journal article·2022-12-20Open access

Upgrading Paper-Grade Pulp as Dissolving Pulp for Lyocell Fiber Preparation

Chen Gong, Jianping Ni, Shujie Fan, Yu Zhang, Bin Yang, Zhenhua Su

Coatings· Volume 13· Issue 1

Abstract

Lyocell fiber has emerged as a new generation of green fiber due to its preparation process and unique properties in comparison with viscose fiber. The raw material for the preparation of Lyocell fiber has a great impact on the quality of the finished product. However, unlike viscose-grade dissolving pulp, there is no evaluation system for Lyocell-grade dissolving pulp, making it difficult to assess the quality of the raw material. This study examined the approach to upgrade the paper-grade pulp to dissolving pulp for the preparation of the raw material for Lyocell fiber. Under the sequence of caustic extraction, acid treatment, and enzymatic treatment, the pulp was prepared with competitive properties compared to the commercial Lyocell-grade dissolving pulp. The assessment of prepared pulp was also accomplished by characterizing the pulp properties, the dissolution properties, and the spinnability and stability of Lyocell solution using the prepared sample. In addition, the dissolution mechanism and influencing factors of pulp in the system were elucidated, providing a theoretical basis for upgrading paper-grade pulp to dissolving pulp for Lyocell fiber production.
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Research context

OpenAlex topics: Advanced Cellulose Research Studies · Biofuel production and bioconversion · Lignin and Wood Chemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

China National Pulp and Paper Research Institute Co., Ltd., Beijing 100102, China

Funding

China National Pulp and Paper Research Institute Co., Ltd.

References (19)

Show source-provided references
1. Cellulose solutions in N-methylmorpholine-N-oxide (NMMO)—Degradation processes and stabilizers10.1023/A:1021127423041 ↗
2. Structure formation of regenerated cellulose materials from NMMO-solutions10.1016/S0079-6700(01)00025-9 ↗
3. Pulidindi, K., and Chakraborty, S. (2020, July 20). Lyocell Fiber Market Size Industry Share Report 2017–2024. Available online: https://www.gminsights.com/industry-analysis/lyocell-fiber-market?utm_source=prnewswire.com&utm_medium=referral&utm_campaign=Paid_prnewswire.
4. A critical review of manufacturing processes used in regenerated cellulosic fibres: Viscose, cellulose acetate, cuprammonium, LiCl/DMAc, ionic liquids, and NMMO based lyocell10.1007/s10570-019-02318-y ↗
5. Influence of intensified cellulose dissolution process on spinning and properties of lyocell fibres10.1016/j.cep.2020.108063 ↗
6. A review on raw materials, commercial production and properties of lyocell fiber10.1016/j.jobab.2020.03.002 ↗
7. Upgrading softwood bleached kraft pulp to dissolving pulp by cold caustic treatment and acid-hot caustic treatment10.1016/j.indcrop.2014.09.051 ↗
8. Enzyme pretreatment of dissolving pulp as a way to improve the following dissolution in NaOH/ZnO10.1515/hf-2013-0070 ↗
9. Heteropoly acid catalytic treatment for reactivity enhancement and viscosity control of dissolving pulp10.1016/j.biortech.2018.01.022 ↗
10. Trends on the Cellulose-Based Textiles: Raw Materials and Technologies10.3389/fbioe.2021.608826 ↗
11. Preparation of Lyocell fiber from high hemicellulose pulp
12. Sixta, H. (2006). Dissolving grade pulp. Handbook of Pulp, Wiley-VCH.10.1002/9783527619887 ↗
13. Discoloration of cellulose solutions in N-methylmorpholine-N-oxide (Lyocell). Part 1: Studies on model compounds and pulps10.1007/s10570-004-0212-1 ↗
14. Zhang, H.R. (2007). Study on Lyocell Fiber from a Cheap Pulp with High Hemicellulose Content. [Ph.D. Thesis].
15. Rheology of Lyocell Solutions from Different Cellulose Sources10.1023/A:1014881901010 ↗
16. Swelling and Dissolution of Cellulose Part 1: Free Floating Cotton and Wood Fibres in N-Methylmorpholine-N-oxide–Water Mixtures10.1002/masy.200651201 ↗
17. Determination of viscoelastic and rheo-optical material functions of water-soluble cellulose derivatives10.1016/S0079-6700(01)00024-7 ↗
18. Severian, D. (2005). Rheological behavior of polysaccharides aqueous systems. Polysaccharides: Structural Diversity and Functional Versatility, Marcel Dekker. [2nd ed.].
19. Rheological behavior of cellulose/monohydrate of n-methylmorpholine n-oxide solutions Part 1: Liquid state10.1007/s003970050096 ↗