journal article·2022-03-04Open access

Investigations of TiO2/NanoTiO2 Bimodal Coatings Obtained by a Hybrid PVD/ALD Method on Al-Si-Cu Alloy Substrate

Marcin Staszuk, Łukasz Reimann, Daniel Pakuła, Mirosława Pawlyta, Małgorzata Musztyfaga-Staszuk, Paweł Czaja, Petr Beneš

Coatings· Volume 12· Issue 3

Abstract

This study aimed to investigate the influence of bimodal TiO2/nanoTiO2 coatings obtained in the PVD/ALD hybrid process on an Al-Si-Cu-type aluminium alloy on the physicochemical properties of the investigated materials. The reference materials were uncoated substrates and samples coated with TiO2 coatings in single PVD and ALD processes. Tests were carried out on the morphology of coatings using scanning electron microscopy (SEM) and atomic force microscopy (AFM) to determine the structure of the tested coatings and their influence on physicochemical properties. The tests of physicochemical properties were carried out using the potentiodynamic and electrochemical impedance spectroscopy methods. The analysis of corrosion products obtained during the study of physicochemical properties was performed using SEM and EDS analysis. Based on the analysis of anode polarisation curves of the tested materials and Tafel analysis, it was found that a sample demonstrated the highest corrosion resistance with a bimodal coating-type TiO2/nanoTiO2, which had the lowest value of corrosion current and the highest value of polarisation resistance. The slightest corrosion resistance was characteristic for uncovered samples. Moreover, the influence of the tested coatings on the improvement of tribological contact of the surfaces of the coated materials with the counter-specimen made of cemented carbides was demonstrated.
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Research context

OpenAlex topics: Semiconductor materials and devices · Anodic Oxide Films and Nanostructures · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Engineering Materials and Biomaterials, Silesian University of Technology, Konarskiego St. 18a, 44-100 Gliwice, Poland

Materials Research Laboratory, Silesian University of Technology, Konarskiego St. 18a, 44-100 Gliwice, Poland

Welding Department, Silesian University of Technology, Konarskiego St. 18a, 44-100 Gliwice, Poland

Institute of Metallurgy and Materials Science, Polish Academy of Sciences, 25 Reymonta St., 30-059 Krakow, Poland

Department of Material Science and Technology, University of West Bohemia, Univerzitní 22, 301 00 Pilsen, Czech Republic

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