journal article·2021-02-22Open access

Synthesis and Frost Suppression Performance of PDMS-SiO2/PFA Hybrid Coating

Li Jia, Jun Sun, Xiaoxiao Li, Xian Zhang, Lin Chen, Xinyou Tian

Coatings· Volume 11· Issue 2

Abstract

In this article, a simple synthesis method was applied to form a branch and tendril structure using hydroxyl-terminated silicone sol modified silica nanoparticles at high temperature, followed by mixing with fluoro-containing polyacrylate emulsion (PFA) to obtained a polydimethylsiloxane (PDMS)-SiO2/PFA hybrid coating. The hydrophobic performance of the PDMS-SiO2/PFA coating was further enhanced through the synergistic action of Si-O and F group. The obtained coating has a similar surface structure of lotus leaf and the contact angle can reach 142.2 ± 2.4°. The PDMS-SiO2/PFA coating could delay the formation of frost crystal and the growth of frost layer. The defrosting droplets were difficult to adhere on the coating and could be easily rolled off for long frosting and defrosting cycles, which indicates the potential application of this coating in the field of frost suppression.
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Research context

OpenAlex topics: Surface Modification and Superhydrophobicity · Aerogels and thermal insulation · Polymer Nanocomposites and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Lab of Photovoltaic and Energy Conservation Materials, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences, Hefei 230031, China

University of Science and Technology of China, Hefei 230026, China

References (39)

Show source-provided references
1. The heat transfer-on tubes with free flow taking into account the formation of condensation and mature
2. Mechanism of supercooled droplet freezing on surfaces10.1038/ncomms1630 ↗
3. Energy-effective frost-free coatings based on superhydrophobic aligned nanocones10.1021/am502607e ↗
4. Preparation and anti-icing behavior of superhydrophobic surfaces on aluminum alloy substrates10.1021/la400979d ↗
5. Regulating water adhesion on superhydrophobic TiO2 nanotube arrays10.1002/adfm.201401462 ↗
6. Ice-phobic gummed tape with nano-cones on microspheres10.1039/c3ta14779g ↗
7. Adhesion of ice to coatings and the performance of ice release coatings
8. Effect of wettability and surface roughness on ice-adhesion strength of hydrophilic, hydrophobic and superhydrophobic surfaces10.1016/j.apsusc.2014.06.101 ↗
9. Reducing ice adhesion on nonsmooth metallic surfaces: Wettability and topography effects10.1021/acsami.6b00187 ↗
10. Reducing ice adhesion by hierarchical micro-nano-pillars10.1016/j.apsusc.2014.03.139 ↗
11. Exploiting topographical texture to impart icephobicity10.1021/nn103214q ↗
12. Development of a transparent and ultrahydrophobic glass plate10.1143/JJAP.32.L614 ↗
13. Patterned superhydrophobic metallic surfaces10.1021/la8037582 ↗
14. Influence of different chemical modifications on the icephobic properties of superhydrophobic surfaces in a condensate environment10.1039/C4TA07077A ↗
15. Reinforced superhydrophobic coating on silicone rubber for longstanding anti -icing performance in severe conditions10.1021/acsami.7b05549 ↗
16. Icephobic/anti-icing properties of micro/nanostructured surfaces10.1002/adma.201104412 ↗
17. Design of ice-free nanostructured surfaces based on repulsion of impacting water droplets10.1021/nn102557p ↗
18. Robust anti-icing performance of a flexible superhydrophobic surface10.1002/adma.201602480 ↗
19. Oil-infused superhydrophobic silicone material for low ice adhesion with long-term infusion stability10.1021/acsami.6b11184 ↗
20. Bioinspired solid organogel materials with a regenerable sacrificial alkane surface layer10.1002/adma.201700865 ↗
21. Fabrication and characterization of stable superhydrophobic fluorinated-polyacrylate/silica hybrid coating10.1016/j.apsusc.2014.01.164 ↗
22. Synthesis, film morphology, and performance of cationic fluorinated polyacrylate emulsion with core-shell structure10.1002/app.36477 ↗
23. Effects of nano-fluorocarbon coating on icing10.1016/j.apsusc.2012.04.043 ↗
24. Robust anti-icing superhydrophobic aluminum alloy surfaces by grafting fluorocarbon molecular chains10.1016/j.apmt.2020.100815 ↗
25. Jia, L., Sun, J., Li, X.X., Zhang, X., Chen, L., and Tian, X.Y. (2020). Preparation and anti-frost performance of PDMS-SiO2/SS superhydrophobic coating. Coatings, 10.10.3390/coatings10111051 ↗
26. Synthesis of UV crosslinkable waterborne siloxane-polyurethane dispersion PDMS-PEDA-PU and the properties of the films10.1007/s11998-007-9062-8 ↗
27. Synthesis of core-shell fluoroacrylate copolymer latex via emulsion polymerization and its application in ink-jet ink10.1002/app.36679 ↗
28. Surface properties and chain structure of fluorinated acrylate copolymers prepared by emulsion polymerization10.1007/s00289-009-0193-1 ↗
29. Surface and mechanical properties of hydrophobic silica contained hybrid films of waterborne polyurethane and fluorinated polymethacrylate10.1016/j.polymer.2013.11.019 ↗
30. A review of the recent advances in superhydrophobic surfaces and the emerging energy-related applications10.1016/j.energy.2015.01.061 ↗
31. Wettability of porous surfaces10.1039/tf9444000546 ↗
32. Resistance of solid surfaces to wetting by water10.1021/ie50320a024 ↗
33. Surface roughness and contact angle10.1021/j150474a015 ↗
34. Contact angles10.1039/df9480300011 ↗
35. Robust prototypical anti-icing coatings with a self-lubricating liquid water layer between ice and substrate10.1021/am401004t ↗
36. A fundamental understanding of factors affecting frost nucleation10.1016/S0017-9310(03)00194-7 ↗
37. Condensation heat transfer on superhydrophobic surfaces10.1557/mrs.2013.103 ↗
38. Review of the vapour pressures of ice and supercooled water for atmospheric applications10.1256/qj.04.94 ↗
39. Modus operandi of protective and anti-icing mechanisms underlying the design of longstanding outdoor icephobic coatings10.1021/acsnano.8b09549 ↗