journal article·2023-06-30Open access

The Influence of Different Types of Expandable Graphite on the Thermal Resistance of Spruce Wood

Elena Kmeťová, Danica Kačíková, Tereza Jurczyková, František Kačík

Coatings· Volume 13· Issue 7

Abstract

In order to not limit the possibilities of using wood due to its flammability, the implementation of fire protection is an essential requirement. An integral part of the research on the fire protection of wood is the determination of the effectiveness of the applied protective means and their effect on changing its behavior under fire conditions. In this work, samples of spruce wood (Picea abies (L.) H. Karst) (50 mm × 40 mm × 10 mm) were treated with an aqueous solution of sodium silicate and different types of expandable graphite flakes that were applied to the surface of the samples. The fire characteristics of the samples were studied using a non-standard test method, the radiant heat source test, which was used to determine the mass loss, burning rate, and ignition time of the test samples, and the measurement was carried out via visual recording with a thermal camera. The results of the laboratory test method showed a significant positive effect of the application of all types of expandable graphite flakes. The main insight is that a suitable wood modification using expandable graphite flakes in combination with water glass has the potential to reduce mass loss by at least 73 ± 3% and reduce the temperature rise on the surface of the sample. The lower temperature of the surface of the burning material reduces the possibility of heat transfer to the surrounding materials and thus reduces the rate of fire spread.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Flame retardant materials and properties · Natural Fiber Reinforced Composites · Lignin and Wood Chemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Fire Protection, Faculty of Wood Sciences and Technology, Technical University in Zvolen, 96001 Zvolen, Slovakia

Department of Wood Processing and Biomaterials, Faculty of Forestry and Wood Sciences, Czech University of Life Sciences Prague, Kamýcka 129, 16000 Prague, Czech Republic

Department of Chemistry and Chemical Technology, Faculty of Wood Sciences and Technology, Technical University in Zvolen, 96001 Zvolen, Slovakia

Funding

Slovak Research and Development Agency (Bratislava, Slovakia) · VEGA Agency of Ministry of Education, Science, Research and Sport of the Slovak Republic

References (32)

Show source-provided references
1. Trends in bioconversion of lignocellulose: Biofuels, platform chemicals and biorefinery concept10.1016/j.pecs.2012.02.002 ↗
2. Ferrari, F., Striani, R., Fico, D., Alam, M.M., Greco, A., and Esposito Corcione, C. (2022). An Overview on Wood Waste Valorization as Biopolymers and Biocomposites: Definition, Classification, Production, Properties and Applications. Polymers, 14.10.3390/polym14245519 ↗
3. Enhancing product selectivity in biomass and bioalcohol reactions over Cu-doped porous metal oxides10.1016/bs.adioch.2020.12.001 ↗
4. Sjöström, E. (1993). Wood Chemistry, Fundamentals and Applications, Academic Press. [2nd ed.].
5. A compressive review on biomass torrefecation
6. Lignin–carbohydrate complexes: Properties, applications, analyses, and methods of extraction: A review10.1186/s13068-018-1262-1 ↗
7. Špilák, D., and Majlingová, A. (2022). Progressive Methods in Studying the Charred Layer Parameters Change in Relation to Wood Moisture Content. Polymers, 14.10.3390/polym14224997 ↗
8. Flame retardancy of clay-sodium silicate composite coatings on wood for construction purposes10.1039/C5RA04682C ↗
9. Recent developments in flame retardant polymeric coatings10.1016/j.porgcoat.2013.07.014 ↗
10. Treatments and modification to improve the reaction to fire of wood and wood based products—An overview10.1002/fam.2779 ↗
11. Characterisation of the fire behaviour of wood: From pyrolysis to fire retardant mechanisms10.1007/s10973-022-11442-0 ↗
12. Flammability behaviour of wood and a review of the methods for its reduction10.1186/2193-0414-2-4 ↗
13. Kačíková, D., Kubovský, I., Eštoková, A., Kačík, F., Kmeťová, E., Kováč, J., and Ďurkovič, J. (2021). The Influence of Nanoparticles on Fire Retardancy of Pedunculate Oak Wood. Nanomaterials, 11.10.3390/nano11123405 ↗
14. Nageswara Rao, T., Naidu, T.M., Kim, M.S., Parvatamma, B., Prashanthi, Y., and Heun Koo, B. (2020). Influence of zinc oxide nanoparticles and char forming agent polymer on flame retardancy of intumescent flame retardant coatings. Nanomaterials, 10.10.3390/nano10010042 ↗
15. Jin, E., and Chung, Y.J. (2023). Assessment of the fire risk rating for wood specimens coated with titanium dioxide/talc/water glass mixtures. Eur. J. Wood Prod.10.1007/s00107-023-01924-9 ↗
16. Current progress of biopolymer-based flame retardant10.1016/j.polymdegradstab.2022.110153 ↗
17. Use of pre-charred surfaces to improve fire performance of wood10.1016/j.firesaf.2023.103745 ↗
18. Flame Retardant Combinations with Expandable Graphite/Phosphorus/CuO/Castor Oil in Flexible Polyurethane Foams10.1021/acsapm.2c01969 ↗
19. Tomiak, F., Schneider, K., Schoeffel, A., Rathberger, K., and Drummer, D. (2022). Expandable Graphite as a Multifunctional Flame-Retarding Additive for Highly Filled Thermal Conductive Polymer Formulations. Polymers, 14.10.3390/polym14081613 ↗
20. Flame retardancy effects between expandable graphite and halloysite nanotubes in silicone rubber foam10.1039/D1RA01409A ↗
21. Flame retardant epoxy/halloysite nanotubes nanocomposite coatings: Exploring low-concentration threshold for flammability compared to expandable graphite as superior fire retardant10.1016/j.porgcoat.2018.02.005 ↗
22. Chun, K., Kim, J., and Rie, D. (2020). Thermal Characteristics of Expandable Graphite–Wood Particle Composites. Materials, 13.10.3390/ma13122732 ↗
23. Mazela, B., Batista, A., and Grześkowiak, W. (2020). Expandable Graphite as a Fire Retardant for Cellulosic Materials—A Review. Forests, 11.10.3390/f11070755 ↗
24. Synergistic effect of intumescent flame retardant and expandable graphite on mechanical and flame-retardant properties of wood flour-polypropylene composites10.1016/j.conbuildmat.2013.09.028 ↗
25. Kmeťová, E., Kačík, F., Kubovský, I., and Kačíková, D. (2022). Effect of Expandable Graphite Flakes on the Flame Resistance of Oak Wood. Coatings, 12.10.3390/coatings12121908 ↗
26. Effect of flaky graphite with different particle sizes on flame resistance of intumescent flame retardant coating10.1016/j.rinma.2020.100061 ↗
27. Wang, Y., Wang, W., Zhou, H., and Qi, F. (2022). Burning Characteristics of Ancient Wood from Traditional Buildings in Shanxi Province, China. Forests, 13.10.3390/f13020190 ↗
28. Intumescent Fireproof Coating Based on Water Glass10.1080/00914030008033339 ↗
29. Kim, J.Y. (2014). Applications and Uses of Soluble Silicates, Hanrimwon.
30. Improvement of flame-retardant performance of polyurethane foam coated with water glass10.7731/KIFSE.43a374e9 ↗
31. Flame-retardant impregnants for woods based on alkaline silicates10.1016/j.firesaf.2008.10.004 ↗
32. Fire resistance of wood impregnated with soluble alkaline silicates10.1155/2007/31956 ↗