journal article·2022-12-27Open access

Influences of Synthetic Parameters on Morphology and Growth of High Entropy Oxide Nanotube Arrays

Yunzhu Shi, Rui Li, Zhifeng Lei

Coatings· Volume 13· Issue 1

Abstract

Nanoscale and nanostructured materials have drawn great attention owing to their outstanding and unique properties. Enlightened by the study of “entropy-stabilized oxides”, nanotubes consisting of multi-component mixed metal oxides are developed, which formed on equi-atomic TiZrHfNbTa high-entropy alloy (HEA). However, the growth mechanism and how the oxidation conditions influence the nanotube growth and morphology remains unknown. In the present study, by controlling the anodization parameters (applied voltages and time) and bath compositions (fluoride concentration and water content), scanning electron microscope and transmission electron microscopy are conducted to reveal the morphological evolution. The present work uncovers how the synthetic parameters influence the tube growth and morphology formed on equi-atomic TiZrHfNbTa HEA, therefore gaining insight into the growth mechanism and the feasibility of controlling the morphology of multi-component oxide nanotubes.
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Research context

OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Electronic and Structural Properties of Oxides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Materials Science and Engineering, Hunan University, Changsha 410082, China

Institute of Clean Energy, Northwestern Polytechnical University, Xi’an 710072, China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Hunan Province · The Fundamental Research Funds for the Central Universities · The Science and Technology Innovation Program of Hunan Province · The Gusu Leading Talents Program · The Basic Research Program of Taicang

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