journal article·2022-04-28Open access

Microstructural Transformation and High-Temperature Aluminum Corrosion Properties of Co-Based Alloy Coating Prepared by Laser Cladding

Rui Liu, Mengyu Zhang, Jiacheng Yu, Qifan Yang, Shiyou Gao

Coatings· Volume 12· Issue 5

Abstract

A Co-based alloy coating was deposited on H13 steel substrate via pulsed Nd:YAG laser and the corrosion resistance to and mechanism of corrosion in molten aluminum were explored. The results showed that the coating was mainly composed of γ-Co dendrite and M23C6 precipitation. The average hardness in the cladding layer was 732.6 HV0.5, which was 3.55 times greater than that of the H13 substrate. During the molten aluminum corrosion test, the surface of the Co-based alloy coating was immersed for 4, 8, 16 and 24 h at 700 °C. The corrosion rate decreased with increases in aluminum erosion time. It was observed that there were two intermediate layers between the coating and the liquid Al, with (Co, Fe, Cr)2Al9 intermetallic compounds (IMCs) layer near the coating side and the (Fe, Cr)4Al13 and (Co, Fe, Cr)2Al5 intermetallic compounds (IMCs) layer near the Al solidification side. After 24 h of static corrosion, the Co-based alloy coating could still maintain its integrity to protect the substrate.
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Research context

OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Additive Manufacturing Materials and Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Advanced Forging and Stamping Technology and Science, Ministry of Education, Yanshan University, Qinhuangdao 066004, China

Funding

Natural Science Foundation of Hebei Province

References (33)

Show source-provided references
1. A study of die failure mechanisms in aluminum extrusion10.1016/S0924-0136(02)01116-0 ↗
2. Effect of chromium on the formation of intermetallic phases in hot-dipped aluminide Cr–Mo steels10.1016/j.apsusc.2013.04.015 ↗
3. Chen, G., Wang, J., Wang, D., Xue, L., Zeng, B., Qin, B., and Tang, Z. (2020). Effect of liquid oxy-nitriding at various temperatures on wear and molten aluminum corrosion behaviors on AISI H13 steel. Corros. Sci., 178.10.1016/j.corsci.2020.109088 ↗
4. Laboratory assessment of wear on nitrided surfaces of dies for hot extrusion of aluminium10.1016/j.triboint.2005.09.032 ↗
5. Corrosion behavior of zirconium diboride coated stainless steel in molten 6061 aluminum alloy10.1016/j.surfcoat.2017.01.069 ↗
6. Interfacial reactions of duplex stainless steels with molten aluminum10.1002/sia.5760 ↗
7. Review on corrosion-wear resistance performance of materials in molten aluminum and its alloys10.1016/S1003-6326(15)63777-3 ↗
8. Research status of laser cladding on titanium and its alloys: A review10.1016/j.matdes.2014.01.077 ↗
9. Laser cladding of aerospace materials10.1016/S0924-0136(01)01121-9 ↗
10. Research and development status of laser cladding on magnesium alloys: A review10.1016/j.optlaseng.2017.02.007 ↗
11. Lu, P., Lewis, S.R., Fretwell-Smith, S., Engelberg, D.L., Fletcher, D.I., and Lewis, R. (2019). Laser cladding of rail; the effects of depositing material on lower rail grades. Wear, 438–439.10.1016/j.wear.2019.203045 ↗
12. Intermetallic formation and its relation to interface mass loss and tribology in die casting dies10.1016/j.wear.2003.08.001 ↗
13. Development of cermet coatings by kinetic spray technology for the application of die-soldering and erosion resistance10.1016/j.surfcoat.2009.07.033 ↗
14. Combat molten aluminum corrosion of AISI H13 steel by low-temperature liquid nitrocarburizing10.1016/j.jallcom.2018.10.298 ↗
15. Protection of carbon steel against molten aluminum attack and high temperature corrosion using high velocity oxygen-fuel WC–Co coatings10.1016/j.surfcoat.2014.12.023 ↗
16. Thermally induced microstructural transformations and anti-corrosion properties of Co70Fe5Si10B15 amorphous alloy10.1016/j.jnoncrysol.2018.08.017 ↗
17. Microstructure, Lattice misfit, and high-temperature strength of γ′-strengthened Co–Al–W–Ge model superalloys10.1007/s11661-016-3408-8 ↗
18. Microstructure and mechanical properties of Co-based alloy coatings fabricated by laser cladding and plasma arc spray welding10.1016/j.jallcom.2019.01.056 ↗
19. Microstructure and interfacial evaluation of Co-based alloy coating on copper by pulsed Nd:YAG multilayer laser cladding10.1016/j.jallcom.2010.06.099 ↗
20. Microstructure and high-temperature wear mechanism of laser cladded CoCrBFeNiSi high-entropy alloy amorphous coating10.1016/j.matlet.2017.09.056 ↗
21. High temperature wear resistance and thermal fatigue behavior of Stellite-6/WC coatings produced by laser cladding with Co-coated WC powder10.1016/j.ijrmhm.2019.02.024 ↗
22. Microstructural and mechanical characteristics of laser coatings10.1016/S0257-8972(99)00394-1 ↗
23. The gradient microstructure and high-temperature wear behavior of the cocrmosi coating by laser cladding10.1007/s11666-021-01184-0 ↗
24. Characteristics of cobalt-based alloy coating on tool steel prepared by powder feeding laser cladding10.1016/j.optlastec.2006.12.005 ↗
25. Constitutive behaviour of A356 during the quenching operation10.1016/j.msea.2004.06.004 ↗
26. Duplex ceramic coating produced by low temperature thermo-reactive deposition and diffusion on the cold work tool steel substrate: Thermodynamics, kinetics and modeling10.1016/j.ceramint.2015.03.306 ↗
27. Interfacial reaction between Co–Cr–Mo alloy and liquid Al10.1016/j.corsci.2013.06.009 ↗
28. Microstructure evolution in Fe-based-aluminide metallic-intermetallic laminate (MIL) composites10.1016/j.msea.2015.10.019 ↗
29. Preparation and characterization of Fe–Al intermetallic layer on the surface of T91 heat-resistant steel10.1016/j.jnucmat.2013.12.027 ↗
30. Crystallography of Fe2Al5 phase at the interface between solid Fe and liquid Al10.1016/j.intermet.2015.07.011 ↗
31. Phase equilibria in the Al-rich portion of the ternary system Co–Ni–Al at 75 and 78 at.% Al
32. The Al–Cr (aluminum-chromium) system10.1007/BF02735058 ↗
33. Experimental and theoretical research on interfacial reaction of solid Co with liquid Al10.1016/j.corsci.2013.03.024 ↗