journal article·2025-04-24Open access

Electrochemical One-Step Synthesis of Cu2O with Tunable Oxygen Defects and Their Electrochemical Performance in Li-Ion Batteries

Yu Zheng, Lanxiang Huang, Feiyu Jian, Shujia Zhao, Wu Tang, Hui Tang

Coatings· Volume 15· Issue 5

Abstract

We report a facile galvanic oxidation corrosion method for the preparation of cuprite nanocrystals (Cu2O) with controllable oxygen vacancies. The Cu2O microspheres have been employed as active anode materials in lithium-ion batteries (LIBs), exhibiting excellent electrochemical performance. The effect of oxygen vacancies on the electrochemical properties was studied. The oxygen vacancy-rich Cu2O electrodes exhibited a high specific discharge capacity (1002.3 mAh g−1 at 0.1 C) and remarkable reversibility. Oxygen vacancies in Cu2O not only promote high electronic conductivity but also provide additional active sites for lithiation/delithiation, further enhancing electrochemical performance. Furthermore, the formation mechanism of Cu2O during the galvanic oxidation–corrosion process has been proposed.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Copper-based nanomaterials and applications · ZnO doping and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, China

School of New Energy Materials and Chemistry, Leshan Normal University, Leshan 614004, China

References (48)

Show source-provided references
1. Guidelines and trends for next-generation rechargeable lithium and lithium-ion batteries10.1039/C7CS00863E ↗
2. The Li-Ion Rechargeable Battery: A Perspective10.1021/ja3091438 ↗
3. Issues and challenges facing rechargeable lithium batteries10.1038/35104644 ↗
4. Unusual pseudocapacitive lithium-ion storage on defective Co3O4 nanosheets10.1088/1361-6528/ac54de ↗
5. Anode materials for lithium-ion batteries: A review10.1016/j.apsadv.2022.100233 ↗
6. Recent developments in advanced anode materials for lithium-ion batteries10.20517/energymater.2021.02 ↗
7. Impact of Electrode Defects on Battery Cell Performance: A Review10.1002/batt.202200239 ↗
8. Building better batteries10.1038/451652a ↗
9. Two-Dimensional Materials to Address the Lithium Battery Challenges10.1021/acsnano.9b08396 ↗
10. Promises, Challenges, and Recent Progress of Inorganic Solid-State Electrolytes for All-Solid-State Lithium Batteries10.1002/adma.201705702 ↗
11. Synthesis of starfish-like Cu2O nanocrystals through γ-irradiation and their application in lithium-ion batteries10.1007/s11051-011-0422-z ↗
12. Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries10.1038/35035045 ↗
13. In-situ reduction synthesis of nano-sized Cu2O particles modifying g-C3N4 for enhanced photocatalytic hydrogen production10.1016/j.apcatb.2014.01.047 ↗
14. An efficient route to Cu2O nanorod array film for high-performance Li-ion batteries10.1016/j.tsf.2016.03.065 ↗
15. Particle size effects on the electrochemical performance of copper oxides toward lithium10.1149/1.1353566 ↗
16. Preparation of Cu2O particles with different morphologies and their application in lithium ion batteries10.1016/j.jpowsour.2007.06.030 ↗
17. Cu2O Nanoparticles and Multi-Branched Nanowires as Anodes for Lithium-Ion Batteries10.1142/S1793292018501035 ↗
18. Novel synthesis and electrochemical performance of nano-structured composite with Cu2O embedment in porous carbon as anode material for lithium ion batteries10.1016/j.jpowsour.2013.03.085 ↗
19. Boosting the activity and stability of Ag-Cu2O/ZnO nanorods for photocatalytic CO2 reduction10.1016/j.apcatb.2019.118380 ↗
20. Cu/Cu2O@Ppy nanowires as a long-life and high-capacity anode for lithium ion battery10.1016/j.cej.2019.123597 ↗
21. The catanionic surfactant-assisted syntheses of 26-faceted and hexapod-shaped Cu2O and their electrochemical performances10.1039/c1ce05319a ↗
22. Electrochemical one-step synthesis of Mn3O4 with tunable oxygen defects for high-performance aqueous zinc-ion batteries10.1016/j.jallcom.2022.167933 ↗
23. Gram-Scale Synthesis of Cu2O Nanocubes and Subsequent Oxidation to CuO Hollow Nanostructures for Lithium-Ion Battery Anode Materials10.1002/adma.200800596 ↗
24. Synthesis of Cu2O/reduced graphene oxide composites as anode materials for lithium ion batteries10.1016/S1003-6326(13)62918-0 ↗
25. Oxygen vacancy-rich Fe3O4 nanoparticle synthesized via facile electrochemical method as anode material for high-performance lithium-ion batteries10.1016/j.jpcs.2022.111028 ↗
26. Superior electrochemical performance and structure evolution of mesoporous Fe2O3 anodes for lithium-ion batteries10.1016/j.nanoen.2013.10.003 ↗
27. Recent progress in conversion reaction metal oxide anodes for Li-ion batteries10.1039/C7QM00175D ↗
28. KOH-Induced Oxygen-Deficient VO2 for High-Rate Aqueous Zn-Ion Batteries10.1021/acsaem.2c03754 ↗
29. Oxygen vacancy–rich Cu2O@Cu with a hydrophobic microenvironment for highly selective C–C coupling to generate C2H410.1016/j.cej.2022.140321 ↗
30. Nickel-doped δ-MnO2 abundant in oxygen vacancies as a cathode material for aqueous Zn-ion batteries with superior performance10.1039/D5NR00009B ↗
31. Phenolphthalein-Modified Multivalent Vanadium Oxide: Harnessing Oxygen Vacancies and Hydrophobicity for Improved Aqueous Zinc-Ion Battery Performance10.1021/acssuschemeng.3c08380 ↗
32. A Robust and Conductive Black Tin Oxide Nanostructure Makes Efficient Lithium-Ion Batteries Possible10.1002/adma.201700136 ↗
33. Electrochemical fabrication of shape-controlled Cu2O with spheres, octahedrons and truncated octahedrons and their electrocatalysis for ORR10.1039/C7NJ04200K ↗
34. Controlled synthesis of micro/nanostructured CuO anodes for lithium-ion batteries10.1016/j.nanoen.2014.08.009 ↗
35. Oxygen-Vacancy-Rich Cu2O Hollow Nanocubes for Nitrate Electroreduction Reaction to Ammonia in a Neutral Electrolyte10.1021/acs.inorgchem.2c02716 ↗
36. Grigore, M., Biscu, E., Holban, A., Gestal, M., and Grumezescu, A. (2016). Methods of Synthesis, Properties and Biomedical Applications of CuO Nanoparticles. Pharmaceuticals, 9.10.3390/ph9040075 ↗
37. Coupling Zn2+ doping and rich oxygen vacancies in MnO2 nanowire toward advanced aqueous zinc-ion batteries10.1016/j.jcis.2023.04.062 ↗
38. Graphene oxide nano-sheets wrapped Cu2O microspheres as improved performance anode materials for lithium ion batteries10.1016/j.nanoen.2014.10.011 ↗
39. Recent progress of advanced anode materials of lithium-ion batteries10.1016/j.jechem.2020.08.056 ↗
40. High-Performance Reversible Aqueous Zn-Ion Battery Based on Porous MnOx Nanorods Coated by MOF-Derived N-Doped Carbon10.1002/aenm.201801445 ↗
41. Three-Dimensionally Mesostructured Fe2O3 Electrodes with Good Rate Performance and Reduced Voltage Hysteresis
42. Cu2O nanowires as anode materials for Li-ion rechargeable batteries10.1007/s11431-014-5509-1 ↗
43. Facile electrochemical fabrication of magnetic Fe3O4 for electrocatalytic synthesis of ammonia used for hydrogen storage application10.1016/j.ijhydene.2021.04.203 ↗
44. Electrodeposition of Cu2O films and their photoelectrochemical properties10.1039/c0ce00829j ↗
45. Controlled growth of Cu2O thin films by electrodeposition approach10.1016/j.mssp.2017.02.012 ↗
46. Controlling the Size of Au Nanoparticles on Reducible Oxides with the Electrochemical Potential10.1021/jacs.2c08422 ↗
47. The Effect of Deposition Time on the Properties of Cu2O Nanocubes Using an Electrochemical Deposition Method10.1007/s11664-020-08495-y ↗
48. High performance Cu2O film/ZnO nanowires self-powered photodetector by electrochemical deposition10.1088/1674-1056/aba610 ↗