journal article·2020-11-07Open access

On the Electrical and Optical Properties Stability of P3HT Thin Films Sensitized with Nitromethane Ferric Chloride Solutions

Laura Hrostea, Liviu Leontie, Marius Dobromir, Corneliu Doroftei, Mihaela Girtan

Coatings· Volume 10· Issue 11

Abstract

The electrical and optical properties stability of poly(3-hexylthiophene) (P3HT) thin films sensitized with nitromethane ferric chloride (FeCl3) solution was investigated. The optical properties modifications were studied by spectrophotometry and ellipsometry. For electrical characterizations, electrical resistivity measurements were performed. In agreement with the observations of other authors, an important decrease in the electrical resistivity by six orders of magnitude was noticed. In addition, the repeatability and stability of this phenomenon were investigated over a few weeks after sensitization and during different cycles of heating and cooling, both in the dark and under illumination.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Thin-Film Transistor Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Faculty of Physics, Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I, nr. 11, 700506 Iasi, Romania

Photonics Laboratory, (LPhiA) E.A. 4464, SFR Matrix, Faculty of Sciences, Angers University, 2 Bd Lavoisier, 49000 Angers, France

Interdisciplinary Research Institute, Sciences Department, Alexandru Ioan Cuza University of Iasi, 11 Carol I Blvd., 700506 Iasi, Romania

Institute of Interdisciplinary Research, Alexandru Ioan Cuza University of Iasi, Integrated Center for Studies in Environmental Science for North-East Region, Bulevardul Carol I, nr. 11, 700506 Iasi, Romania

Funding

undefined undefined · Erasmus+ · Campus France

References (25)

Show source-provided references
1. Semiconducting and metallic polymers: The fourth generation of polymeric materials (nobel lecture)10.1002/1521-3773(20010716)40:14<2591::AID-ANIE2591>3.0.CO;2-0 ↗
2. Michaelson, L. (2015). Advances in Conducting Polymers Research, Nova Publisher. Polymer Science and Technology.
3. Krebs, F. (2012). Stability and Degradation of Organic and Polymer Solar Cells, Wiley.10.1002/9781119942436 ↗
4. Ludwings, S. (2014). P3HT Revisited—From Molecular Scale to Solar Cell Devices, Springer. Advances in Polymer Science 265.10.1007/978-3-662-45145-8 ↗
5. Maple prepared organic heterostructures for photovoltaic applications10.1007/s00339-011-6440-y ↗
6. Flexible heterostructures based on metal phthalocyanines thin films obtained by MAPLE10.1016/j.apsusc.2015.10.166 ↗
7. Study of charge carriers’ transport in organic solar cells by illumination area shifting10.1016/j.solmat.2016.11.011 ↗
8. High-performance carbon fiber/gold/copper composite wires for lightweight electrical cables10.1016/j.jmst.2019.08.057 ↗
9. Enhanced thermoelectric performance of bar-coated SWCNT/P3HT thin films10.1021/acsami.5b00626 ↗
10. Etxebarria, I., Ajuria, J., and Pacios, R. (2015). Polymer: Fullerene solar cells: Materials, processing issues, and cell layouts to reach power conversion efficiency over 10%, a review. J. Photonics Energy, 5.10.1117/1.JPE.5.057214 ↗
11. Single-junction organic solar cell with over 15% efficiency using fused-ring acceptor with electron-deficient core10.1016/j.joule.2019.01.004 ↗
12. Solar cell efficiency tables (version 54)10.1002/pip.3171 ↗
13. Influence of FeCl3 dopant on the electrical conductivity of pyrolysed aromatic polymers10.1007/BF00357872 ↗
14. Yabara, Y., Izawa, S., and Hiramoto, M. (2020). Donor/acceptor photovoltaic cells fabricated on p-doped organic single-crystal substrates. Materials, 13.10.3390/ma13092068 ↗
15. Bedia, J., Peñas-Garzón, M., Gómez-Avilés, A., Rodriguez, J.J., and Belver, C. (2020). Review on activated carbons by chemical activation with FeCl3. C J. Carbon Res., 6.10.3390/c6020021 ↗
16. Effective doping by spin-coating and enhanced thermoelectric power factors in SWCNT/P3HT hybrid films10.1039/C5TA02443A ↗
17. Electronic and vibrational spectra of positive polarons and bipolarons in regioregular poly(3-hexylthiophene) doped with ferric chloride10.1021/jp512654b ↗
18. Singh, R.K., Kumar, J., Singh, R., Kant, R., Rastogi, R.C., Chand, S., and Kumar, V. (2006). Structure-conductivity correlation in ferric chloride-doped poly(3-hexylthiophene). New J. Phys., 8.10.1088/1367-2630/8/7/112 ↗
19. Vijayakumar, V., Zhong, Y., Untilova, V., Bahri, M., Herrmann, L., Biniek, L., Leclerc, N., and Brinkmann, M. (2019). Bringing conducting polymers to high order: Toward conductivities beyond 105 S cm−1 and thermoelectric power factors of 2 mW m−1 K−2. Adv. Energy Mater., 9.10.1002/aenm.201900266 ↗
20. On the stability of the electrical and photoelectrical properties of P3HT and P3HT:PCBM blends thin films10.1016/j.orgel.2012.10.023 ↗
21. Singh, R., Kumar, J., Singh, R.K., Chand, S., Kumar, V., and Rastogi, R.C. (2006). Mechanism of charge transport in poly(3-octylthiophene). J. Appl. Phys., 100.10.1063/1.2213348 ↗
22. Thermoelectric composites of poly(3-hexylthiophene) and carbon nanotubes with a large power factor10.1039/c2ee23406h ↗
23. Photon assisted conducting atomic force microscopy study of nanostructured additives in P3HT:PCBM10.1039/C5RA20266C ↗
24. Use of Highly Reactive Zinc Leads to a New, Facile Synthesis for Polyarylenes10.1021/ma00065a036 ↗
25. Study of oxide/metal/oxide thin films for transparent electronics and solar cells applications by spectroscopic ellipsometry10.3934/matersci.2017.3.594 ↗