journal article·2023-10-02Open access

Pomace from Oil Plants as a New Type of Raw Material for the Production of Environmentally Friendly Biocomposites

Izabela Betlej, Piotr Borysiuk, Sławomir Borysiak, Katarzyna Rybak, Małgorzata Nowacka, Marek Barlak, Bogusław Andres, Krzysztof Krajewski, Karolina Lipska, Tomasz Cebulak, Piotr Boruszewski

Coatings· Volume 13· Issue 10

Abstract

The production of environmentally friendly biocomposites can be based on attractive and low-cost vegetable pomace, a waste product from oil production. In the present study, biocomposites made from HDPE and pomace from black cumin, corn, and flax seeds were subjected to evaluation of structural, morphological, and thermal parameters and susceptibility to germination by filamentous fungi. Based on the characteristics of the produced biocomposites, it should be concluded that vegetable waste from oil production, applied at a 1:1 ratio as a filler for polyethylene-based biocomposites, significantly reduces the crystallinity of the produced material and decreases its thermal stability. It should also be noted that such biocomposites are more easily overgrown by fungi, which may facilitate their biodegradation. Very poor antioxidant properties, resulting from the encapsulation of the plant fraction in polyethylene, limit the functionality of this type of material as, for example, active biomaterials to prevent free radical processes. Although the structural and physical characteristics of the produced biocomposites have been shown to be inferior to polyethylene, efforts should be made to improve these characteristics. Plant waste can be a valuable raw material for the production of materials compatible with various industries.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Natural Fiber Reinforced Composites · Nanocomposite Films for Food Packaging

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Wood Sciences and Furniture, Warsaw University of Life Sciences—SGGW, 159 Nowoursynowska St., 02-776 Warsaw, Poland

Institute of Chemical Technology and Engineering, Faculty of Chemical Technology, Poznan University of Technology, Berdychowo 4, 60-965 Poznan, Poland

Department of Food Engineering and Process Management, Institute of Food Sciences, Warsaw University of Life Sciences—SGGW, 159C Nowoursynowska St., 02-776 Warsaw, Poland

Plasma/Ion Beam Technology Division, Material Physics Department, National Centre for Nuclear Research Świerk, 7 Sołtana St., 05-400 Otwock, Poland

Department of Food Technology and Human Nutrition, Institute of Food Technology and Nutrition, College of Natural Sciences, University of Rzeszów, 4 Zelwerowicza St.; 35-601 Rzeszów, Poland

References (63)

Show source-provided references
1. Food and Agriculture Organization of United Nations (FAO) (2017). The Future of Food and Agriculture—Trends and Challenges, FAO. Available online: https://www.fao.org/3/i6583e/i6583e.pdf.
2. Babu, S., Singh Rathore, S., Singh, R., Kumar, S., Singh, V.K., Yadav, S.K., Yadav, V., Raj, R., Yadav, D., and Shekhawat, K. (2022). Exploring Agricultural Waste Biomass for Energy, Food and Feed Production and Pollution Mitigation: A Review. Bioresour. Technol., 360.10.1016/j.biortech.2022.127566 ↗
3. The History and Current Applications of the Circular Economy Concept10.1016/j.rser.2016.09.123 ↗
4. Agricultural Waste Management Strategies for Environmental Sustainability10.1016/j.envres.2021.112285 ↗
5. Acar, S., and Yeldan, E. (2019). Handbook of Green Economics, Academic Press.
6. Grumezescu, A.M., and Holban, A.M. (2017). Handbook of Food Bioengineering, Food Bioconversion, Academic Press.
7. Rice Waste Streams as a Promising Source of Biofuels: Feedstocks, Biotechnologies and Future Perspectives10.1016/j.rser.2022.112673 ↗
8. Evaluation of the possibility of using apple pomace for fertilizing purposes
9. Galal, T.M., Ali, E.F., Eid, E.M., Al-Yasi, H.M., Magrashi, A., Althobaiti, F., and Farahat, E.A. (2022). Evaluating the Nutrient Contents and Nutritive Value of Taif’s Rose (Rosa damascena Mill var. trigintipetala) Waste to Be Used as Animal Forage or Soil Organic Fertilizers. Agriculture, 12.10.3390/agriculture12091481 ↗
10. Juárez-Alvarado, C.A., Magniont, C., Escadeillas, G., Terán-Torres, B.T., Rosas-Diaz, F., and Valdez-Tamez, P.L. (2022). Sustainable Proposal for Plant-Based Cementitious Composites, Evaluation of Their Mechanical, Durability and Comfort Properties. Sustainability, 14.10.3390/su142114397 ↗
11. Plant Fibers and Wasted Fiber/Epoxy Green Composites10.1016/j.compositesb.2012.04.044 ↗
12. Developing Fire Retardant Composites of Biodegradable Polyethylene Reinforced with Agricultural Wastes10.1016/j.asej.2022.101768 ↗
13. Ashori, A. (2017). 2—Hybrid thermoplastic composites using nonwood plant fibers. Hybrid Polym. Compos. Mater. Prop. Characteris., 39–56.10.1016/B978-0-08-100787-7.00002-0 ↗
14. Singh, A., Gu, Y., Castellarin, S.D., Kitts, D.D., and Pratap-Singh, A. (2020). Development and Characterization of the Edible Packaging Films Incorporated with Blueberry Pomace. Foods, 9.10.3390/foods9111599 ↗
15. Ballinas-Casarrubias, L., Camacho-Davila, A., Gutierrez Méndez, N., Ramos-Sánchez, V.H., Chávez-Flores, D., Manjarrez-Nevárez, L., Zaragoza-Galán, G., and González-Sanchez, G. (2016). Recent Advances in Biopolymers, InTech.
16. Jawaid, M., and Thariq, M. (2018). Woodhead Publishing Series in Composites Science and Engineering, Woodhead Publishing Series in Composites Science and Engineering.
17. Mechanical and Thermal Properties of Natural Fibers Reinforced Polymer Composites: Doum/Low Density Polyethylene10.1016/j.matdes.2012.06.056 ↗
18. Hemp Fiber Reinforced Polypropylene Composites: The Effects of Material Treatments10.1016/j.compositesb.2017.02.001 ↗
19. Barczewski, M., Aniśko, J., Hejna, A., Mysiukiewicz, O., Kosmela, P., Sałasińska, K., Boczkowska, A., Przybylska-Balcerek, A., and Stuper-Szablewska, K. (2023). Ground lemon and stevia leaves as renewable functional fillers with antioxidant activity for high-density polyethylene composites. Clean Technol. Environ. Policy.10.1007/s10098-023-02565-5 ↗
20. Mechanical performance of woodfibre- waste plastic composite materials10.1016/j.resconrec.2003.12.001 ↗
21. Novel cork polymer composites reinforced with short natural coconut fibres: E_ect of fibre loading and coupling agent addition. Compos
22. Studying the e_ect of fiber size and fiber loading on the mechanical properties of hybridized kenaf/ PALF reinforced HDPE composite10.1177/0731684411399141 ↗
23. Thermal Properties of Olive Pomace Filled Linear Low Density Polyethylene Bio-Composites10.1080/00222348.2021.1923877 ↗
24. Gustafsson, J., Landberg, M., Bátori, V., Åkesson, D., Taherzadeh, M.J., and Zamani, A. (2019). Development of Bio-Based Films and 3D Objects from Apple Pomace. Polymers, 11.10.3390/polym11020289 ↗
25. Raschip, I.E., Fifere, N., and Dinu, M.V. (2021). A Comparative Analysis on the Effect of Variety of Grape Pomace Extracts on the Ice-Templated 3D Cryogel Features. Gels, 7.10.3390/gels7030076 ↗
26. Balancing Degradability and Physical Properties of Amorphous Poly(d,l-lactide) by Making Blends10.1002/mame.202100602 ↗
27. Polyethylene-like materials from plant oils10.1098/rsta.2019.0266 ↗
28. Recent advances in biodegradable polymers for sustainable applications10.1038/s41529-022-00277-7 ↗
29. Prochon, M., and Dzeikala, O. (2021). Biopolymer Composites as an Alternative to Materials for the Production of Ecological Packaging. Polymers, 13.10.3390/polym13040592 ↗
30. Sustainable thermal insulation biocomposites from rice husk, wheat husk, wood fibers and textile waste fibers: Elaboration and performances evaluation10.1016/j.indcrop.2019.04.053 ↗
31. Characterization and Comparative Study on Chemically Treated Luffa Fiber as Reinforcement for Polylactic Acid Bio-Composites10.15376/biores.17.2.2576-2597 ↗
32. Mirowski, J., Oliwa, R., Oleksy, M., Tomaszewska, J., Ryszkowska, J., and Budzik, G. (2021). Poly(vinyl chloride) Composites with Raspberry Pomace Filler. Polymers, 13.10.3390/polym13071079 ↗
33. Betlej, I., Salerno-Kochan, R., Borysiuk, P., Boruszewski, P., Monder, S., Krajewski, K., Andres, B., Krochmal-Marczak, B., Pisulewska, E., and Danecki, L. (2022). Quality Parameters of PE–Pomace Based Membranes. Membranes, 12.10.3390/membranes12111086 ↗
34. The resolution of multipeak data in fibre science10.1088/0022-3727/4/2/311 ↗
35. An assessment of the susceptibility of bacterial cellulose films to fouling by mold fungi10.5604/01.3001.0014.5235 ↗
36. Apak, R., and Capanoglu, E. (2018). Measurement of Antioxidant Activity & Capacity: Recent Trends and Applications, Wiley.10.1002/9781119135388 ↗
37. Space chargé distribution and crystalline structure in low density polyethylene (LDPE) blended with high density polyethylene (HDPE)10.1002/pi.1727 ↗
38. Mechanical and thermal performance of high-density polyethylene/alumina nanocomposites10.1080/00222348.2012.733297 ↗
39. Cellulose nanocrystals from grape pomace and their use for the development of starch-based nanocomposite films10.1016/j.ijbiomac.2020.05.046 ↗
40. Dintcheva, N.T., Infurna, G., Baiamonte, M., and D’Anna, F. (2020). Natural Compounds as Sustainable Additives for Biopolymers. Polymers, 12.10.3390/polym12040732 ↗
41. Preparation and Characterization of Polyethylene Biocomposites Reinforced by Rice Husk: Application as Potential Packaging Material10.3390/chemistry3040096 ↗
42. Polylactic acid–agave fiber biocomposites produced by rotational molding: A comparative study with compression molding10.1002/adv.21928 ↗
43. Polypropylene—Cellulose fibres composites. Part I. Influence of conditions of extrusion and injection processes on the structure of polypropylene matrix10.14314/polimery.2004.541 ↗
44. Grząbka-Zasadzińska, A., Klapiszewski, Ł., Borysiak, S., and Jesionowski, T. (2018). Thermal and Mechanical Properties of Silica–Lignin/Polylactide Composites Subjected to Biodegradation. Materials, 11.10.3390/ma11112257 ↗
45. The infrared spectra of polymers II: Polyethylene10.56530/spectroscopy.mh7872q7 ↗
46. Surface characterization of plasma-modified low density polyethylene by attenuated total reflectance fourier-transform infrared (ATR-FTIR) spectroscopy combined with chemometrics10.1016/j.polymertesting.2021.107080 ↗
47. Use of Fourier Transform Infrared Spectroscopy in Combination with Partial Least Square for Authentication of Black Seed Oil10.1080/10942912.2014.908207 ↗
48. Structural characterization, antimicrobial activity, and in vitro cytotoxicity effect of black seed oil10.1155/2019/6515671 ↗
49. Effect of chemical treatments on water sorption and mechanical properties of flax fibres10.1016/j.biortech.2009.04.067 ↗
50. Differentiating between Natural and Modified Cellulosic Fibres Using ATR-FTIR Spectroscopy10.3390/heritage5040213 ↗
51. Influence of Giant Reed Fibers on Mechanical, Thermal, and Disintegration Behavior of Rotomolded PLA and PE Composites10.1007/s10924-022-02542-x ↗
52. Rotational molding of biocomposites with addition of buckwheat husk filler. Structure-property correlation assessment for materials based on polyethylene (PE) and poly(lactic acid) PLA10.1016/j.compositesb.2020.108410 ↗
53. Manufacture and research of TPS/PE biocomposites properties10.1016/j.compositesb.2014.08.045 ↗
54. Thermogravimetric behavior of natural fibers reinforced polymer composites—An overview10.1016/j.msea.2012.05.109 ↗
55. da Costa Borges, M.A., Sorigotti, A.R., Paschoalin, R.T., Júnior, J.A.P., da Silva, L.H.D., Dias, D.S., Ribeiro, C.A., de Araújo, E.S., Resende, F.A., and da Silva Barud, H. (2023). Self-Supported Biopolymeric Films Based on Onion Bulb (Allium cepa L.): Gamma-Radiation Effects in Sterilizing Doses. Polymers, 15.10.3390/polym15040914 ↗
56. Nigella sativa oil: A promising prospective antifungal agent in the manufacture of low-salt soft cheese
57. Biocomposite materials from flax plants: Preparation and properties10.1016/j.compositesa.2008.08.008 ↗
58. Canales, D., Montoille, L., Rivas, L.M., Ortiz, J.A., Yañez-S, M., Rabagliati, F.M., Ulloa, M.T., Alvarez, E., and Zapata, P.A. (2019). Fungicides Films of Low-Density Polyethylene (LDPE)/Inclusion Complexes (Carvacrol and Cinnamaldehyde) against Botrytis cinereal. Coatings, 9.10.3390/coatings9120795 ↗
59. Evaluation of bioactive compounds and antibacterial activity of Pulicaria jaubertii extract obtained by supercritical and conventional methods10.1007/s11694-020-00652-5 ↗
60. Ordon, M., Nawrotek, P., Stachurska, X., and Mizielińska, M. (2021). Polyethylene Films Coated with Antibacterial and Antiviral Layers Based on CO2 Extracts of Raspberry Seeds, of Pomegranate Seeds and of Rosemary. Coatings, 11.10.3390/coatings11101179 ↗
61. Two different processes to obtain antimicrobial packaging containing natural oils10.1007/s11947-011-0626-3 ↗
62. Fortification of dietary biopolymers-based packaging material with bioactive plant extracts10.1016/j.foodres.2012.07.023 ↗
63. Antioxidant Migration Studies in Chitosan Films Incorporated with Plant Extracts