journal article·2024-01-24Open access

A Comparison Study on the Microstructure, Mechanical Features, and Tribological Characteristics of TiN Coatings on Ti6Al4V Using Different Deposition Techniques

Zhen Liu, Shuai Ren, Tijun Li, Pinghu Chen, Liangbin Hu, Wenxing Wu, Sheng Li, Hao Liu, Ruiqing Li, Yun Zhang

Coatings· Volume 14· Issue 2

Abstract

Titanium alloys are considered lightweight alloys and are widely applied across various industries. However, their low hardness, poor wear resistance, and limited oxidation resistance restrict their prospects for wider application. In this paper, nitride coatings were prepared using three preparation processes, namely laser surface nitriding (LSN), physical vapor deposition (PVD), and plasma ion implantation (PII). Their microstructure, microhardness, tribological behavior, and high-temperature oxidation characteristics were compared. The experimental results revealed that nitrided coatings were successfully prepared using the three methods. However, a comparison of these data shows that the LSN coating exhibited superior comprehensive performance. It achieved the maximum thickness within the shortest preparation time: the thickness was about 280 μm and the deposition rate of the LSN method was 2250 and 90,000 times higher than those of the PVD and PII methods. Nitrides have high hardness, but the carrying capacity could be attributed to the thickness of the coatings: the PVD coating could withstand a force of 500 g, while the PII coating only withstood a force of less than 25 g. In addition, as hardness is the most important factor for excellent wear resistance, the average volumetric wear rate of the LSN and PVD coatings was about 9 × 10−6 mm3/m·N, and their relative wear resistance was 49.2 times that of Ti6Al4V. Meanwhile, the excellent bond between the LSN coating and the substrate was evidenced by a high-temperature oxidation test during a rapid heating–cooling cycle.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Metal and Thin Film Mechanics · Diamond and Carbon-based Materials Research · High Entropy Alloys Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Mechatronics and Control Engineering, Shenzhen University, Shenzhen 518060, China

State-Owned Sida Machinery Manufacturing Company, Xianyang 610400, China

Key Laboratory of Hunan Province of Equipment Safety Service Technology under Extreme Environment, College of Mechanical Engineering, College of Nuclear Science and Technology, School of Resource Environment and Safety Engineering, University of South China, Hengyang 421001, China

College of Mechanical Engineering, Hunan Institute of Engineering, Xiangtan 411104, China

State Key Laboratory of Precision Manufacturing for Extreme Service Performance, Light Alloys Research Institute, Central South University, Changsha 410083, China

School of Mechanical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China

Funding

National Natural Science Foundation of China · Education Department of Hunan Province · Project of the State Key Laboratory of Precision Manufacturing for Extreme Service Performance, Central South University · Hengyang City research project of the Science and Technology Bureau

References (32)

Show source-provided references
1. Recent developments in cold dwell fatigue of titanium alloys for aero-engine applications: A review10.1016/j.jmrt.2022.07.094 ↗
2. The Trajectory of Additively Manufactured Titanium Alloys with Superior Mechanical Properties and Engineered Microstructures
3. High-strength titanium alloys for aerospace engineering applications: A review on melting-forging process10.1016/j.msea.2022.143260 ↗
4. Tshephe, T.S., Akinwamide, S.O., Olevsky, E., and Olubambi, P.A. (2022). Additive manufacturing of titanium-based alloys- A review of methods, properties, challenges, and prospects. Heliyon, 8.10.1016/j.heliyon.2022.e09041 ↗
5. High efficient co-doping in plasma electrolytic oxidation to obtain long-term self-lubrication on Ti6Al4V10.1016/j.triboint.2021.107018 ↗
6. Alloying strategies for additive manufacturing of Ti6Al4V based alloys, composites and functionally graded materials: Microstructure and phase evolution of intra and inter-layer10.1016/j.jmrt.2023.11.060 ↗
7. Evaluation of laser cladding of Ti6Al4V-ZrO2-CeO2 composite coating on Ti6Al4V alloy substrate10.1016/j.surfcoat.2023.129988 ↗
8. Interfacial wear damage mechanism between Ti-alloy and Al-alloy in interference-fit joint and influence of surface coatings: Experimental and numerical study10.1016/j.engfailanal.2022.106931 ↗
9. The comparison of wear performances of CP-Ti, Ti6Al4V, Ti45Nb alloys oxidized by anodic oxidation under ambient air and vacuum conditions10.1016/j.mtcomm.2023.105466 ↗
10. Interfacial wear damage of CFRP/Ti-alloy single-lap bolted joint after long-term seawater aging10.1016/j.engfailanal.2022.106464 ↗
11. Effect of applied load on tribological behaviour of Ti–48Al–2Cr–2Nb alloy under oil-lubricated condition10.1016/j.wear.2023.205210 ↗
12. High-temperature oxidation behaviors and mechanical properties of TiAlCrMn HEAs during heat treatment10.1016/S1003-6326(23)66392-7 ↗
13. Development of a Ti30Hf20Nb20Ta10V10Mo7W3 refractory high entropy alloy with excellent mechanical properties and wear resistance10.1016/j.jallcom.2023.171571 ↗
14. The effect of Cu content on corrosion, wear and tribocorrosion resistance of Ti-Mo-Cu alloy for load-bearing bone implants10.1016/j.corsci.2020.109007 ↗
15. Investigation of microstructure and wear resistance of laser-clad CoCrNiTi and CrFeNiTi medium-entropy alloy coatings on Ti sheet10.1016/j.optlastec.2021.107518 ↗
16. NiTi coating on Ti-6Al-4V alloy by TIG cladding process for improvement of wear resistance: Microstructure evolution and mechanical performances10.1016/j.jmatprotec.2018.07.033 ↗
17. Microstructure, wear resistance and cell proliferation ability of in situ synthesized Ti–B coating produced by laser alloying10.1016/j.optlastec.2014.10.009 ↗
18. Design of high strength and wear-resistance β-Ti alloy via oxygen-charging10.1016/j.actamat.2022.117686 ↗
19. Improving impact wear resistance of Ti-6Al-4V alloy treated by laser shock peening10.1016/S1003-6326(19)65051-X ↗
20. Wear resistance enhancement of titanium alloy (Ti–6Al–4V) by ball burnishing process10.1016/j.jmrt.2016.03.007 ↗
21. Wear resistance of TiN(Ti2N)/Ti composite layer formed on C17200 alloy by plasma surface Ti-alloying and nitriding10.1016/j.apsusc.2016.03.059 ↗
22. A detailed analysis of the structural, morphological characteristics and micro-abrasive wear behavior of nitrided layer produced in α (CP–Ti), α+β (Ti–6Al–4V), and β (TNZ33) type Ti alloys10.1016/j.jmrt.2023.10.109 ↗
23. Effect of nitrogen ion implantation dose on torsional fretting wear behavior of titanium and its alloy10.1016/S1003-6326(17)60037-2 ↗
24. Formation of self-layered hydrothermal coating on magnesium aided by titanium ion implantation: Synergistic control of corrosion resistance and cytocompatibility10.1016/j.surfcoat.2020.126251 ↗
25. Wear and corrosion studies of duplex surface-treated AISI-304 steel by a combination of cathodic cage plasma nitriding and PVD-TiN coating10.1016/j.ceramint.2022.04.115 ↗
26. Investigation of nitrogen ionization state and its effect on the nitride layer during fiber laser gas nitriding of Ti-6Al-4V alloy10.1016/j.surfcoat.2021.127254 ↗
27. Metastable FeCrMnCo HEAs with the reinforcement of tungsten carbide fabricated by laser melting: Microstructure, mechanical properties and tribological behaviors10.1016/j.matchar.2023.113397 ↗
28. Influence of carbon-partitioning treatment on the microstructure, mechanical properties and wear resistance of in situ VCp-reinforced Fe-matrix composite10.1007/s12613-019-1909-3 ↗
29. The effect of manganese additions on the high temperature oxidation behaviour of the high-vanadium cast iron10.1016/j.jallcom.2018.07.113 ↗
30. Microstructure and corrosion resistance of novel β-type titanium alloys manufactured by selective laser melting10.1016/j.jmrt.2022.07.021 ↗
31. High temperature oxidation behavior of thermal and plasma processed aluminide coated Ti6Al4V alloys10.1016/j.surfcoat.2022.128839 ↗
32. Duplex treatment of arc plasma nitriding and PVD TiN coating applied to dental implant screws10.1016/j.surfcoat.2022.128449 ↗