journal article·2024-12-23Open access

Carbon-Negative Nano-TiO2-Modified Photocatalytic Cementitious Composites: Removal of Airborne Pollutants (NOx and O3) and Its Impact on CO2 Footprint

Maciej Kalinowski, Karol Chilmon, Wioletta Jackiewicz-Rek

Coatings· Volume 14· Issue 12

Abstract

This study explores the development and performance of photocatalytic cementitious composites modified with nano-TiO2 to address urban air quality and sustainability challenges. Nine mortar series were prepared, incorporating binders with varying carbon footprints and mass contents across different series. The interplay between the fundamental (abrasion resistance) and functional (air purification efficiency) properties of the composites’ surfaces and interfaces was investigated. The photocatalytic removal of airborne pollutants, specifically nitrogen oxides (NOx) and ozone (O3), was evaluated under simulated environmental conditions. The variations in binder composition influenced the composites’ overall initial carbon footprint and air purification efficiency. The assessment revealed a possible net decrease in carbon emissions over the life cycle of the composite due to the removal of ozone (greenhouse gas) and its precursor—NOx, highlighting the potential of photocatalytic cementitious composites for dual environmental benefits in an urban environment, emphasizing the critical role of surface and interface engineering in achieving carbon-negative composites.
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Research context

OpenAlex topics: Concrete and Cement Materials Research · Building materials and conservation · TiO2 Photocatalysis and Solar Cells

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Faculty of Civil Engineering, Warsaw University of Technology, 00-637 Warsaw, Poland

Funding

Joint Venture between NCBiR (National Centre for Research and Development) and PKP PLK S.A.

References (75)

Show source-provided references
1. Enhancing sustainability in concrete production: A novel compression casting technique for optimizing cement usage10.1016/j.jobe.2024.110215 ↗
2. Recent advances in the concrete industry to reduce its carbon dioxide emissions10.1016/j.envc.2020.100004 ↗
3. Carbon dioxide implications of building materials
4. Green concrete mix using solid waste and nanoparticles as alternatives—A review10.1016/j.conbuildmat.2017.11.174 ↗
5. Supplementary cementitious materials origin from agricultural wastes—A review10.1016/j.conbuildmat.2014.10.010 ↗
6. Carbon dioxide emissions from traditional and modified concrete: A review
7. Study of two concrete mix-design strategies to reach carbon mitigation objectives10.1016/j.cemconcomp.2009.04.001 ↗
8. Kępniak, M., Zabawski, J., and Prochoń, P. (2024). Enhancing fire resistance of geopolymers modified with thermal insulation additives. Materials, 17.10.3390/ma17194854 ↗
9. Steel slag and its applications in cement and concrete technology: A review10.1016/j.conbuildmat.2021.122783 ↗
10. Waste glass in the production of cement and concrete—A review10.1016/j.jece.2014.03.016 ↗
11. Use of oil palm shell as an aggregate in cement concrete: A review10.1016/j.conbuildmat.2020.120357 ↗
12. Influence of fly ash on concrete—A systematic review10.1016/j.matpr.2020.06.425 ↗
13. Mechanical and hydration properties of low clinker cement containing high volume superfine blast furnace slag and nano silica10.1016/j.conbuildmat.2019.117683 ↗
14. Influence of sand substitution with waste lime powder on the concrete carbonation
15. Low-CO2 emission strategies to achieve net zero target in the cement sector10.1016/j.jclepro.2023.137466 ↗
16. Mitigation options for decarbonization of the non-metallic minerals industry and their impacts on costs, energy consumption, and GHG emissions in the EU—Systematic literature review10.1016/j.jclepro.2022.132006 ↗
17. Direct olivine carbonation: Optimal process design for a low-emission and cost-efficient cement production10.1021/acs.iecr.2c00984 ↗
18. Kalinowski, M., Chilmon, K., Bogacki, J., and Woyciechowski, P. (2024). Organic and inorganic modifications to increase the efficiency in immobilization of heavy metal (Zn) in cementitious composites—The impact of cement matrix pore network characteristics. Materials, 17.10.3390/ma17215281 ↗
19. Leaching and retention of dissolved metals in particulate loaded pervious concrete columns10.1016/j.jenvman.2016.12.047 ↗
20. Chilmon, K., Jaworska, B., Kalinowski, M., Jackiewicz-Rek, W., and Podkoń, A. (2023). Significance of vibration time in developing properties of precast pervious concrete. Materials, 16.10.3390/ma16186239 ↗
21. Research on the purification efficiency and mechanism for road runoff pollutants in pervious concrete with recycled aggregates10.1016/j.jenvman.2024.120180 ↗
22. Application of ternary cementless hybrid binders for pervious concrete10.1016/j.conbuildmat.2022.128497 ↗
23. Pb removal in pervious concrete filter: Effects of accelerated carbonation and hydraulic retention time10.1016/j.conbuildmat.2018.04.116 ↗
24. Design of a chitosan-modifying alkali-activated slag pervious concrete with the function of water purification10.1016/j.conbuildmat.2020.118979 ↗
25. A review of sustainable pervious concrete systems: Emphasis on clogging, material characterization, and environmental aspects10.1016/j.conbuildmat.2020.120491 ↗
26. Chilmon, K., Kalinowski, M., and Jackiewicz-Rek, W. (2024). Effect of cement substitution with mineral fillers on NOx air-purification efficiency and photocatalytic reaction selectivity of nano-TiO2-modified cementitious composites. Materials, 17.10.3390/ma17235775 ↗
27. Chilmon, K., Kalinowski, M., and Jackiewicz-Rek, W. (2024). Influence of coarse aggregate exposure on air purification efficiency in photocatalytic cement composites. Buildings, 14.10.3390/buildings14113639 ↗
28. Clay-supported TiO2 nanoparticles for photocatalytic degradation of environmental pollutants: A review10.1016/j.jece.2018.09.029 ↗
29. In situ evaluation of the NOx removal efficiency of photocatalytic pavements: Statistical analysis of the relevance of exposure time and environmental variables10.1007/s11356-019-04322-y ↗
30. Field study of air purifying paving elements containing TiO210.1016/j.atmosenv.2015.02.025 ↗
31. Kalinowski, M., Chilmon, K., Jackiewicz-Rek, W., and Rakowski, B. (2023). The influence of selected material variables of photocatalytic cementitious composites on the self-cleaning properties and air purification efficiency from NOx pollutants. Sustainability, 15.10.3390/su15010853 ↗
32. Photocatalytic degradation of nitrogen oxides (NOx) in a continuous-flow photoreactor with aluminosilicate microspheres coated with TiO2 thin films10.1016/j.cep.2024.109856 ↗
33. A case of familial cardiac amyloidosis10.4070/kcj.2004.34.5.520 ↗
34. Tryba, B., Prowans, B., Wróbel, R.J., Szołdra, P., and Pichór, W. (2024). Application of TiO2 supported on nickel foam for limitation of NOx in the air via photocatalytic processes. Molecules, 29.10.3390/molecules29081766 ↗
35. Investigating the role of organic compounds in intercontinental ozone transport: Reactivity scales and Global Warming Potentials (GWPs)10.1016/j.atmosenv.2023.119817 ↗
36. Life cycle greenhouse gas emissions of hemp–lime wall constructions in the UK10.1016/j.resconrec.2012.09.001 ↗
37. A comprehensive review on the properties of hemp incorporated concrete: An approach to low carbon footprint construction10.1016/j.nxsust.2024.100075 ↗
38. Modelling the impacts of emission changes on O3 sensitivity, atmospheric oxidation capacity, and pollution transport over the Catalonia region10.5194/acp-23-10751-2023 ↗
39. Central role of nitric oxide in ozone production in the upper tropical troposphere over the Atlantic Ocean and western Africa10.5194/acp-21-8195-2021 ↗
40. Effects of temperature-dependent NOx emissions on continental ozone production10.5194/acp-18-2601-2018 ↗
41. (2016). Methods of Testing Cement—Part 1: Determination of Strength (Standard No. EN 196-1:2016).
42. (1999). Methods of Test for Mortar for Masonry—Part 3: Determination of Consistence of Fresh Mortar (by Flow Table) (Standard No. EN 1015-3:1999).
43. (2014). Methods of Test for Screed Materials—Part 3: Determination of Wear Resistance–Böhme (Standard No. EN 13892-3:2014).
44. (2016). Fine Ceramics (Advanced Ceramics, Advanced Technical Ceramics)—Test Method for Air-Purification Performance of Semiconducting Photocatalytic Materials (Standard No. ISO 22197-1:2016).
45. (2011). Cement—Part 1: Composition, Specifications and Conformity Criteria for Common Cements (Standard No. EN 197-1:2011).
46. (2016). Methods of Testing Cement—Part 3: Determination of Setting Times and Soundness (Standard No. EN 196-3:2016).
47. Stowarzyszenie Producentów Cementu (2020). Environmental Product Declaration (EPD) for CEM I, CEM II, CEM III, CEM IV, and CEM V Cements Produced in Poland, Instytut Techniki Budowlanej (ITB). Available online: https://www.polskicement.pl.
48. (2002). Aggregates for Mortar (Standard No. EN 13139:2002).
49. Witkowski, H., Jackiewicz-Rek, W., Jarosławski, J., Chilmon, K., and Szkop, A. (2022). Ozone formation during photocatalytic oxidation of nitric oxides under UV irradiation with the use of commercial TiO2 photocatalytic powders. Materials, 15.10.3390/ma15175905 ↗
50. Carbon Footprint and CO2 Emissions in the Concrete-Polymer Composites Technology
51. A life cycle assessment of solar-based treatments (H2O2, TiO2 photocatalysis, circumneutral photo-Fenton) for the removal of organic micropollutants10.1016/j.scitotenv.2020.143258 ↗
52. Carbon dioxide equivalent (CO2-e) emissions: A comparison between geopolymer and OPC cement concrete10.1016/j.conbuildmat.2013.01.023 ↗
53. Park, H.J., Hossain, S.M., Choi, K., Shon, H.K., and Kim, J.H. (2022). A study on the evaluation methods of nitrogen oxide removal performance of photocatalytic concrete for outdoor applications. Catalysts, 12.10.3390/catal12080846 ↗
54. Russell, H.S., Frederickson, L.B., Hertel, O., Ellermann, T., and Jensen, S.S. (2021). A review of photocatalytic materials for urban NOx remediation. Catalysts, 11.10.3390/catal11060675 ↗
55. Effect of TiO2 and fly ash on photocatalytic NOx abatement of engineered cementitious composites10.1016/j.conbuildmat.2019.117559 ↗
56. TiO2/porous cementitious composites: Influences of porosities and TiO2 loading levels on photocatalytic degradation of gaseous benzene10.1016/j.conbuildmat.2017.06.004 ↗
57. Assessment of the long-term photocatalytic performance of cementitious systems incorporating different mineral admixtures10.1016/j.conbuildmat.2022.129215 ↗
58. Evaluation of the influence of environmental conditions on the efficiency of photocatalytic coatings in the degradation of nitrogen oxides (NOx)10.1016/j.buildenv.2011.09.016 ↗
59. Indoor air purification using heterogeneous photocatalytic oxidation. Part I: Experimental study10.1016/j.apcatb.2009.09.004 ↗
60. Photocatalytic oxidation of nitrogen oxides using TiO2 loading on woven glass fabric10.1016/j.chemosphere.2006.04.071 ↗
61. Photocatalytic systems as an advanced environmental remediation: Recent developments, limitations, and new avenues for applications10.1016/j.jece.2016.09.009 ↗
62. Andersson, A. (2021). Mechanisms for log-normal concentration distributions in the environment. Sci. Rep., 11.10.1038/s41598-021-96010-6 ↗
63. Principles of Photocatalysis10.1016/B978-0-443-18786-5.00002-0 ↗
64. (2024, November 30). Available online: https://klimada2.ios.gov.pl/rsds/.
65. Kalinowski, M., Woyciechowski, P., and Jackiewicz-Rek, W. (2023). Surface Modification of Photocatalytic Cementitious Composites with Polyacrylic Superabsorbent Polymers (SAP). Mater. Proc., 13.10.3390/materproc2023013023 ↗
66. Enhancement of Carbonation, Water Purification and CO2 Self-Sequestration in Hydrophobic Piezo-Photocatalytic Carbonation Coating for Concrete10.1016/j.cemconcomp.2024.105756 ↗
67. Purification Effect on Runoff Pollution of Porous Concrete with Nano-TiO2 Photocatalytic Coating10.1016/j.trd.2021.103101 ↗
68. Photocatalytic TiO2 Nanosheets-SiO2 Coatings on Concrete and Limestone: An Enhancement of De-Polluting and Self-Cleaning Properties by Nanoparticle Design10.1016/j.conbuildmat.2022.127349 ↗
69. Recent Advances in TiO2-Based Photocatalytic Concrete: Synthesis Strategies, Structure Characteristics, Multifunctional Applications, and CFD Simulation10.1016/j.cej.2024.154186 ↗
70. Cleaning up Oil Pollution in the Ocean with Photocatalytic Concrete Marine Structures10.1016/j.jclepro.2021.129636 ↗
71. Witkowski, H., Jarosławski, J., Szkop, A., Chilmon, K., Kalinowski, M., and Jackiewicz-Rek, W. (2024). The Potential Risk of Nanoparticulate Release from Photocatalytic Pavement Concrete Surface Due to a Simulated Abrasion Load—An Experimental Study. Materials, 17.10.3390/ma17123022 ↗
72. Self-Cleaning Durability Assessment of TiO2/SiO2 Photocatalysts Coated Concrete: Effect of Indoor and Outdoor Conditions on the Photocatalytic Activity10.1016/j.buildenv.2021.108743 ↗
73. Enhanced Photocatalytic Decomposition of NO on Portland Cement Concrete Pavement Using Nano-TiO2 Suspension10.1016/j.conbuildmat.2020.122135 ↗
74. Ramanavicius, S., and Jagminas, A. (2024). Synthesis, Characterisation, and Applications of TiO and Other Black Titania Nanostructures Species (Review). Crystals, 14.10.3390/cryst14070647 ↗
75. Kępniak, M. (2019). Ocena Przydatności Odpadu z Odpylania Kruszywa Jako Składnika Betonu Cementowego. [Ph.D. Thesis, Oficyna Wydawnicza Politechniki Warszawskiej].