journal article·2022-11-07Open access

Manufacture and Characterization of Geopolymer Coatings Deposited from Suspensions on Aluminium Substrates

Jan Novotný, Martin Jaskevič, Filip Mamoń, Jakub Mareš, Roman Horký, Pavel Houška

Coatings· Volume 12· Issue 11

Abstract

Geopolymers compete with a number of conventional coatings and a few of them have already been replaced. The aim of this work was the analysis of alkali-activated metakaolin-based geopolymers and their use as brush-applied coatings, which were chosen due to their simplicity and cost-effectiveness. Eight coatings were prepared and the AlMgSi aluminum alloy underlying the substrate was also studied. The main characterizations of the prepared coatings were the microscopy analysis, which showed that manual painting with a brush on the coatings we prepared could achieve a high-quality geopolymer layer, and that if microscopic cracks are visible on the surface, they are uniform and do not affect the resulting cohesiveness of the coating. The thicknesses of these coatings are different, ranging from 1.5 to 11 μm, with no visible anomalies. For the evaluation of the properties of the coatings, we determined the analysis of adhesion to the adjacent substrate, microhardness and thermal expansion determined using the so-called dilatometric analysis as important criteria. For these analyses, the results vary by geopolymer type and are discussed in the following chapters.
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Research context

OpenAlex topics: Concrete and Cement Materials Research · Innovative concrete reinforcement materials · Smart Materials for Construction

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Faculty of Mechanical Engineering, J. E. Purkyne University in Usti nad Labem, Pasteurova 3334/7, 40001 Usti nad Labem, Czech Republic

Faculty of Social and Economic Studies, J. E. Purkyne University in Usti nad Labem, Pasteurova 3334/7, 40001 Usti nad Labem, Czech Republic

Funding

Creation of micro and nanocomposites based on inorganic matrices

References (52)

Show source-provided references
1. Kolek, T. (2021). Research on the Properties of Geopolymer Coatings Doped with Particles of Alloys and Metal Oxides. [Master’s Thesis, Jan Evangelista Purkyně University in Ústí nad Labem, Faculty of Mechanical Engineering, Institute of Technology and Materials].
2. Matsimbe, J., Dinka, M., Olukanni, D., and Musonda, I. (2022). Geopolymer: A systematic review of methodologies. Materials, 15.10.3390/ma15196852 ↗
3. Microscopic study of the concrete/geopolymer coating interface
4. Processing and properties of geopolymers as thermal insulating materials: A review
5. Synthesis and characterisation of materials based on inorganic polymers of alumina and silica: Sodium polysialate polymers10.1016/S1466-6049(00)00041-6 ↗
6. Microstructure and microhardness property of the interface between a metakaolin/GGBFS-based geopolymer paste and granite aggregate10.1016/j.conbuildmat.2019.06.090 ↗
7. Geopolymer coating paste on concrete for photocatalytic performance10.1063/5.0044215 ↗
8. Horký, R. (2021). Analysis of the effect of geopolymer coatings on thermal dilatations of metal alloys. [Master’s Thesis, Jan Evangelista Purkyně University in Ústí nad Labem, Faculty of Mechanical Engineering, Institute of Technology and Materials].
9. Dissolution processes, hydrolysis and condensation reactions during geopolymer synthesis: Part I—Low Si/Al ratio systems10.1007/s10853-006-0820-2 ↗
10. Jamaludin, L., Razak, R.A., Al Bakri Abdullah, M.M., Vizureanu, P., Bras, A., Imjai, T., Sandu, A.V., Rahim, S.Z., and Yong, H.C. (2022). The suitability of photocatalyst precursor materials in geopolymer coating applications: A review. Coatings, 12.10.3390/coatings12091348 ↗
11. Davidovits, R., Pelegris, C., and Davidovits, J. (2019). Standardized method in testing commercial metakaolins for geopolymer formulations. Geopolym. Inst. Libr.
12. Erdman, V. (2020). Creating coatings based on geopolymer suspension. [Bachelor’s Thesis, Jan Evangelista Purkyně University in Ústí nad Labem, Faculty of Mechanical Engineering, Institute of Technology and Materials].
13. Břešťan, T. (2022). Evaluation of the Possibility of Creating Building Materials Using Energy by-Products. [Bachelor’s Thesis, Jan Evangelista Purkyně University in Ústí nad Labem, Faculty of Mechanical Engineering, Institute of Technology and Materials].
14. Vickers, L., Riessen, v.A., and Rickard, W.D.A. (2015). Fire-Resistant Geopolymers Role of Fibres and Fillers to Enhance Thermal Properties, Springer.10.1007/978-981-287-311-8 ↗
15. Amritphale, S.S., Bhardwaj, P., and Gupta, R. (2020). Advanced Geopolymerization Technology. Geopolymers and Other Geosynthetics, IntechOpen.10.5772/intechopen.87250 ↗
16. Wang, A., Fang, Y., Zhou, Y., Wang, C., Dong, B., and Chen, C. (2022). Green Protective Geopolymer Coatings: Interface Characterization, Modification and Life-Cycle Analysis. Materials, 15.10.3390/ma15113767 ↗
17. Cirstea, N.F., Badanoiu, A., and Boscornea, A.C. (2022). Intumescent Silicate Coatings with the Addition of Alkali-Activated Materials. Polymers, 14.10.3390/polym14101937 ↗
18. Akeed, M.H. (2022). Mine Tailings-based Geopolymers: Durability, Microstructure, Thermal and Leaching Properties, ScienceOpen Preprints.10.14293/S2199-1006.1.SOR-.PPCAF1O.v1 ↗
19. Hydrophobic Modification of a Slag-based Geopolymer Coating10.1088/1755-1315/783/1/012015 ↗
20. Multifaceted geopolymer coating: Material development, characterization and study of long term anti-corrosive properties10.1016/j.micromeso.2021.110995 ↗
21. Machovský, T. (2009). Testing the Reactivity of Raw Materials for Geopolymerization. [Master’s Thesis, Jan Evangelista Purkyně University in Ústí nad Labem, Faculty of Mechanical Engineering, Institute of Technology and Materials].
22. Thermal properties of spray-coated geopolymer-type compositions10.1007/s10973-011-1766-4 ↗
23. Subaer The thermal properties of metakaolin geopolymer coated with MgO particles10.1063/1.5118100 ↗
24. Thermal behaviour of inorganic geopolymers and composites derived from sodium polysialate10.1016/S0025-5408(02)01022-X ↗
25. Thermal evolution of metakaolin geopolymers: Part 1—Physical evolution10.1016/j.jnoncrysol.2006.09.019 ↗
26. Van Riessen, A., Rickard, W., and Sanjayan, J. (2009). Thermal properties of geopolymers. Geopolymers, 315–342.10.1533/9781845696382.2.315 ↗
27. Effects of Substrate Surface Characteristics on the Adhesion Properties of Geopolymer Coatings10.1021/acsomega.2c00170 ↗
28. Characterization and Design of Alkali Activated Binder for Coating Application
29. Metakaolin-based geopolymer coatings on metals by airbrush spray deposition10.1007/s11998-019-00310-6 ↗
30. Chuchala, D., Dobrzynski, M., Pimenov, D.Y., Orlowski, K.A., Krolczyk, G., and Giasin, K. (2021). Surface Roughness Evaluation in Thin EN AW-6086-T6 Alloy Plates after Face Milling Process with Different Strategies. Materials, 14.10.3390/ma14113036 ↗
31. Residual Stress Distribution through Thickness in Cold-Rolled Aluminum Sheet10.4028/www.scientific.net/KEM.622-623.1000 ↗
32. Chemical characterisation of the steel-geopolymeric gel interface. Colloid Surfaces10.1016/j.colsurfa.2007.03.004 ↗
33. Fly ash based geopolymer thin coatings on metal substrates and its thermal evaluation10.1016/j.jhazmat.2010.04.121 ↗
34. Preparation of metakaolin based geopolymer coatings on metal substrates as thermal barriers10.1016/j.clay.2009.08.015 ↗
35. Geopolymer: A review on physical properties of inorganic aluminosilicate coating materials10.4028/www.scientific.net/MSF.803.367 ↗
36. Preparation and thermal properties of fire resistant metakaolin-based geopolymer-type coatings10.1016/j.jnoncrysol.2010.09.063 ↗
37. Leiva, C., Vilches, L.F., Querol, X., Vale, J., and Fernandez, C.P. (2007). Use of Zeolitised Fly Ashes in Fire Resistant Plates. Proceedings of the World of Coal Ash: Science, Applications and Sustainability, World of Coal Ash.
38. Development of new fire-proof products made from coal fly ash: The CEFYR project10.1002/jctb.592 ↗
39. (1978). AlMgSi. Standard No. EN AW 6060.
40. (2022, October 25). Nedal Aluminium. Available online: https://www.nedal.com/wp-content/uploads/2019/07/NEDAL_Datasheet-6060.pdf.
41. Durability properties of geopolymer concrete produced with recycled coarse aggregates and quarry stone dust
42. Study on properties and morphology of kaolin based geopolymer coating on clay substrates
43. Effect of Geopolymer Coating on Mild Steel10.4028/www.scientific.net/SSP.273.175 ↗
44. A Review on the Immobilization of Heavy Metals with Geopolymers10.4028/www.scientific.net/AMR.634-638.173 ↗
45. Durability of geopolymers and geopolymers concretes: A review10.1515/rams-2021-0002 ↗
46. Optimization studies and characterization of advanced geopolymer coatings for the fabrication of mild steel substrate by spin coating technique
47. Review on the Adhesion of Geopolymer Coatings10.1021/acsomega.0c06343 ↗
48. Jiang, C., Wang, A., Bao, X., Chen, Z., Ni, T., and Wang, Z. (2020). Protective Geopolymer Coatings Containing Multi-Componential Precursors: Preparation and Basic Properties Characterization. Materials, 13.10.3390/ma13163448 ↗
49. Novotný, J., Hren, I., Michna, Š., and Legutko, S. (2022). Analysis of Composite Coating of Deep Drawing Tool. Coatings, 12.10.3390/coatings12060863 ↗
50. Layered compounds of alkali metals in graphite in fine organic synthesis10.1070/RC1990v059n08ABEH003552 ↗
51. Substrate hardness dependency on properties of Al2O3 thick films grown by aerosol deposition10.1016/j.surfcoat.2012.08.012 ↗
52. (2022, September 30). DIL L75 PT Vertical. Available online: https://www.linseis.com/en/products/dilatometer/dil-l75-pt-vertical/.