From Molecular Design to Scenario Adaptation: Cutting-Edge Exploration of Silicone-Modified Polyurethane in Smart Sports Fields
Source abstract
Abstract
To overcome the shortcomings of traditional polyurethane, such as poor weather resistance and susceptibility to hydrolysis, this study systematically explores the preparation techniques of organic silicon-modified polyurethane and its application in intelligent sports fields. By introducing siloxane into the polyurethane matrix through copolymerization, physical blending, and grafting techniques, the microphase separation structure and interfacial properties of the material are effectively optimized. In terms of synthesis processes, the one-step method achieves efficient preparation by controlling the isocyanate/hydroxyl molar ratio (1.05–1.15), while the prepolymer chain extension method optimizes the crosslinked network through dual reactions. The modified material exhibits significant performance improvements: tensile strength reaches 60 MPa, tear resistance reaches 80 kN/m, and the elastic recovery rate ranges from 85% to 92%, demonstrating outstanding weather resistance. In sports field applications, the 48% impact absorption rate meets the requirements for athletic tracks, wear resistance of <15 mg suits gym floors, and the impact resistance for skate parks reaches 55%–65%. Its environmental benefits are notable, with volatile organic compounds (VOC) <50 g/L and a recycling rate >85%, complying with green building material standards. However, its development is still constrained by multiple factors: insufficient material interface compatibility, a comprehensive cost of 435 RMB/m2, and the lack of a quality evaluation system. Future research priorities include constructing dynamic covalent crosslinked networks (e.g., self-healing systems), adopting bio-based raw materials to reduce carbon footprint by 30%–50%, and integrating flexible sensing technologies for intelligent responsiveness. Through multidimensional innovation, this material is expected to evolve toward multifunctionality and environmental friendliness, providing core material support for the intelligent upgrading of sports fields.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Environmental Engineering and Cultural Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
College of Physical Education, Sichuan Agricultural University, Ya’an 625014, China
Ya’an Key Laboratory of Sports Human Science and National Physical Fitness Promotion, College of Physical Education, Sichuan Agricultural University, Ya’an 625014, China
College of Science, Sichuan Agricultural University, Ya’an 625014, China
References (100+)
Show source-provided references
1. Reducing the Thrombogenicity of Ion-Selective Electrode Membranes through the Use of a Silicone-Modified Segmented Polyurethane10.1021/ac010375i ↗
2. Preparation of hydroxy-terminated polydimethylsiloxane and nano-SiO2 hydrophobic polyurethane coated urea and investigation of controlled nitrogen release10.1016/j.ces.2024.120728 ↗
3. Partial crystalline organosilicon-based polysiloxane-polyurethane copolymers10.1016/j.eurpolymj.2023.112416 ↗
4. Polyurethane (PU) based multifunctional materials: Emerging paradigm for functional textiles, smart, and biomedical applications10.1002/app.52832 ↗
5. Synthesis and characterization of novel organosilicon-modified polyurethane10.1002/app.36245 ↗
6. A review on carbon nanofiller-based hyperbranched polyurethane nanocomposites: Synthesis strategies, applications and challenges10.1007/s10853-024-10158-w ↗
7. Complexation of titanium alkoxides with pentenoic acid and allylacetoacetate and their hydrolysis and addition reactions with H-silanes10.1002/app.21315 ↗
8. Polystyrene/thermoplastic polyurethane interpenetrating network-based nanocomposite with high-speed, thermo-responsive shape memory behavior10.1016/j.polymer.2020.122575 ↗
9. Novel photo-thermal staged-responsive supramolecular shape memory polyurethane complex10.1016/j.polymer.2019.121671 ↗
10. UV-triggered self-healing polyurethane with enhanced stretchability and elasticity10.1016/j.polymer.2019.03.045 ↗
11. Yin, C., Okamoto, R., Kondo, M., Tanaka, T., Hattori, H., Tanaka, M., Sato, H., Iino, S., and Koshiro, Y. (2018). Electrospinning of Block and Graft Type Silicone Modified Polyurethane Nanofibers. Nanomaterials, 9.10.3390/nano9010034 ↗
12. New zwitterionic polyurethanes containing pendant carboxyl-pyridinium with shape memory, shape reconfiguration, and self-healing properties10.1016/j.polymer.2019.121727 ↗
13. Chemically-crosslinked zwitterionic polyurethanes with excellent thermally-induced multi-shape memory effect and moisture-induced shape memory effect10.1016/j.polymer.2018.06.037 ↗
14. Waterborne polyurethane modified with silicone macromer and the nylon airbag coated with it10.1177/0040517515619352 ↗
15. Effects of fluorosilane addition on polyurethane electrospun membranes with waterproof and breathable performance10.1177/00405175241237827 ↗
16. Multi-color photochromic waterborne polyurethane with high color fastness from hydroxyl-functionalized trichromatic spiropyrans10.1016/j.dyepig.2024.112577 ↗
17. Preparation of photochromic microcapsules with a diarylethene and polyurethane/chitosan for smart textiles10.1016/j.dyepig.2024.112546 ↗
18. Investigation of the migration ability of silicone and properties of waterborne polyurethanes10.1016/j.ijadhadh.2020.102654 ↗
19. Recycled tires shreds based polyurethane binder: Production and characterization10.1016/j.mechmat.2020.103351 ↗
20. Preparation of waterborne polyurethane with high solid content: The crystallinity control of soft segment and the organosilicon modification10.1007/s00289-023-04718-4 ↗
21. Yin, C., Rozet, S., Okamoto, R., Kondo, M., Tamada, Y., Tanaka, T., Hattori, H., Tanaka, M., Sato, H., and Iino, S. (2019). Physical Properties and In Vitro Biocompatible Evaluation of Silicone-Modified Polyurethane Nanofibers and Films. Nanomaterials, 9.10.3390/nano9030367 ↗
22. A novel method for fabricating elastic conductive polyurethane filaments by in-situ reduction of polydopamine and electroless silver plating10.1016/j.matdes.2016.10.027 ↗
23. A human muscle-inspired, high strength, good elastic recoverability, room-temperature self-healing, and recyclable polyurethane elastomer based on dynamic bonds10.1016/j.compscitech.2024.110457 ↗
24. Vat photopolymerization printing of strong tear-resistance and stretchable polyurethane elastomer for highly sensitive strain sensors10.1002/pc.27943 ↗
25. Composite coatings based on silicone-modified polyurethane and marine natural product chlorogentisyl alcohol for marine antifouling10.1016/j.porgcoat.2024.108906 ↗
26. Cashew nut shell liquid terminated self-healable polyurethane as an effective anticorrosive coating with biodegradable attribute10.1016/j.porgcoat.2019.105472 ↗
27. Preparation of a wear-resistant, superhydrophobic SiO2/silicone-modified polyurethane composite coating through a two-step spraying method10.1016/j.porgcoat.2020.105710 ↗
28. Composites prepared from polyurethanes modified with silicone-acrylic nanopowders10.1016/j.porgcoat.2014.12.016 ↗
29. Schiff base modified polyurethane coating with enhanced mechanical property for marine antifouling application10.1016/j.porgcoat.2025.109138 ↗
30. Synthesis and application of silicone-modified polyurethane as a slip-elastic finishing agent for polyamide fabrics10.1016/j.porgcoat.2024.108420 ↗
31. Organosilicon-modified double crosslinked waterborne polyurethane coatings10.1016/j.porgcoat.2024.108372 ↗
32. Strong Thermo-tolerant Silicone-Modified Waterborne Polyurethane/Polyimide Pressure-Sensitive Adhesive10.1021/acs.langmuir.3c01564 ↗
33. Preparation and properties of organosilicon and castor-oil-modified rosin-based waterborne polyurethane coatings10.1016/j.indcrop.2024.118230 ↗
34. The Triboelectric Nanogenerator as an Innovative Technology toward Intelligent Sports10.1002/adma.202004178 ↗
35. Effect of polycaprolactone percentage on thermal and mechanical behavior of polyurethane/polycaprolactone/graphene oxide nanocomposite utilizing molecular dynamics simulation10.1016/j.enganabound.2024.01.014 ↗
36. A flexible, high-strength, conductive shape memory composite fabric based on continuous carbon fiber/polyurethane yarn10.1088/1361-665X/ab9f4a ↗
37. High Tensile Strength UV-Cured Castor Oil-Based Silicone-Modified Polyurethane Acrylates10.1021/acsomega.1c06959 ↗
38. Antibacterial and Alkali-responsive Cationic Waterborne Polyurethane Based on Modification of Aloe Emodin10.1007/s40242-022-2179-6 ↗
39. Castor oil-segmented polyurethanes with disulfide bonds: Excellent self-healing and mechanical properties10.1007/s10965-025-04341-z ↗
40. Characteristics of organosilicon urethane composite materials and coatings10.1007/s11003-008-9028-8 ↗
41. Preparation and properties of a polyurethane film based on novel photochromic spirooxazine chain extension10.1039/D2NJ00162D ↗
42. Flexible strain sensor based on CNT/TPU composite nanofiber yarn for smart sports bandage10.1016/j.compositesb.2021.109605 ↗
43. Liu, C., Zhu, F., Yang, D., Bai, C., Wang, X., Li, G., and Luo, Y. (2024). Research on the Thermal Aging Performance of a GAP-Based Polyurethane Elastomer. Polymers, 16.10.3390/polym16060795 ↗
44. Effects of accelerated environmental aging on glass fiber reinforced thermoset polyurethane composites10.1016/j.compositesb.2016.03.059 ↗
45. Nicoleta, I. (2023). Accelerated versus Slow In Vitro Aging Methods and Their Impact on Universal Chromatic, Urethane-Based Composites. Materials, 16.10.3390/ma16062143 ↗
46. Trzaskowska, P.M., Robakowska, M., Gierz, L., Pach, J., and Mazur, E. (2024). Observation of the Effect of Aging on the Structural Changes of Polyurethane/Polyurea Coatings. Polymers, 16.10.3390/polym16010023 ↗
47. Thermal Degradation Behavior and Mechanism of Organosilicon Modified Epoxy Resin10.1002/macp.202200164 ↗
48. Photorheologic Silicone Composites with Adaptive Properties by Utilizing Light-Degradable Organosilica Nanoparticles as Fillers10.1002/admi.202400574 ↗
49. Degradation behaviors of silicone gel encapsulation material with moisture intrusion10.1016/j.polymdegradstab.2022.110197 ↗
50. Analysis of oxidative degradation and calcification behavior of a silicone polycarbonate polyurethane-polydimethylsiloxane material10.1002/jbm.a.37357 ↗
51. Self-reinforced thermoplastic polyurethane composite with excellent mechanical properties, heat resistance and sustainable recycling10.1016/j.compositesb.2025.112342 ↗
52. Eco-friendly and recyclable thermosetting polyurethane composites for human motion monitoring10.1007/s10854-024-14189-6 ↗
53. Silicone-recycled pyrolyzed fillers for enhanced thermal–and flame—Resistant silicone elastomers10.1016/j.polymdegradstab.2022.109947 ↗
54. Guo, S.Y., Wang, H.B., Liu, Y., Fu, Y., Zhang, X.F., Qin, B., and Liu, T. (2023). Preparation and Closed-Loop Recycling of Ultra-High-Filled Wood Flour/Dynamic Polyurethane Composites. Polymers, 15.10.3390/polym15061418 ↗
55. Shape memory polyurethane nanocomposites with porous architectures for enhanced microwave shielding10.1016/j.cej.2018.07.048 ↗
56. High solid and low viscosity waterborne polyurethane acrylate with excellent anti-corrosion and anti-bacterial performances10.1016/j.porgcoat.2023.107767 ↗
57. Sun, M.T., Huang, S., Yu, M.H., and Hang, K.Q. (2021). Toughening Modification of Polylactic Acid by Thermoplastic Silicone Polyurethane Elastomer. Polymers, 13.10.3390/polym13121953 ↗
58. A multi-stimulus responsive nanogel actuator with the π-π stacking interaction self-assembly and application for bioinspired smart skin with light, heat and humidity responses and superb UV resistance10.1016/j.cej.2024.156092 ↗
59. Xu, S., Dong, X., Zhao, Y., Han, J., Ji, Y., Kuang, R., Zhang, S., and Ma, S. (2024). Preparation of Environmentally Friendly Anticorrosive Coatings with Aniline Trimer-Modified Waterborne Polyurethane. Coatings, 14.10.3390/coatings14111380 ↗
60. Yang, P., Xiang, S., Li, R., Ruan, H., Chen, D., Zhou, Z., Huang, X., and Liu, Z. (2022). Highly Stretchable and Sensitive Flexible Strain Sensor Based on Fe NWs/Graphene/PEDOT:PSS with a Porous Structure. Int. J. Mol. Sci., 23.10.3390/ijms23168895 ↗
61. Synthesis and characterization of organosilicon-modified self-matting waterborne polyurethane with excellent wear resistance10.1007/s11998-023-00790-7 ↗
62. Mendes, J.J., Vieira, M., Pires, M., and Stevan, S. (2016). Sensor Fusion and Smart Sensor in Sports and Biomedical Applications. Sensors, 16.10.3390/s16101569 ↗
63. Pinelli, S., Mandorino, M., Lacome, M., and Fantozzi, S. (2024). Evaluation of WIMU Sensor Performance in Estimating Running Stride and Vertical Stiffness in Football Training Sessions: A Comparison with Smart Insoles. Sensors, 24.10.3390/s24248087 ↗
64. Poirot, A., Bedrici, N., Walrick, J.C., and Arrigoni, M. (2023). Piezoresistive Behavior of a Conductive Polyurethane Based-Foam for Real-Time Structural Monitoring. Sensors, 23.10.20944/preprints202305.0076.v1 ↗
65. Zhao, J., Yang, Y., Bo, L., Qi, J., and Zhu, Y. (2024). Research Progress on Applying Intelligent Sensors in Sports Science. Sensors, 24.10.3390/s24227338 ↗
66. Recent Progress on 2D-Material-Based Smart Textiles: Materials, Methods, and Multifunctionality10.1002/adem.202500188 ↗
67. Smart Shape Memory Polyurethane with Photochromism and Mechanochromism Properties10.1002/mame.202100778 ↗
68. Electrically Triggered Actuation of Plasticized Thermoplastic Polyurethane Gels10.1002/mame.201600050 ↗
69. UV-Curable Polyurethane Elastomer with UV-Irradiation/Thermo Dual-Activated Self-Healability10.1002/mame.202100874 ↗
70. Electrical-Triggered Multicolor Reversible Color-Changing Ag Nanoparticles/Reduced Graphene Oxide/Polyurethane Conductive Fibers10.1002/mame.202200438 ↗
71. Preparation and surface properties of silicone-modified polyester-based polyurethane coats10.1007/s11998-006-0031-4 ↗
72. Carbon Nanotubes Embedded Shape Memory Polyurethane Foams10.1007/s13233-019-7129-x ↗
73. A Multiple Remotely Controlled Platform from Recyclable Polyurethane Composite Network with Shape-Memory Effect and Self-Healing Ability10.1002/smll.202205286 ↗
74. Designing Strong yet Tough, Multifunctional and Printable Dynamic Cross-Linking Waterborne Polyurethane for Customizable Smart Soft Devices10.1002/adfm.202502720 ↗
75. Improving mechanical and water vapor barrier properties of the parylene C film by UV-curable polyurethane acrylate coating10.1515/epoly-2021-0047 ↗
76. Intelligent interaction system based on multimodal conformal triboelectric nanogenerator patch for disabled sports and life10.1007/s11431-024-2744-5 ↗
77. Pyridine type zwitterionic polyurethane with both multi-shape memory effect and moisture-sensitive shape memory effect for smart biomedical application10.1039/C6PY01099G ↗
78. Facile Preparation of Robust Superamphiphobic Coatings on Complex Substrates via Nonsolvent-Induced Phase Separation10.1021/acsami.2c11985 ↗
79. Park, Y.J., Yoon, J.Y., Kang, B.H., Kim, G.W., and Choi, S.B. (2020). A Tactile Device Generating Repulsive Forces of Various Human Tissues Fabricated from Magnetic-Responsive Fluid in Porous Polyurethane. Materials, 13.10.3390/ma13051062 ↗
80. Lee, J.H., and Kim, S.H. (2023). Shape memory polyurethanes crosslinked with castor oil-based multifunctional polyols. Sci. Rep., 13.10.1038/s41598-023-42024-1 ↗
81. Seo, E., Choi, J., Lee, B., Son, Y.-A., and Lee, K.J. (2019). Dye Clicked Thermoplastic Polyurethane as a Generic Platform toward Chromic-Polymer Applications. Sci. Rep., 9.10.1038/s41598-019-54832-5 ↗
82. Smart polyurethane foam with magnetic field controlled modulus and anisotropic compression property10.1039/c2ra22824f ↗
83. Contemporary advances in polymer applications for sporting goods: Fundamentals, properties, and applications10.1039/D4RA06544A ↗
84. Magneto-induced rheological properties of magnetorheological gel under quasi-static shear with large deformation10.1039/D0RA05843B ↗
85. Multi-material 3D printing-enabled multilayers for smart actuation magnetic and thermal stimuli10.1039/D2TC01109C ↗
86. Strong, detachable, and self-healing dynamic crosslinked hot melt polyurethane adhesive10.1039/C9QM00233B ↗
87. Li, F., Weng, K., Nakamura, A., Ono, K., Tanaka, T., Noda, D., Tanaka, M., Irifune, S., and Sato, H. (2024). Preparation of Waterborne Silicone-Modified Polyurethane Nanofibers and the Effect of Crosslinking Agents on Physical Properties. Polymers, 16.10.3390/polym16111500 ↗
88. Li, F., Weng, K., Tanaka, T., He, J., Zheng, H., Noda, D., Irifune, S., and Sato, H. (2024). Fabrication of Waterborne Silicone-Modified Polyurethane Nanofibers for Nonfluorine Elastic Waterproof and Breathable Membranes. Polymers, 16.10.3390/polym16111505 ↗
89. Liu, H., Xiong, H., Chang, Y., Xu, J., Xu, C., and Liu, Y. (2022). Fabrication of Superhydrophobic Coating Based on Waterborne Silicone-Modified Polyurethane Dispersion and Silica Nanoparticles. Polymers, 15.10.3390/polym15010022 ↗
90. Wang, Q., Dong, F., Dai, J., Zhang, Q., Jiang, M., and Xiong, Y. (2019). Recycled-Oil-Based Polyurethane Modified with Organic Silicone for Controllable Release of Coated Fertilizer. Polymers, 11.10.3390/polym11030454 ↗
91. Xu, T., Shen, W., Lin, X., and Xie, Y.M. (2020). Mechanical Properties of Additively Manufactured Thermoplastic Polyurethane (TPU) Material Affected by Various Processing Parameters. Polymers, 12.10.3390/polym12123010 ↗
92. Yang, X., Han, Z., Jia, C., Wang, T., Wang, X., Hu, F., Zhang, H., Zhao, J., and Zhang, X. (2023). Preparation and Characterization of Body-Temperature-Responsive Thermoset Shape Memory Polyurethane for Medical Applications. Polymers, 15.10.3390/polym15153193 ↗
93. Pekas, D., Radaš, J., Baić, M., Barković, I., and Čolakovac, I. (2023). The Use of Wearable Monitoring Devices in Sports Sciences in COVID Years (2020–2022): A Systematic Review. Appl. Sci., 13.10.3390/app132212212 ↗
94. Rajšp, A., and Fister, I. (2020). A Systematic Literature Review of Intelligent Data Analysis Methods for Smart Sport Training. Appl. Sci., 10.10.3390/app10093013 ↗
95. Hao, G., Li, X., Wang, S., Wang, S., Ryu, M., and Yang, J. (2023). Surface Modification of Carbon Nanotubes in Silicone–Polyurethane for Improved Mechanical and Anticorrosion Properties. Coatings, 13.10.3390/coatings13030634 ↗
96. Carbonaro, N., Lorussi, F., and Tognetti, A. (2016). Assessment of a Smart Sensing Shoe for Gait Phase Detection in Level Walking. Electronics, 5.10.3390/electronics5040078 ↗
97. Sun, F., Zhu, Y., Jia, C., Ouyang, B., Zhao, T., Li, C., Ba, N., Li, X., Chen, S., and Che, T. (2022). A Flexible Lightweight Triboelectric Nanogenerator for Protector and Scoring System in Taekwondo Competition Monitoring. Electronics, 11.10.3390/electronics11091306 ↗
98. Tensile Stress-Gated Electromagnetic Interference Shielding Fabrics with Real-Time Adjustable Shielding Efficiency10.1021/acssuschemeng.1c05589 ↗
99. Developments in smart organic coatings for anticorrosion applications: A review10.1007/s13399-022-02363-x ↗
100. A volatile organic compound free unibody triboelectric nanogenerator and its application as a smart green track10.1016/j.nanoen.2022.108001 ↗