Novel Coatings on Zirconia for Improved Bonding with Veneer Ceramics

This study aimed to compare the effects of two surface-coating methods on the shear bond strength (SBS) of veneering ceramics (VC) to zirconia. Eighty pre-sintered zirconia cubes were randomly assigned into four study groups: E60S, E60P, N60S, and N60P. The zirconia surface was coated with a mixture of two types of glaze and alumina (<60 μm) by airbrush spraying and fine- brush painting. Surface roughness (Ra), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and SBS measurements (both initial and artificial aged conditions, including one month of water storage) were performed. The Ra results revealed significant differences among all groups (p < 0.001). The N60P group exhibited higher values of Ra (5.717 ± 0.20 µm) and SBS before and after water storage with values of 37.22 ± 4.954 MPa and 34.42 ± 3.977 MPa, respectively. The fine-brush coatings showed significantly higher SBS than that of airbrush coatings, in both initial and artificial conditions. Both coating methods and various coating materials (p < 0.001) produced a significant influence on VC-zirconia SBS. A significant correlation between Ra and SBS (Spearman’s rho = 0.808; p < 0.001) was found. The novel coating by fine-brush painting is a promising surface treatment and an easy technique for obtaining a rougher surface, which subsequently improves the bond strength to VC.