journal article·2024-10-08Open access

Effect of Sintering Process on Microstructure and Properties of (Zr0.2Ta0.2Ti0.2Cr0.2Hf0.2)Si2 High-Entropy Silicide Ceramics

Zihao Zhang, Huaigan Yi, Mengtian Liang, Linying Xie, Bingbing Yin, Yi Yang

Coatings· Volume 14· Issue 10

Abstract

In this study, five kinds of (Zr0.2Ta0.2Ti0.2Cr0.2Hf0.2)Si2 high-entropy ceramics were prepared by a two-step method under different vacuum pressureless pre-sintering processes, and the microstructures and mechanical properties of the ceramics under different parameters of the pre-sintering process were systematically discussed. The results show that the physical structure of the ceramic samples remains basically unchanged by changing the pre-sintering conditions; the longer the holding time of the initial pre-sintering, the higher the densification of the samples and all of them are above 95%. The hardness of the ceramics was around 10 GPa, with the best hardness of 10.11 GPa at 1300 °C for 3 h. This conclusion provides data support for the optimization of the high-entropy ceramics preparation process.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: High Entropy Alloys Studies · Intermetallics and Advanced Alloy Properties · Advanced materials and composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, China

Funding

Science and Technology on Advanced Ceramic Fibers and Composites Laboratory

References (37)

Show source-provided references
1. Kasim, K., Muley, A., Stoia, M., and Ladeinde, F. (2017, January 3–9). Advanced heat transfer devices for aerospace applications. Proceedings of the ASME International Mechanical Engineering Congress and Exposition, Tampa, FL, USA.10.1115/IMECE2017-72382 ↗
2. Patterson, R.L., Hammoud, A., and Elbuluk, M. (2008, January 11–14). Electronic components for use in extreme temperature aerospace applications. Proceedings of the 12th International Components for Military and Space Electronics Conference (CMSE 08), San Diego, CA, USA.
3. Carbon–carbon composite materials10.1023/B:INMA.0000036327.90241.5a ↗
4. Structure and oxidation of C/C composites: Role of the interface10.1016/S0008-6223(00)00142-1 ↗
5. A low-temperature prepared composite coating to protect SiC-coated C/C composites against oxidation in a wide temperature range for long-life service10.1016/j.jeurceramsoc.2023.03.037 ↗
6. Oxidation protection of B4C modified HfB2-SiC coating for C/C composites at 1073–1473 K10.1016/j.ceramint.2021.10.094 ↗
7. Microstructural evolution of SiC coating on C/C composites exposed to 1500 °C in ambient air10.1016/j.ceramint.2018.09.255 ↗
8. Oxidation behavior and protection of carbon/carbon composites10.1016/0008-6223(87)90197-7 ↗
9. Advances in oxidation and ablation resistance of high and ultra-high temperature ceramics modified or coated carbon/carbon composites10.1016/j.jeurceramsoc.2017.08.013 ↗
10. Microstructure and properties of aluminum-containing refractory high-entropy alloys10.1007/s11837-014-1066-0 ↗
11. Low-density, refractory multi-principal element alloys of the Cr-Nb-Ti-V-Zr system: Microstructure and phase analysis10.1016/j.actamat.2012.11.032 ↗
12. Mechanical properties of low-density, refractory multi-principal element alloys of the Cr-Nb-Ti-V-Zr system10.1016/j.msea.2012.12.018 ↗
13. Silicide coating fabricated by HAPC/SAPS combination to protect niobium alloy from oxidation10.1021/acsami.6b04599 ↗
14. Development of silicide coatings to ensure the protection of Nb and silicide composites against high temperature oxidation10.1016/j.surfcoat.2013.07.053 ↗
15. Synthesis of oxidation resistant silicide coatings on Mo-Si-B alloys10.1016/j.scriptamat.2005.05.015 ↗
16. Microstructure and mechanical properties of high-entropy borides derived from boro/carbothermal reduction10.1016/j.jeurceramsoc.2019.05.017 ↗
17. (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high-entropy ceramics with low thermal conductivity10.1111/jace.15779 ↗
18. Calcium-magnesium-alumina-silicate (CMAS) resistant high entropy ceramic (Y0.2Gd0.2Er0.2Yb0.2Lu0.2)2Zr2O7 for thermal barrier coatings10.1016/j.jmst.2021.07.053 ↗
19. Investigation of effects of process parameters on microstructure and fracture toughness of SLM CoCrFeMnNi10.1016/j.jallcom.2024.173998 ↗
20. Assessing fracture toughness in sintered Al2O3-ZrO2(3Y)-SiC ceramic composites through indentation technique10.1016/j.ceramint.2020.07.194 ↗
21. Microstructure of Al-Si-Mg alloy with Zr/Hf additions during solidification and solution treatment10.1007/s12598-018-1100-4 ↗
22. Vacuum rapid fabrication of (Nb, Ti, Cr) Si2 coatings with Mo, W addition: Microstructure and oxidation resistance at 1450 °C10.1016/j.vacuum.2019.03.037 ↗
23. Chinese Society for Metals (CSM), and The Minerals, Metals & Materials Society (TMS) (2016). Separation of zirconium and hafnium: A review. Energy Materials 2014, Spinger.
24. Entropy-stabilized silicides: Expanding the B20 single-phase region from mono-silicide to high-entropy silicide10.1063/5.0123794 ↗
25. EEffect of sintering temperature on the morphology, crystallinity and mechanical properties of carbonated hydroxyapatite (CHA)10.1016/j.ceramint.2020.07.153 ↗
26. Limitations of pore-stress concentrations on the mechanical properties of porous materials10.1023/A:1018674713006 ↗
27. Influence of sintering temperatures on material properties and corresponding milling machinability of zirconia ceramics10.1016/j.jmapro.2021.05.012 ↗
28. Fracture toughness of ZrO2-SiC/MoSi2 composite ceramics prepared by powder metallurgy10.1016/j.ceramint.2021.03.309 ↗
29. High hardness and high fracture toughness B4C-diamond ceramics obtained by high-pressure sintering10.1016/j.jeurceramsoc.2023.01.044 ↗
30. Densification and mechanical properties of TiC by SPS-effects of holding time, sintering temperature and pressure condition10.1016/j.jeurceramsoc.2012.04.017 ↗
31. Densification and mechanical properties of alumina ceramics via two-step sintering with different holding times
32. On mode II fracture toughness of sintered silver based on end-notch flexure (ENF) test considering various sintering parameters10.1016/j.msea.2021.141729 ↗
33. Alloying of MoSi2 for improved mechanical properties10.1016/S0966-9795(01)00084-X ↗
34. Complete elimination of pest oxidation by high entropy refractory metallic silicide (Mo0.2W0.2Cr0.2Ta0.2Nb0.2)Si210.1016/j.scriptamat.2020.07.059 ↗
35. Formation and oxidation behavior of refractory high-entropy silicide (NbMoTaW)Si2 coating10.1016/j.corsci.2022.110134 ↗
36. Ab initio investigation of phase stability, thermo-physical and mechanical properties of (Mo0.2Cr0.2Ta0.2Nb0.2X0.2)Si2 (X = W, V) high-entropy refractory metal silicides10.1016/j.commatsci.2021.111116 ↗
37. A high-entropy silicide: (Mo0.2Nb0.2Ta0.2Ti0.2W0.2)Si2