journal article·2021-07-26Open access

Preparation and Properties of Multilayer Ca/P Bio-Ceramic Coating by Laser Cladding

Boda Liu, Zixin Deng, Defu Liu

Coatings· Volume 11· Issue 8

Abstract

In order to enhance the bioactivity and wear resistance of titanium (Ti) and its alloy for use as an implant surface, a multilayer Ca/P (calcium/phosphorus) bio-ceramic coating on a Ti6Al4V alloy surface was designed and prepared by a laser cladding technique, using the mixture of hydroxyapatite (HA) powder and Ti powder as a cladding precursor. The main cladding process parameters were 400 W laser power, 3 mm/s scanning speed, 2 mm spot diameter and 30% lapping rate. When the Ca/P ceramic coating was immersed in simulated body fluid (SBF), ion exchange occurred between the coating and the immersion solution, and hydroxyapatite (HA) was induced and deposited on its surface, which indicated that the Ca/P bio-ceramic coating had good bioactivity. The volume wear of Ca/P ceramic coating was reduced by 43.2% compared with that of Ti6Al4V alloy by the pin-disc wear test, which indicated that the Ca/P bio-ceramic coating had better wear resistance.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Bone Tissue Engineering Materials · Titanium Alloys Microstructure and Properties · High Entropy Alloys Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Mechanical and Electrical Engineering, Central South University, Changsha 410083, China

State Key Laboratory of High Performance Complex Manufacturing, Changsha 410083, China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Hunan Province · State Key Laboratory of High Performance Complex Manufacturing

References (46)

Show source-provided references
1. Luo, Y., Yang, L., and Tian, M. (2013). Application of Biomedical-Grade Titanium Alloys in Trabecular Bone and Artificial Joints, John Wiley & Sons.10.1533/9780857092205.181 ↗
2. Avila, J., Bose, S., and Bandyopadhyay, A. (2018). Additive manufacturing of titanium and titanium alloys for biomedical applications. Titanium in Medical and Dental Applications, Elsevier.10.1016/B978-0-12-812456-7.00015-9 ↗
3. An updated review on surface functionalisation of titanium and its alloys for implants applications10.1016/j.matpr.2021.01.499 ↗
4. Osteolysis around total knee arthroplasty: A review of pathogenetic mechanisms10.1016/j.actbio.2013.05.005 ↗
5. Modular tibial stem use and risk of revision for aseptic loosening in cemented primary total knee arthroplasty10.1016/j.arth.2020.11.003 ↗
6. The genetic variations associated with time to aseptic loosening after total joint arthroplasty10.1016/j.arth.2019.11.004 ↗
7. Wiliams, D.F. (1989). Biomechanical considerations in the loosening of hip replacement prosthesis. Current Perspectives on Implantable Devices, JAI Press Inc.
8. Ti based biomaterials, the ultimate choice for orthopaedic implants—A review10.1016/j.pmatsci.2008.06.004 ↗
9. Laser cladding of bioactive glass coating on pure titanium substrate with highly refined grain structure10.1016/j.jmbbm.2021.104519 ↗
10. Synthesis and characterization of wollastonite (CaSiO3)/titanium oxide (TiO2) and hydroxyapatite (HA) ceramic composites for bio-medical applications fabricated by spark plasma sintering technology10.1016/j.matpr.2020.10.1007 ↗
11. Laser processing of bioactive tricalcium phosphate coating on titanium for load-bearing implants10.1016/j.actbio.2007.09.008 ↗
12. Argon atmospheric plasma sprayed hydroxyapatite/Ti composite coating for biomedical applications10.1016/j.surfcoat.2012.07.009 ↗
13. Coating of hydroxyapatite films on metal substrates by seeded hydrothermal deposition10.1016/j.surfcoat.2011.02.008 ↗
14. Comparison of osteoconduction, cytocompatibility and corrosion protection performance of hydroxyapatite-calcium hydrogen phosphate composite coating synthesized in-situ through pulsed electro-deposition with varying amount of phase and crystallinity10.1016/j.surfin.2017.11.002 ↗
15. Microstructures, hardness and bioactivity of hydroxyapatite coatings deposited by direct laser melting process10.1016/j.msec.2014.06.032 ↗
16. Structural evaluation, preliminary in vitro stability and electrochemical behavior of apatite coatings on Ti6Al4V substrates10.1016/j.ceramint.2016.08.141 ↗
17. Influence of Ag/Ca ratio on the osteoblast growth and antibacterial activity of TiN coatings on Ti-6Al-4V by Ag and Ca ion implantation10.1016/j.surfcoat.2020.126415 ↗
18. Effect of bioglass addition on the properties of HA/BG composite films fabricated by pulsed laser deposition10.1016/j.ceramint.2018.05.069 ↗
19. Investigation of functionally graded HA-TiO2 coating on Ti–6Al–4V substrate fabricated by sol-gel method10.1016/j.ceramint.2019.05.317 ↗
20. Structure, morphology, adhesion and in vitro biological evaluation of antibacterial multi-layer HA-Ag/SiO2/TiN/Ti coatings obtained by RF magnetron sputtering for biomedical applications10.1016/j.msec.2020.111268 ↗
21. Improvement of surface properties and corrosion resistance of Ti13Nb13Zr titanium alloy by plasma-sprayed HA/ZnO coatings for biomedical applications10.1016/j.matchemphys.2020.123738 ↗
22. Recent research and development status of laser cladding: A review10.1016/j.optlastec.2021.106915 ↗
23. Effect of Na2O and ZnO on the microstructure and properties of laser cladding derived CaO-SiO2 ceramic coatings on titanium alloys10.1016/j.jcis.2021.02.064 ↗
24. Laser cladding with HA and functionally graded TiO2-HA precursors on Ti–6Al–4V alloy for enhancing bioactivity and cyto-compatibility10.1016/j.surfcoat.2018.08.044 ↗
25. The controllable lanthanum ion release from Ca-P coating fabricated by laser cladding and its effect on osteoclast precursors10.1016/j.msec.2018.08.059 ↗
26. Osteoblast interaction with laser cladded HA and SiO2-HA coatings on Ti–6Al–4V10.1016/j.msec.2011.07.009 ↗
27. Functionally graded carbon nanotubes/hydroxyapatite composite coating by laser cladding10.1016/j.surfcoat.2011.03.036 ↗
28. Plasma sprayed hydroxyapatite coatings on titanium substrates Part 1: Mechanical properties and residual stress levels10.1016/S0142-9612(98)00103-3 ↗
29. Multiphysics simulation of laser–material interaction during laser powder depositon10.1007/s00170-011-3571-4 ↗
30. Preparation and assessment of revised simulated body fluids10.1002/jbm.a.10482 ↗
31. Preparation of SBF with different HCO3− content and its influence on the composition of biomimetic apatites10.1016/j.actbio.2005.11.001 ↗
32. Bioactive calcium pyrophosphate glasses and glass-ceramics10.1016/j.actbio.2004.08.001 ↗
33. Bio-active glass coatings manufactured by thermal spray: A status report10.1016/j.jmrt.2019.07.011 ↗
34. CaTiO3 nanobricks prepared from anodized TiO2 nanotubes10.1016/j.elecom.2012.05.012 ↗
35. CaTiO3/α-TCP coatings on CP-Ti prepared via electrospinning and pulsed laser treatment for in-vitro bone tissue engineering10.1016/j.surfcoat.2020.126256 ↗
36. Compositionally graded hydroxyapatite/tricalcium phosphate coating on Ti by laser and induction plasma10.1016/j.actbio.2010.09.016 ↗
37. Calcium phosphate coatings obtained by Nd: YAG laser cladding: Physicochemical and biologic properties
38. Ye, D. (2002). Manual of Practical Inorganic Thermodynamics Data, Metallurgical Industry Press.
39. Controlling cellular volume via mechanical and physical properties of substrate10.1016/j.bpj.2017.11.3785 ↗
40. Wettability and kinetics of hydroxyapatite precipitation on a laser-textured Ca-P bioceramic coating10.1016/j.actbio.2009.03.004 ↗
41. Theoretical analysis of calcium phosphate precipitation in simulated body fluid10.1016/j.biomaterials.2004.05.034 ↗
42. Mechanism of apatite formation on a poorly crystallized calcium phosphate in a simulated body fluid (SBF) at 37 °C10.1016/j.jpcs.2021.110122 ↗
43. Structure and formation of amorphous calcium phosphate and its role as surface layer of nanocrystalline apatite: Implications for bone mineralization10.1016/j.mtla.2021.101107 ↗
44. Solubility study at high phosphorus pentoxide concentration in ternary system CaCO3 + P2O5 + H2O at 25, 35 and 70 °C10.1016/j.fluid.2018.09.006 ↗
45. Novel bi-layered nanostructured SiO2/Ag-FHAp coating on biodegradable magnesium alloy for biomedical applications10.1016/j.ceramint.2016.04.119 ↗
46. Physical meaning of the wear volume equation for nitrogenated diamond-like carbon based on energy considerations10.1016/j.wear.2016.09.013 ↗