journal article·2024-01-20Open access

Formation and Electrochemical Properties of Heterostructured Electrodes Based on Cu2O and CuCo2O4

Anna A. Murashkina, Aida V. Rudakova, Tair V. Bakiev, Alexei V. Emeline, Detlef W. Bahnemann

Coatings· Volume 14· Issue 1

Abstract

Individual (FTO/Cu2O and FTO/CuCo2O4) and heterostructured (FTO/BiVO4/Cu2O, FTO/BiVO4/CuCo2O4, and FTO/CuCo2O4/Cu2O) electrodes were successfully formed using the electrodeposition method on copper-containing compounds. The morphology of the synthesized electrode systems, which affect the electrochemical properties, was determined. A comparative study of the electrochemical and photoelectrochemical properties of the individual and heterostructured electrodes showed that the modification of the BiVO4 electrode surface with Cu2O and CuCo2O4 oxides led to a significant increase in its efficiency as a photoanode. The deposition of Cu2O nanoclusters onto CuCo2O4 nanoflakes increased the electrochemical stability of the electrode while maintaining its high capacitance.
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Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Copper-based nanomaterials and applications · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Laboratory of Photoactive Nanocomposite Materials, Saint Petersburg State University, 199034 Saint-Petersburg, Russia

Department of Photonics, Saint Petersburg State University, 199034 Saint-Petersburg, Russia

Funding

Russian Science Foundation

References (44)

Show source-provided references
1. Heterostructure engineering in electrode materials for sodium-ion batteries: Recent progress and perspectives10.1016/j.esci.2023.100139 ↗
2. Goodarzi, N., Ashrafi-Peyman, Z., Khani, E., and Moshfegh, A.Z. (2023). Recent progress on semiconductor heterogeneous photocatalysts in clean energy production and environmental remediation. Catalysts, 13.10.3390/catal13071102 ↗
3. Heterostructured electrode with concentration gradient shell for highly efficient oxygen reduction at low temperature10.1038/srep00155 ↗
4. Heterostructured catalysts for electrocatalytic and photocatalytic carbon dioxide reduction10.1002/adfm.201910768 ↗
5. Emerging of heterostructured materials in CO2 electroreduction: A perspective10.1016/j.ccst.2022.100043 ↗
6. Heterostructures for electrochemical hydrogen evolution reaction: A review10.1002/adfm.201803291 ↗
7. A Simple two-step electrodeposition of Cu2O/ZnO nanopillar solar cells10.1021/jp1004314 ↗
8. Challenges in synthesis of heterostructures10.1039/D2TC00324D ↗
9. Emeline, A.V., Rudakova, A.V., Mikhaylov, R.V., Bulanin, K.M., and Bahnemann, D.W. (2021). Photoactive heterostructures: How they are made and explored. Catalysts, 11.10.3390/catal11020294 ↗
10. Stable α-MoO3 electrode with a widened electrochemical potential window for aqueous electrochemical capacitors10.1021/acsaem.0c02990 ↗
11. Growth and characterization of electrodeposited Cu2O thin films10.1088/0268-1242/28/11/115005 ↗
12. Effect of pH on the electrodeposition nucleation and growth mechanism of cuprous oxide10.1007/s10008-023-05408-x ↗
13. Electrodeposition of one-dimensional nanostructures: Environmentally friendly method10.12974/2311-8717.2022.10.03 ↗
14. Synthetic strategies of BiVO4 for efficient visible-light-induced photocatalytic oxidation reactions: Activation via nanoparticulation and surface modification10.2109/jcersj2.22153 ↗
15. A tandem photoelectrochemical water splitting cell consisting of CuBi2O4 and BiVO4 synthesized from a single Bi4O5I2 nanosheet template10.1039/C8FD00183A ↗
16. Su, Q., Zuo, C., Liu, M., and Tai, X. (2023). A review on Cu2O-based composites in photocatalysis: Synthesis, modification, and applications. Molecules, 28.10.3390/molecules28145576 ↗
17. Electrochemical oxygen evolution reaction of controllable self-assembled CuCo2O410.1007/s11581-022-04667-4 ↗
18. Synthesis of CuCo2O4 nanoparticles as an anode material with high performance for lithium-ion batteries10.1007/s10854-021-06395-3 ↗
19. Design of porous double-shell Cu2O@CuCo2O4 Z-scheme hollow microspheres with superior redox property for synergistic photocatalytic degradation of multi-pollutants10.1016/j.cej.2020.124339 ↗
20. A review on the synthesis of CuCo2O4-based electrode materials and their applications in supercapacitors
21. CTAB-templated formation of CuCo2O4/CuO nanorods and nanosheets for high-performance supercapacitor applications10.1007/s10854-021-06845-y ↗
22. Maevskaya, M.V., Rudakova, A.V., Koroleva, A.V., Sakhatskii, A.S., Emeline, A.V., and Bahnemann, D.W. (2021). Effect of the type of heterostructures on photostimulated alteration of the surface hydrophilicity: TiO2/BiVO4 vs. ZnO/BiVO4 planar heterostructured coatings. Catalysts, 11.10.3390/catal11121424 ↗
23. Highly improved quantum efficiencies for thin film BiVO4 photoanodes10.1021/jp203004v ↗
24. Electrodeposition of Cu2O: Growth, properties, and applications10.1007/s10008-017-3660-x ↗
25. Electrodeposition of p-type, n-type and p-n homojunction cuprous oxide thin films10.4038/sljp.v9i0.2509 ↗
26. Electrodeposited Cu2O homojunction solar cells: Fabrication of a cell of high short circuit photocurrent10.1016/j.solmat.2016.07.005 ↗
27. Facile electrodeposition of high-density CuCo2O4 nanosheets as a high-performance Li-ion battery anode material10.1016/j.jiec.2018.09.042 ↗
28. Electrodeposition of Cu2O films and their photoelectrochemical properties10.1039/c0ce00829j ↗
29. Photoelectrochemistry of electrodeposited Cu2O10.1149/1.1393221 ↗
30. Electrochemical deposition of copper(I) oxide films10.1021/cm9602095 ↗
31. Electrodeposition and characterization of cuprous oxide10.1016/0040-6090(87)90157-X ↗
32. Electrodeposited copper oxide films: Effect of bath pH on grain orientation and orientation-dependent interfacial behavior10.1016/j.tsf.2006.08.041 ↗
33. Nanoporous CuCo2O4 nanosheets as a highly efficient bifunctional electrode for supercapacitors and water oxidation catalysis10.1016/j.apsusc.2018.11.151 ↗
34. CuxCo3−xO4 used as bifunctional electrocatalyst: Physicochemical properties and electrochemical characterization for the oxygen evolution reaction
35. Physicochemical and electrochemical properties of CuCo2O4 electrodes prepared by thermal decomposition for oxygen evolution10.1149/1.2069516 ↗
36. Photoelectrochemical stability of electrodeposited Cu2O films10.1021/jp103437y ↗
37. Photoelectrochemical stability improvement of cuprous oxide (Cu2O) thin films in aqueous solution10.1002/er.3328 ↗
38. Facile synthesis of Cu2O microstructures and their morphology dependent electrochemical supercapacitor properties10.1039/C5RA20331G ↗
39. Nawaz, B., Ullah, M.O., and Ali, G. (2021). An Investigation of the electrochemical properties of CuCo2 O4@NiCo2O4 composite as binder-free electrodes of a supercapacitor. Energies, 14.10.3390/en14113237 ↗
40. Smart design of free-standing ultrathin Co–Co(OH)2 composite nanoflakes on 3D nickel foam for high-performance electrochemical capacitors10.1039/C4CC07499H ↗
41. Characterization of thin CuCo2O4 films prepared by chemical spray pyrolysis. Study of their electrochemical stability by ex situ spectroscopic analysis10.1016/S0022-0728(96)05072-3 ↗
42. Self-templated formation of CuCo2O4 triple-shelled hollow microspheres for all-solid-state asymmetric supercapacitors10.1016/j.jallcom.2019.02.134 ↗
43. Effect of precursor on the morphology and supercapacitor performance of CuCo2O410.20964/2019.04.62 ↗
44. Diffusion kinetics of CuCo2O4 nanorods for next-generation solid state sodium-ion hybrid supercapacitor10.1002/est2.482 ↗