journal article·2023-10-31Open access

Influence of Electron Beam Treatment on Structure and Phase Composition of TiB2–Ag Coating Deposited by Electrical Explosion Spraying

Artem D. Filyakov, Vasilii V. Pochetukha, Denis A. Romanov, Ekaterina S. Vashchuk

Coatings· Volume 13· Issue 11

Abstract

Due to many factors, the electrical explosion spraying process is not stable, which directly causes unstable coating quality and structure. Electron beam treatment may be used to improve the surface and modified structure of coatings sprayed by electrical explosions. In this study, a new TiB2–Ag metal matrix composite coating was deposited by electrical explosion spraying and modified by electron beam treatment. The prepared coatings were characterized by surface macro- and microanalysis, XDR, cross-section SEM, and TEM. The composition of the spray-coating phase differs from sample to sample. The electron beam treatment normalized the phase composition. Ag TiB2 B2O became the main phase in the modified coating. Increasing the pulse energy density and duration leads to a reduction in the low-melting Ag phase and the formation of copper contact phases due to heating and melting of the copper substrate by excess electron beam energy. The coating structure consists of a silver matrix and TiB2 inclusions. The electron beam treatment did not affect the structure; however, the microstructure of the coating transformed into a cellular crystallization structure. The silver matrix nanostructure was transformed into a nanocrystalline structure with an average crystal size ranging from tens to hundreds of nanometers.
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Research context

OpenAlex topics: Diamond and Carbon-based Materials Research · High-Temperature Coating Behaviors · Advanced materials and composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Laboratory of Scanning Electron Microscopy and Image Processing, Siberian State Industrial University, Novokuznetsk 654007, Russia

Scientific Research Department, Siberian State Industrial University, Novokuznetsk 654007, Russia

Funding

Russian Science Foundation

References (33)

Show source-provided references
1. Copper-MAX-Phase Composite Coatings Obtained by Electro-Co-Deposition: A Promising Material for Electrical Contacts10.1016/j.surfcoat.2017.04.060 ↗
2. Low-Voltage Circuit Breaker Arcs—Simulation and Measurements10.1088/0022-3727/46/27/273001 ↗
3. Fretting Corrosion Behavior of Electrical Contacts with Tin Coating in Atmosphere and Vacuum10.1016/j.wear.2018.11.024 ↗
4. Arc-Erosion Behavior of Boric Oxide-Reinforced Silver-Based Electrical Contact Materials Produced by Mechanical Alloying10.1007/s11664-014-3399-4 ↗
5. Influence of Fabrication Technology on Arc Erosion of Ag/10SnO2 Electrical Contact Materials10.1016/j.jallcom.2018.06.317 ↗
6. Arc Erosion Characteristics Evolution of Ag/Ti3SiC2 Composites during Repetitive Arc Breakdowns in SF6 Gaseous Medium10.1111/ijac.13727 ↗
7. Effect of WC Particle Size and Ag Volume Fraction on Electrical Contact Resistance and Thermal Conductivity of Ag–WC Contact Materials10.1016/j.matdes.2015.07.006 ↗
8. Corrosion, Oxidation, Erosion and Performance of Ag/W-Based Circuit Breaker Contacts: A Review10.1016/j.corsci.2018.02.010 ↗
9. Research on the Influence of Different Oxide Particles on Properties of AgCdO Contact Material10.1088/1742-6596/1948/1/012192 ↗
10. Fabrication and Arc Erosion Behaviors of AgTiB2 Contact Materials10.1016/j.powtec.2014.01.068 ↗
11. Nilsson, O., Hauner, F., and Jeannot, D. (2004, January 23–23). Replacement of AgCdO by AgSnO/Sub2/ in DC Contactors. Proceedings of the 50th IEEE Holm Conference on Electrical Contacts and the 22nd International Conference on Electrical Contacts Electrical Contacts, Seattle, WA, USA.
12. Fabrication of a Novel Silver-Based Electrical Contact Composites and Assessment of Its Mechanical and Electrical Properties
13. Comparison of Properties of Silver-Metal Oxide Electrical Contact Materials10.2298/JMMB111101013C ↗
14. Investigation on Preparation, Microstructure, and Properties of AgTiB2 Composite10.1177/0021998310376100 ↗
15. Effect of Strengthening Phase on Material Transfer Behavior of Ag-Based Contact Materials under Different Voltages10.1016/j.vacuum.2016.10.031 ↗
16. Material Transfer Behavior of AgTiB2 and AgSnO2 Electrical Contact Materials under Different Currents10.1016/j.matdes.2016.10.056 ↗
17. The Wear and Arc Erosion Behavior of Novel Copper Based Functionally Graded Electrical Contact Materials Fabricated by Hot Pressing Assisted Electroless Plating10.1016/j.apt.2021.05.053 ↗
18. Fabrication and Characterization of Novel Layered Materials Produced by Electroless Plating and Hot Pressing10.1016/j.jallcom.2020.155278 ↗
19. Effect of Al2O3 Content and Milling Time on the Properties of Silver Coated Cu Matrix Composites Fabricated by Electroless Plating and Hot Pressing10.1016/j.mtcomm.2020.101153 ↗
20. Comparison on Corrosion-Resistance Performance of Electro-Thermal Explosion Plasma Spraying FeAl-Based Coatings10.1016/j.surfcoat.2006.07.100 ↗
21. Zirconium Boride and Tantalum Carbide Coatings Sprayed by Electrothermal Explosion of Powders10.1007/s11666-997-0032-6 ↗
22. Nanostructuring of Surfaces of Metalloceramic and Ceramic Materials by Electron-Beams10.1007/s11182-008-9073-7 ↗
23. Dai, D., Zhang, C., Fang, Z., and Lu, X. (2022, January 14–16). Discharge Characteristics and Dynamic Process of Directional Spraying Binary and Ternary Alloy Coating via Electrical Explosion Method. Proceedings of the 4th International Symposium on Plasma and Energy Conversion, Foshan, China.
24. Improvement of Copper Alloy Properties in Electro-Explosive Spraying of ZnO-Ag Coatings Resistant to Electrical Erosion10.1016/j.jmrt.2019.09.019 ↗
25. TiN–TiB2 Ceramics Degradation in the Region of a Steady-State Laser Heating10.1016/j.surfcoat.2019.06.058 ↗
26. Ma, G., Chen, S., and Wang, H. (2022). Micro Process and Quality Control of Plasma Spraying, Springer Nature.10.1007/978-981-19-2742-3 ↗
27. Formation Mechanism of Gas Phase in Supersonic Atmospheric Plasma Sprayed NiCr-Cr3C2 Cermet Coatings10.1016/j.surfcoat.2020.126052 ↗
28. Phase Composition, Structure, and Wear Resistance of Electric-Explosive CuO–Ag System Coatings after Electron Beam Processing10.3103/S1062873819100174 ↗
29. Electrical Explosion Spray of Ag/C Composite Coating and Its Deposition Behavior10.1016/j.ceramint.2021.10.235 ↗
30. Modeling of the Initial Stages of the Formation of Heterogeneous Plasma Flows in the Electric Explosion of Conductors10.1016/j.cap.2018.06.010 ↗
31. Surface Modification by the EVU 60/10 Electroexplosive System10.3103/S0967091211060131 ↗
32. Nevskii, S., Sarychev, V., Konovalov, S., Granovskii, A., and Gromov, V. (2020). Formation Mechanism of Micro- and Nanocrystalline Surface Layers in Titanium and Aluminum Alloys in Electron Beam Irradiation. Metals, 10.10.3390/met10101399 ↗
33. Model of Nanostructure Formation in Al–Si Alloy at Electron Beam Treatment10.1088/2053-1591/aaec1f ↗