray diffraction. BaTiO3:Er3+ films elaborated with PVP via single-step dip coating produced crack-free films with thicknesses of ~800 nm. SEM micrographs for the obtained BaTiO3:Er3+ films revealed high homogeneity and density. Mapping images obtained from BaTiO3:Er3+ revealed homogeneous distribution of Er3+ ions on the surface. XPS analyses of the chemical state and chemical environment of the constituent elements in the compositions showed that Er3+ ions in (Ba1−x Er x )TiO3 are in mixed valence of Er3+/Er2+. The BaTiO3:Er3+-PVP film exhibited luminescent properties under near-infrared excitation, as revealed by green emissions. The BaTiO3:Er3+-PVP film has good potential for optical applications.
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Research context
OpenAlex topics: Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis · Photorefractive and Nonlinear Optics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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