Theoretical and Experimental Studies of 1-Dodecyl-3-phenylquinoxalin-2(1H)-one as a Sustainable Corrosion Inhibitor for Carbon Steel in Acidic Electrolyte
Source abstract
Abstract
The anti-corrosion features of 1-dodecyl-3-phenylquinoxalin-2(1H)-one (QO12) for carbon steel CS were evaluated in a 1 M HCl solution using potentiodynamic polarization (PDP), electrochemical impedance (EIS) and UV-visible spectroscopy, and scanning electron microscopy (SEM), as well as quantum-chemical methods. The inhibition performance achieves a maximum of 95.33% at 0.001 M. The PDP study revealed that QO12 acts with the character of a mixed-type inhibitor. The EISs mention that the process of corrosion for CS is essentially predominated by the transfer-of-charge mechanism. Moreover, quinoxalinone adsorption follows the Langmuir adsorption isotherm. SEM snapshots show no deterioration after the contribution of QO12 compared to the reference electrolyte. Theoretical calculations suggest that the envisaged inhibitor presents a perfect arrangement capacity through the structure of quinoxalinone.
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Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Synthesis and Biological Evaluation · Multicomponent Synthesis of Heterocycles
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Laboratory of Advanced Materials and Process Engineering, Faculty of Sciences, Ibn Tofail University, BP 242, Kenitra 14000, Morocco
Laboratory of Materials, Nanotechnology and Environment, Faculty of Sciences, Mohammed V University Rabat, Rabat 10090, Morocco
Laboratory of Medicinal Chemistry, Drug Sciences Research Center, Faculty of Medicine and Pharmacy, Mohammed V University Rabat, Rabat 10090, Morocco
Laboratory of Applied Sciences, National School of Applied Sciences (ENSAH), Abdelmalek Essaadi University, Tetouan 93000, Morocco
Laboratory of Organic Chemistry, Bioorganic and Environment, Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, El Jadida 24000, Morocco
Department of Chemistry, AN-Najah National University, Nablus P.O. Box 7, Palestine
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