journal article·2021-07-26Open access

Study on the Characteristics of a TBC System Containing a PVD-Al Interlayer under Isothermal Loading

Ibrahim Ali, Paweł Sokołowski, Lech Pawłowski, Daniel Wett, Thomas Grund, Thomas Lampke

Coatings· Volume 11· Issue 8

Abstract

In this work, the oxidation behavior of an atmospheric plasma-sprayed thermal barrier coating (TBC) system with a thin Al physical vapor deposition (PVD) film deposited over the bond coat is discussed. The TBC consisted of: (i) CoNiCrAlY bond coat sprayed on the Inconel 600 substrate; (ii) a thin Al interlayer deposited by direct current DC magnetron sputtering; and (iii) yttria-stabilized zirconia (YSZ) sprayed as the top coat. Such thermal barrier coatings (Al-TBC) were isothermally oxidized at 1150 °C with different holding times, and then they were compared with the reference TBC (R-TBC) systems without an Al interlayer (R-TBC). Scanning electron microscopy with energy-dispersive X-ray analysis was used to study the oxide formation along the bond coat (BC) and top coat (TC) interface, as well as crack formation in the yttria-stabilized zirconia top coat. Then, using Image Analysis, the oxide formation and crack formation were characterized in all specimens after a slow heating and cooling cycle, and after 100, 300, and 600 h of isothermal exposure. The results showed that the Al-TBC system proposed here exhibits higher oxidation resistance at the bond coat and top coat interface, less crack formation in the YSZ top coat, and enhanced mechanical stability compared to the conventional TBCs. It was found that enrichment of the bond coat and top coat interface with Al limited the formation of detrimental transition metal oxides during isothermal loading. Finally, the corresponding failure caused by thermally grown oxide (TGO) phenomena is “mixed failure mode” for both studied TBCs.
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Research context

OpenAlex topics: High-Temperature Coating Behaviors · Advanced materials and composites · Nuclear Materials and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Technology Repair Services (MSAT), MTU Maintenance Hannover GmbH, Muenchner Straße 31, 30855 Langenhagen, Germany

Department of Metal Forming, Welding and Metrology, Faculty of Mechanical Engineering, Wroclaw University of Science and Technology, Wyb. Wyspianskiego 27, 50-370 Wroclaw, Poland

IRCER UMR CNRS 7315, University of Limoges, 87068 Limoges, France

Department of Corrosion Protection and Process Engineering, Institute for Corrosion Protection (IKS) Dresden GmbH, Gostritzer Straße 65, 01217 Dresden, Germany

Materials and Surface Engineering Group, Institute of Materials Science and Engineering, Chemnitz University of Technology, 09111 Chemnitz, Germany

Funding

Narodowe Centrum Nauki

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