Ionic Liquid/Na-Bentonite/Microcrystalline Cellulose Ionogels as Conductive Multifunctional Materials
Source abstract
Abstract
For the synthesis of ionogels containing microcrystalline cellulose (MCC) and Na-bentonite (Na-Bent), ionic liquid (IL) 1-butyl-3-methylimidazolium acetate was used as an MCC solvent. Characterization and research of the physicochemical properties of the synthesized materials were carried out using methods such as SEM, WAXS, thermal analysis, FTIR, conductometry, and viscometry. WAXS analysis showed an increase in the interlayer distance of Na-bentonite in composites due to the intercalation of IL molecules. Based on the data on the characteristic temperatures of thermal degradation, enhanced thermal stability of triple IL/Na-Bent/MCC ionogels was revealed compared to that for cellulose-free systems. It was found that the electrical conductivity of both triple IL/Na-Bent/MCC and binary IL/MCC ionogels was non-monotonous. The data obtained can be used in the formation of multifunctional coatings with enhanced thermal stability.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Advanced Cellulose Research Studies · Ionic liquids properties and applications · Nanocomposite Films for Food Packaging
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
G.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo 153045, Russia
Funding
State Assignment
References (37)
Show source-provided references
1. Environmental applications of chitosan and cellulosic biopolymers: A comprehensive outlook10.1016/j.biortech.2017.03.119 ↗
2. Ionic liquid-modified cellulosic hydrogels for loading and sustained release of selenourea: An ensuing inhibition of tyrosinas activity10.1016/j.mtchem.2020.100365 ↗
3. Creep and stress relaxation behavior of functionalized microcrystalline cellulose/epoxy composites10.1007/s10570-022-05020-8 ↗
4. Ahmad, U., and Akhtar, U. (2019). Pharmaceutical Formulation Design—Recent Practices, IntechOpen.10.5772/intechopen.78460 ↗
5. Microcrystalline cellulose: Isolation, characterization and bio-composites application10.1016/j.ijbiomac.2016.09.056 ↗
6. Rasheed, M., Jawaid, M., Karim, Z., and Abdullah, L.C. (2020). Morphological, physiochemical and thermal properties of microcrystalline cellulose (MCC) extracted from bamboo Fiber. Molecules, 25.10.3390/molecules25122824 ↗
7. Structure formation of regenerated cellulose materials from nmmo-solutions10.1016/S0079-6700(01)00025-9 ↗
8. Novel solvents for cellulose10.15376/biores.16.2.2192-2195 ↗
9. Fabrication of cellulose film with enhanced mechanical properties in ionic liquid 1-allyl-3-methylimidaxolium chloride (AmimCl)10.3390/ma6041270 ↗
10. Ionic liquids: Solvent properties and organic reactivity10.1002/poc.863 ↗
11. Ionic liquids as electrolytes10.1016/j.electacta.2006.03.016 ↗
12. The effect of the nature of cation on transport properties of bis(trifluoromethylsulfonyl)imide ionic liquids10.1134/S1023193519100057 ↗
13. Ionic liquids confined in porous matrices: Physicochemical properties and applications10.1016/j.pmatsci.2014.03.001 ↗
14. The hype with ionic liquids as solvents10.1016/j.cplett.2016.07.044 ↗
15. Flieger, J., and Flieger, M. (2020). Ionic liquids toxicity—Benefits and threats. Int. J. Mol. Sci., 21.10.3390/ijms21176267 ↗
16. Cellulose based faber spinning processes using ionic liquids10.1007/s10570-022-04473-1 ↗
17. Understanding the dissolution of cellulose in 1-butyl-3-methylimidazolium acetate+ DMAc solvent10.1016/j.ijbiomac.2015.09.058 ↗
18. Novel chemically cross-linked chitosan-cellulose based ionogel with self-healability, high ionic conductivity, and high thermo-mechanical stability10.1007/s10570-020-03144-3 ↗
19. Cellulose dissolution in ionic liquid from hydrogen bonding perspective: First principles calculations10.1007/s10570-023-05140-9 ↗
20. Shamsuri, A.A., Abdan, K., and Kaneko, T. (2021). A Concise review on the physicochemical properties of biopolymer blends prepared in ionic Liquids. Molecules, 26.10.3390/molecules26010216 ↗
21. Fabrication of ionic liquid-cellulose-silica hydrogels with appropriate thermal stability and good salt tolerance as potential drilling fluid10.1016/j.arabjc.2020.05.027 ↗
22. Bionanocomposites of regenerated cellulose/zeolite prepared using environmentally benign ionic liquid solvent10.1016/j.carbpol.2014.02.085 ↗
23. Evans, S.K., Wesley, O.N., Koech, L., Nelana, S.M., and Rutto, H.L. (2023). Structural features of cellulose and cellulose nanocrystals via in situ incorporation of magnetic iron oxide nanoparticles: Modification and characterization. Coatings, 13.10.3390/coatings13010039 ↗
24. Application of montmorillonite in bentonite as a pharmaceutical excipient in drug delivery systems10.1007/s40005-016-0258-8 ↗
25. High performance liquid crystalline bionanocomposite ionogels prepared by in situ crosslinking of cellulose/halloysite nanotubes/ionic liquid dispersions and its application in supercapacitors10.1016/j.apsusc.2018.06.026 ↗
26. Alekseeva, O.V., Shibaeva, V.D., Noskov, A.V., Ivanov, V.K., and Agafonov, A.V. (2021). Enhancing the thermal stability of ionogels: Synthesis and properties of triple ionic liquid/halloysite/MCC ionogels. Molecules, 26.10.3390/molecules26206198 ↗
27. Idealized powder diffraction patterns for cellulose polymorphs10.1007/s10570-013-0030-4 ↗
28. Optimized methods for obtaining cellulose and cellulose sulfates from birch wood10.1007/s00226-015-0723-y ↗
29. Microcrystalline cellulose powders: Structure, surface features and water sorption capability10.1023/A:1009204309120 ↗
30. Evaluation of the role of an ionic liquid as organophilization agent into montmorillonite for NBR rubber nanocomposite production10.1016/j.clay.2013.09.002 ↗
31. Effect of synthesis conditions on the properties of an ionic liquid in the 1-butyl-3-methylimidazolium acetate-Na-bentonite ionogel. Steric stabilization and confinement10.1016/j.molliq.2020.113703 ↗
32. Inter molecular interactions in mixtures of 1-n-butyl-3-methylimidazolium acetate and water: Insights from IR, Raman, NMR spectroscopy and quantum chemistry calculations10.1016/j.molliq.2015.05.015 ↗
33. Study of the properties of microcrystalline cellulose particles from different renewable resources by XRD, FTIR, Nanoindentation, TGA and SEM10.1007/s10924-010-0167-2 ↗
34. Bionanocomposite fibers based on cellulose and montmorillonite using ionic liquid 1-ethyl-3-methylimidazolium acetate10.1007/s10853-014-8679-0 ↗
35. Zielinska, D., Skrzypczak, A., Peplinska, B., and Borysiak, S. (2022). Nanocellulose-based polymer composites functionalized with new gemini ionic liquids. Int. J. Mol. Sci., 23.10.3390/ijms232415807 ↗
36. Synthesis, structure and thermal properties of montmorillonite/ionic liquid ionogels10.1039/D0RA06443B ↗
37. Alekseeva, O.V., Noskov, A.V., Grishina, E.P., Ramenskaya, L.M., Kudryakova, N.O., Ivanov, V.K., and Agafonov, A.V. (2019). Structure and thermal properties of the montmorillonite/ionic liquid composites. Materials, 12.10.3390/ma12162578 ↗