Effect of Post-Fabrication Heat Treatments on the Microstructure of WC-12Co Direct Energy Depositions

Laser-Directed Energy Deposition (L-DED) is an additive manufacturing technique that has lately been employed to deposit coatings of cemented carbides, such as WC-Co. During deposition, complex microstructural phenomena usually occur, strongly affecting the microstructural and mechanical behavior of the coatings. Post-fabrication heat treatments (PFHTs) may be applied to homogenize and strengthen the microstructure; nevertheless, to the best of the authors’ knowledge, just a few papers deepened the effect of these treatments on cemented carbides fabricated by additive manufacturing. This work evaluates the influence of four PFHTs on the microstructural evolution and hardness of L-DED WC-12Co. For each treatment, different combinations of solubilization time and temperature (between 30 and 180 min and from 400 °C to 700 °C, respectively) were adopted. The microstructure was investigated by optical and scanning electron microscopy equipped with energy-dispersive spectroscopy, whereas the mechanical properties were determined by Vickers hardness measurements. Based on the results, high microstructural heterogeneity in terms of WC particles, η-phase structures, and Co distribution was observed in the sample in the as-built condition. Some cracking defects were also observed in the samples, irrespective of the heat treatment conditions. Finally, a finer microstructure and a lower amount of brittle ternary η-phase, together with an increase in hardness (1030 ± 95 HV10), were found for the highest dwelling times (180 min) and for solubilization temperatures in the range of 500–600 °C.