Corrosion Resistance of a Plasma-Oxidized Ti6Al4V Alloy for Dental Applications
Source abstract
Abstract
A Ti6Al4V alloy was plasma-oxidized at 600 °C during 1, 2, 3, 5 and 8 h and corroded in an artificial saliva solution. Electrochemical evaluation was performed by using potentiodynamic polarization curves, linear polarization resistance (LPR), and electrochemical impedance spectroscopy (EIS) measurements during 100 h. Corroded specimens were characterized by using Raman spectroscopy and scanning electronic microscopy (SEM). All tests indicated that the highest corrosion resistance was obtained for specimen oxidized during 3 h since the noblest free corrosion potential, lowest passive and corrosion current density values, as well as the highest polarization resistance values were obtained under these circumstances. EIS measurements indicated that the highest impedance and phase angle values obtained for this specimen exhibited a high capacitive behavior typical of a very compact passive film.
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Research context
OpenAlex topics: Titanium Alloys Microstructure and Properties · Corrosion Behavior and Inhibition · Hydrogen embrittlement and corrosion behaviors in metals
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Center for Research in Engineering and Applied Sciences, Autonomous University of the State of Morelos, Cuernavaca 62209, Mexico
Department of Chemical Engineering and Metallurgy, University of Sonora, Hermosillo 83000, Mexico
Institute of Physics, National Autonomous University of Mexico, Cuernavaca 62209, Mexico
Faculty of Chemical Sciences and Engineering, Autonomous University of the State of Morelos, Cuernavaca 62209, Mexico
Division of Industrial Mechanics, Emiliano Zapata Technological University of the State of Morelos, Emiliano Zapata 62565, Mexico
References (51)
Show source-provided references
1. Leyens, C., and Perters, M. (2003). Titanium and Titanium Alloys: Fundamentals and Applications, Wiley-VCH.10.1002/3527602119 ↗
2. The use of titanium in family automobiles: Current trends10.1007/s11837-001-0143-3 ↗
3. Titanium in the family automobile: The cost challenge10.1007/s11837-004-0144-0 ↗
4. Titanium for aerospace: Rationale and applications10.1007/BF00705316 ↗
5. The use of titanium for medical applications in the USA10.1016/0921-5093(96)10243-4 ↗
6. Mechanical properties and microstructures of low cost β titanium alloys for healthcare applications10.1016/j.msec.2004.12.015 ↗
7. Titanium in Dentistry: Historical Development, State of the Art and Future Perspectives10.1007/s13191-012-0190-1 ↗
8. The additive manufacturing (AM) of titanium alloys10.1016/j.mprp.2016.12.062 ↗
9. A peptide-based biological coating for enhanced corrosion resistance of titanium alloy biomaterials in chloride-containing fluids10.1177/0885328217692949 ↗
10. Chávez-Díaz, M.P., Escudero-Rincón, M.L., Arce-Estrada, E.M., and Cabrera-Sierra, R. (2017). Osteoblast Cell Response on the Ti6Al4V Alloy Heat-Treated. Materials, 10.10.3390/ma10040445 ↗
11. Influence of hot deformation on the electrochemical behavior of natural oxides of hipped Ti6Al4V10.1016/j.corsci.2015.01.042 ↗
12. Tribological, electrochemical and tribo-electrochemical characterization of bare and nitrided Ti6Al4V in simulated body fluid solution10.1016/j.corsci.2011.01.057 ↗
13. Influence of regulated modification of nitride layer by oxygen on the electrochemical behavior of Ti–6Al–4V alloy in the Ringer’s solution10.1002/maco.201911018 ↗
14. Electrochemical evaluation of Ti-13Nb-13Zr, Ti-6Al-4V and Ti-6Al-7Nb alloys for biomedical application by long-term immersion tests10.1002/maco.200604027 ↗
15. Corrosion characterization of titanium alloys by electrochemical techniques10.1016/j.electacta.2005.02.121 ↗
16. Degradation characteristics of hydroxyapatite coatings on orthopaedic TiAlV in simulated physiological media investigated by electrochemical impedance spectroscopy10.1016/S0142-9612(03)00362-4 ↗
17. Cao, L., Wan, Y., Yang, S., and Pu, J. (2018). The Tribocorrosion and Corrosion Properties of Thermally Oxidized Ti6Al4V Alloy in 0.9 wt.% NaCl Physiological Saline. Coatings, 8.10.3390/coatings8080285 ↗
18. Electrochemical studies on the stability and corrosion resistance of titanium-based implant materials10.1016/S0142-9612(00)00309-4 ↗
19. Corrosion behaviour of low-cost Ti–4.5Al–xV–yFe alloys in sodium chloride and sulphuric acid solutions10.1080/1478422X.2019.1654218 ↗
20. Torsional fretting corrosion behaviours of Ti6Al4V alloys in Hank’s simulated body fluid10.1080/1478422X.2019.1589675 ↗
21. Electrochemical corrosion properties of Ti–6Al–4V implant alloy in the biological environment10.1016/j.msea.2004.03.069 ↗
22. Effect of Nb on oxidation behavior of high Nb containing TiAl alloys10.1016/j.intermet.2010.08.029 ↗
23. First-principles investigation of the alloying effect of Ta and W on γ-TiAl10.1007/s11434-006-2183-0 ↗
24. The role of chromium in protective alumina scale formation during the oxidation of ternary TiAlCr alloys in air10.1016/j.intermet.2003.09.014 ↗
25. Oxidation behavior of a high Si content AleSi composite coating fabricated on Tie6Ale4V substrate by mechanical alloying method10.1016/j.jallcom.2017.01.078 ↗
26. Plasma niobium surface alloying of pure titanium and its oxidation at 900 °C10.1016/S1000-9361(07)60015-6 ↗
27. Microstructure and properties of Ti-Al coating and Ti-Al-Si system coatings on Ti-6Al-4V fabricated by laser surface alloying10.1016/j.surfcoat.2016.10.082 ↗
28. Deposition and characterization of titanium aluminum nitride coatings prepared by RF magnetron sputtering10.1016/j.apsusc.2015.02.053 ↗
29. Bahi, R., Nouveau, C., Beliardouh, N., Ramoul, C., Meddah, S., and Ghelloudj, O. (2020). Surface performances of Ti-6Al-4V substrates coated PVD multilayered films in biological environments. Surf. Coatings Technol., 385.10.1016/j.surfcoat.2020.125412 ↗
30. Corrosion of Ti6Al4V pins produced by direct metal laser sintering10.1016/j.apsusc.2016.10.031 ↗
31. Porous TiO2 film prepared by micro-arc oxidation and its electrochemical behaviors in Hank’s solution10.1016/j.surfcoat.2010.09.058 ↗
32. Influence of shallow and deep cryogenic treatment on the corrosion behavior of Ti6Al4V alloy in isotonic solution10.1002/maco.201911378 ↗
33. Corrosion behavior of TiO2-coated Ti-6Al-7Nb surfaces obtained by anodic oxidation in sulfuric or acetic acid10.1002/maco.201407687 ↗
34. Jia, Q., Li, D., Li, S., Zhang, Z., and Zhang, N. (2018). High-Temperature Oxidation Resistance of NiAl Intermetallic Formed In Situ by Thermal Spraying. Coatings, 8.10.3390/coatings8080292 ↗
35. Zhou, H., and Peng, C. (2021). Effect of Shroud in Plasma Spraying on Chemical Composition and Thickness of Titanium Coatings. Coatings, 11.10.3390/coatings11040446 ↗
36. Low-temperature nitriding of nanocrystalline Inconel 718 alloy10.1016/j.surfcoat.2017.09.040 ↗
37. Corrosion behavior of pre-oxidized and thermally nitrided stainless steel for polymer electrolyte membrane fuel cell bipolar plates10.1016/j.corsci.2012.01.014 ↗
38. Wear and corrosion properties of AISI 420 martensitic stainless steel treated by active screen plasma nitriding10.1016/j.surfcoat.2017.09.021 ↗
39. Study of plasma nitriding and nitrocarburizing for higher corrosion resistance and hardness of 2205 duplex stainless steel10.1016/j.corsci.2015.07.014 ↗
40. Surface characterization of plasma sprayed pure and reinforced hydroxyapatite coating on Ti6Al4V alloy10.1016/j.surfcoat.2011.04.064 ↗
41. Effect of laser surface texturing (LST) on tribological behavior of double glow plasma surface zirconizing coating on Ti6Al4V alloy10.1016/j.surfcoat.2019.04.038 ↗
42. Characterization and corrosion behavior of hydroxyapatite coatings on Ti6Al4V fabricated by electrophoretic deposition10.1016/j.apsusc.2009.02.086 ↗
43. Dipcoating of poly (ε-caprolactone)/hydroxyapatite composite coating on Ti6Al4V for enhanced corrosion protection10.1016/j.surfcoat.2014.02.048 ↗
44. Sobolev, A., Zinigrad, M., and Borodiansky, K. (2021). Ceramic coating on Ti-6Al-4V by plasma electrolytic oxidation in molten salt: Development and characterization. Surf. Coat. Technol., 408.10.1016/j.surfcoat.2021.126847 ↗
45. Lupi, S.M., Galinetto, P., Albini, B., Di Ronza, E., Rizzo, S., and Rodriguez Baena, R. (2020). Micro-raman spectroscopy of dental Implants subjected to deferent surface treatments. Appl. Sci., 10.10.3390/app10072417 ↗
46. Structural and optical characterization of the crystalline phase transformation of electrospinning TiO2 nanofibres by high-temperatures annealing10.31349/RevMexFis.65.459 ↗
47. Raman spectra of titanium dioxide10.1016/0022-4596(82)90006-8 ↗
48. Investigation of structural transformations in nanophase titanium dioxide by Raman spectroscopy10.1007/s003390050723 ↗
49. Inhibiting effect of 2-mercaptobenzimidazole on the corrosion of Cu–30Ni alloy in aerated 3% NaCl in presence of ammonia10.1016/j.corsci.2007.03.017 ↗
50. Effects of solution treatment and aging on the microstructure, mechanical properties, and corrosion resistance of a β type Ti–Ta–Hf–Zr alloy10.1039/C6RA28464G ↗
51. Electrochemical impedance spectroscopy characterization of passive film formed on implant Ti–6Al–7Nb alloy in Hank’s solution10.1023/B:JMSM.0000010097.86245.74 ↗