Epoxy Resin/Ionic Liquid Composite as a New Promising Coating Material with Improved Toughness and Antibiofilm Activity
Source abstract
Abstract
Long-chain imidazolium-based ionic liquids (ILs) possess a broad-spectrum biological activity and are considered promising antifouling agents for protective coatings. A new hydrophobic IL, 1-dodecyl-3-methylimidazolium dodecylbenzenesulfonate (C12C1IM-DBS), has been synthesized, and a modified epoxy coating material containing 10, 20, and 30 wt% of this IL was prepared by dissolution of C12C1IM-DBS in commercial DER 331 epoxy resin, followed by a curing phase with diethylenetriamine. Infrared analysis revealed physicochemical interactions between the hydroxyl groups of the resin and the IL. Spectrophotometric studies showed no release of C12C1IM-DBS after 30 days of exposure of the modified coatings to water. The plasticizing effect of the IL on the epoxy resin was established by differential scanning calorimetry analysis. The introduction of 10 and 20% C12C1IM-DBS into DER 331 reduced its glass transition temperature from 122.8 °C to 109.3 and 91.5 °C, respectively. The hardness of epoxy resin decreased by approximately 26% after the introduction of the IL. Moreover, DER 331/C12C1IM-DBS coatings on steel substrates showed significantly improved impact resistance compared to neat resin. The antibiofilm efficiency of DER 331/C12C1IM-DBS coatings was evaluated by assessing the capability of two biofilm-forming model strains, Staphylococcus aureus ATCC 25923 and Pseudomonas aeruginosa PA01, to form attached biofilms on the surface. The IL effectively inhibited S. aureus surface-associated biofilm development even at the lowest content of 10%. On the contrary, an approximately 50% inhibition of biofilm metabolic activity was detected for DER 331/C12C1IM-DBS coatings containing 20% and 30% of the IL. Overall, the results of this study indicate that the hydrophobic IL C12C1IM-DBS is an efficient modifying additive for epoxy resins, which can significantly improve their operational properties for various industrial applications.
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Research context
OpenAlex topics: Ionic liquids properties and applications · Antimicrobial agents and applications · Nanocomposite Films for Food Packaging
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Laboratory of Modification of Polymers, V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, 02160 Kyiv, Ukraine
Department of Cell Regulatory Mechanisms, Institute of Molecular Biology and Genetics, National Academy of Sciences of Ukraine, 03143 Kyiv, Ukraine
Department of Surface and Plasma Science, Faculty of Mathematics and Physics, Charles University, 18000 Prague, Czech Republic
Department of Polymers, Faculty of Chemical Tecnology, University of Chemistry and Technology (UCT) Prague, 16628 Prague, Czech Republic
Department of Synthesis and Sintering of Superhard Materials, V. Bakul Institute for Superhard Materials, National Academy of Sciences of Ukraine, 04074 Kyiv, Ukraine
AMACORT, Nautical Faculty, Antwerp Maritime Academy, Noordkasteel Oost 6, 2030 Antwerp, Belgium
Department of Bioscience Engineering, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp, Belgium
Funding
Simons Support
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