journal article·2024-03-22Open access

Effect of Ultrasonic Vibration on Microstructure and Antifouling Capability of Cu-Modified TiO2 Coating Produced by Micro-Arc Oxidation

Pengfei Hu, Liyang Zhu, Jiejun Liu, You Lv, Guangyi Cai, Xinxin Zhang

Coatings· Volume 14· Issue 4

Abstract

Ti and its alloys have received wide attention in marine engineering. However, the limited anti-biofouling capability may hinder their wide application. In the present work, micro-arc oxidation (MAO) with and without the introduction of ultrasonic vibration (UV) has been conducted on metallic Ti substrate in an aqueous solution containing Na2Cu-EDTA to produce a Cu-modified TiO2 coating. Microstructural characterization reveals that the introduction of UV increased the thickness of the coating (ranging from ~13.5 μm to ~26.2 μm) compared to the coating (ranging from ~8.1 μm to ~12.8 μm) without UV. A relatively higher Cu content (~2.13 wt.%) of the coating with UV relative to the coating (~1.39 wt.%) without UV indicates that UV enhances the incorporation of Cu into TiO2. Further, both electrochemical properties and the response to sulfate-reducing bacteria (SRB) were evaluated, revealing that UV introduction endows Cu-modified TiO2 coating with enhanced corrosion resistance and antifouling capability. The present results suggest that ultrasound-auxiliary micro-arc oxidation (UMAO) obviously enhances the surface performance of Ti alloys for promising applications in marine engineering.
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Research context

OpenAlex topics: Marine Biology and Environmental Chemistry · Bone Tissue Engineering Materials · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Key Laboratory of Electromagnetic Energy, Naval University of Engineering, Wuhan 430033, China

Key Laboratory of Material Chemistry for Energy Conversion and Storage, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Ministry of Education, 1037 Luoyu Road, Hongshan District, Wuhan 430074, China

Xiangtan Electric Power Co., Ltd., Xiangtan 411101, China

Funding

National Natural Science Foundation of China · Hubei Provincial Natural Science Foundation of China

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