journal article·2021-09-29Open access

Preparation and Thermal Shock Resistance of Gd2O3 Doped La2Ce2O7 Thermal Barrier Coatings

Lihua Gao, Fang Jia, Xiaoliang Lu

Coatings· Volume 11· Issue 10

Abstract

As one of the promising thermal barrier coating (TBC) candidates, stoichiometric (La0.8Gd0.2)2Ce2O7 (LGC) coatings were prepared by atmospheric plasma spraying (APS), using (La0.8Gd0.2)2Ce2.5O8 as a spray powder and optimized spray parameters. It was found that spray distance and spray power both play an important role in the phase composition and microstructure of the coating. The LGC coating exhibited lower thermal conductivities than that of La2Ce2O7 (LC) coating, which is ~0.67 W/m·K at 1200 °C. Double-ceramic-layer (DCL) optimum (La0.8Gd0.2)2Ce2O7/YSZ (LGC/YSZ) thermal barrier coating was prepared and its thermal shock behavior was investigated. The LGC/YSZ DCL TBCs had better thermal shock resistance ability than that of LC/YSZ TBCs, which was around 109 cycles at 1100 °C. However, the failure mode was similar to that of LC/YSZ DCL TBCs, which was still layer-by-layer spallation in the top ceramic layer due to the sintering of the ceramic coating.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: High-Temperature Coating Behaviors · Advanced ceramic materials synthesis · Advanced materials and composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Physics, Beihang University, No. 37 Xueyuan Road, Beijing 100191, China

BGRIMM Technology Group, No. 5 Fusheng Road, Beijing 102206, China

Funding

National Natural Science Foundation for Young Scientist Fund of China

References (39)

Show source-provided references
1. Thermal barrier coatings for gas-turbine engine applications10.1126/science.1068609 ↗
2. A nondestructive technique for determining thermal properties of thermal barrier coatings10.1063/1.1826217 ↗
3. Metallugraphic techniques for evaluation of thermal barrier coatings10.1016/1044-5803(90)90029-J ↗
4. Thermal barrier coatings for aircraft engines: History and directions10.1007/BF02646310 ↗
5. Vapor phase deposition using plasma spray-PVD10.1007/s11666-009-9428-9 ↗
6. Columnar-Structured thermal barrier coatings (TBCs) by thin film low-pressure plasma spraying (LPPS-TF)10.1007/s11666-010-9549-1 ↗
7. Design of high lifetime suspension plasma sprayed thermal barrier coatings10.1016/j.jeurceramsoc.2019.10.061 ↗
8. Review of suspension and solution precursor plasma sprayed thermal barrier coatings10.1016/j.ceramint.2016.06.063 ↗
9. Microstructure and texture of EB-PVD TBCs grown under different rotation modes10.1016/S0921-5093(03)00470-2 ↗
10. Microstructure-property correlations in industrial thermal barrier coatings10.1111/j.1151-2916.2004.tb07725.x ↗
11. Mechanisms governing the performance of thermal barrier coatings
12. Zirconates as new materials for thermal barrier coatings10.1111/j.1151-2916.2000.tb01506.x ↗
13. Effect of heat treatment on elastic properties of separated thermal barrier coatings10.1557/JMR.1999.0628 ↗
14. Phase transformation in EB-PVD yttria partially stabilized zirconia thermal barrier coatings during annealing10.1111/j.1151-2916.2000.tb01292.x ↗
15. Lanthanum hexaaluminate-a new material for atmospheric plasma spraying of advanced thermal barrier coatings10.1361/105996301770349105 ↗
16. Thermal stability of lanthanum zirconate plasma-sprayed coating10.1111/j.1151-2916.2001.tb00962.x ↗
17. Thermophysical properties of Yb2O3 doped Gd2Zr2O7 and thermal cycling durability of (Gd0.9Yb0.1)2Zr2O7/YSZ thermal barrier coatings10.1016/j.jeurceramsoc.2013.11.035 ↗
18. Lanthanum-cerium oxide as a thermal barrier-coating material for high-temperature applications10.1002/adma.200304132 ↗
19. Effect of gadolinia on phase structure and thermal conductivity of ZrO2-4.5 mol%Y2O3 ceramics10.1016/j.matlet.2008.03.052 ↗
20. Thermo-physical properties and thermal shock resistance of segmented La2Ce2O7/YSZ thermal barrier coatings10.1007/s11666-009-9350-1 ↗
21. Plasma-sprayed La2Ce2O7 thermal barrier coatings against calcium-magnesium-alumina-silicate penetration10.1016/j.jeurceramsoc.2014.02.031 ↗
22. Thermal cycling behavior of La2Ce2O7/YSZ double-ceramic-layer thermal barrier coatings prepared by atmospheric plasma spraying10.1016/j.surfcoat.2010.03.053 ↗
23. On improving the phase stability and thermal expansion coefficients of lanthanum cerium oxide solid solutions10.1016/j.scriptamat.2005.12.043 ↗
24. Influence of Gd2O3 addition on thermophysical properties of La2Ce2O7 ceramics for thermal barrier coatings10.1016/j.jeurceramsoc.2012.06.003 ↗
25. Investigation about thermal conductivities of La2Ce2O7 doped with calcium or magnesium for thermal barrier coatings10.1016/j.jallcom.2011.11.034 ↗
26. Preparation and thermal shock resistance of Gd2O3 doped La2Ce2O7 thermal barrier coatings
27. Review on advanced EB-PVD ceramic topcoats for TBC applications10.1111/j.1744-7402.2004.tb00182.x ↗
28. Effect of spraying power on microstructure and property of nanostructured YSZ thermal barrier coatings10.1016/j.jallcom.2017.09.323 ↗
29. Estimation of heat capacity of solid mixed oxides10.1016/S0040-6031(02)00177-6 ↗
30. The evolution of thermal barrier coatings status and upcoming solutions for today’s key issues10.1016/S0257-8972(99)00342-4 ↗
31. The quenching stress in thermally sprayed coatings10.1016/0040-6090(91)90029-W ↗
32. Thermal conductivity of dense and porous yttria-stabilized zirconia10.1023/A:1017970924312 ↗
33. Low-thermal-conductivity rare-earth zirconates for potential thermal-barrier-coating applications10.1111/j.1151-2916.2002.tb00574.x ↗
34. Thermal properties of La2O3–YSZ powder fabricated by heterogeneous precipitation10.1016/j.jallcom.2009.07.005 ↗
35. Methods to reduce the thermal conductivity of EB-PVD TBCs10.1016/S0257-8972(01)01651-6 ↗
36. Thermal stability of plasma-sprayed La2Ce2O7/YSZ composite coating10.1016/j.ceramint.2016.01.179 ↗
37. Optimization and thermal cycling behavior of La2Ce2O7 thermal barrier coatings10.1016/j.ceramint.2012.08.034 ↗
38. Thermal barrier coating life modeling in aircraft gas turbine engines10.1007/BF02646317 ↗
39. Tailoring columnar microstructure of axial suspension plasma sprayed TBCs for superior thermal shock performance10.1016/j.matdes.2018.02.011 ↗