Electrodeposition of Nanocrystalline Fe-P Coatings: Influence of Bath Temperature and Glycine Concentration on Structure, Mechanical and Corrosion Behavior
Source abstract
Abstract
A detailed electrochemical study and investigation of a Fe-P glycine bath as a function of the temperature and glycine concentrations and current density, and their resulting corrosion and mechanical behavior is presented. A low addition of glycine to the electrolyte led to a drastic increase of the P content. At low Fe-P deposition rates, heterogeneous rough deposits with morphological bumps and pores were observed. By increasing the Fe-P deposition rate, the number of pores were reduced drastically, resulting in smooth coatings. Increasing the P content led to the formation of nanocrystalline grains from an “amorphous-like” state. Coatings with higher P contents exhibited better corrosion resistance and hardening, most likely attributed to grain boundary strengthening.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Electrodeposition and Electroless Coatings · Corrosion Behavior and Inhibition · Metal and Thin Film Mechanics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Hirtenberger Engineered Surfaces GmbH, Leobersdorferstrasse 31-33, A-2552 Hirtenberg, Austria
Department of Physical Chemistry, University of Vienna, Währinger Strasse 42, A-1090 Vienna, Austria
Department of Physical Chemistry, Vilnius University, Naugarduko str. 24, LT-03225 Vilnius, Lithuania
Leibniz Institute for Solid State and Materials Research Dresden (IFW), Helmholtzstrasse 20, D-01069 Dresden, Germany
Department de Física, Facultat de Ciències, Universitat Autònoma de Barcelona, Campus UAB, Building Cc, E-08193 Bellaterra, Spain
Institució Catalana de Recerca i Estudis Avançats (ICREA), Pg. Lluís Companys 23, E-08010 Barcelona, Spain
Funding
Horizon 2020
References (37)
Show source-provided references
1. Microstructural and magnetic properties study of Fe–P rolled sheet alloys10.1016/j.jmmm.2014.01.032 ↗
2. AC magnetic properties and core loss behavior of Fe–P soft magnetic sheets10.1109/TMAG.2014.2331084 ↗
3. Lippens, P.-E., Jumas, J.-C., and Génin, J.-M.R. (2006). Mössbauer and XRD study of pulse plated Fe-P and Fe-Ni thin layers. ICAME 2005, Proceedings of the 28th International Conference on the Applications of the Mössbauer Effect (ICAME 2005) held in Montpellier, France, 4–9 September 2005, Springer.10.1007/978-3-540-49853-7 ↗
4. Solidification of highly undercooled Fe-P alloys10.1007/BF02851370 ↗
5. The effects of pH and temperature on Ni–Fe–P alloy electrodeposition from a sulfamate bath and the material properties of the deposits10.1016/j.tsf.2005.05.011 ↗
6. Electrocatalytic activity of simple and modified Fe-P electrodeposits for hydrogen evolution from alkaline media10.1016/j.energy.2010.12.030 ↗
7. Fe and Fe-P foam for biodegradable bone replacement material: Morphology, corrosion behaviour, and mechanical properties
8. Electrodeposition and lithium storage performance of novel three-dimensional porous Fe–Sb–P amorphous alloy electrode10.1016/j.elecom.2008.12.054 ↗
9. Superior Li storage anode based on novel Fe–Sn–P alloy prepared by electroplating10.1016/j.electacta.2017.07.002 ↗
10. Electrocatalytic activities of nickel-phosphorous composite coating reinforced with codeposited graphite carbon for hydrogen evolution reaction in alkaline solution
11. Study of the hydrogen evolution reaction on Fe-Mo-P coatings as cathodes for chlorate production10.1016/j.ijhydene.2016.08.167 ↗
12. The acid corrosion of Fe-P alloys10.1002/maco.19870380105 ↗
13. Study of the crystallization kinetics in amorphous Fe83P17 alloy10.1007/BF02162632 ↗
14. The low-temperature electrical resistivity of amorphous iron-phosphorus alloys10.1016/0022-3093(76)90102-2 ↗
15. Electrochemical preparation of amorphous Fe–P alloys10.1007/BF01016891 ↗
16. Structure and magnetic properties of pulse-plated Fe–P and Fe–Cu–P amorphous alloys10.1016/0921-5093(94)90767-6 ↗
17. Internal stress and magnetic properties of electrodeposited amorphous Fe-P alloys10.1023/A:1018404024196 ↗
18. Electrochemically deposited thin films of amorphous Fe–P alloy: Part I. Chemical composition and phase structure characterization10.1016/S0022-0728(97)00417-8 ↗
19. Effects of glycine in DES-based plating baths on structural and magnetic properties of Fe-Ni films
20. Voltammetric determination of stability constants of iron(III)—Glycine complexes in water solution10.1016/j.jelechem.2005.05.011 ↗
21. Mössbauer study of electrochemically deposited Fe-P amorphous alloys10.1016/0013-4686(88)80139-7 ↗
22. Magnetic properties and microstructure of electrodeposited Fe–P amorphous alloy10.1007/BF01021977 ↗
23. Electrochemical behaviour of electrodeposited Fe–8P amorphous alloys
24. Studies on autocatalytic deposition of ternary Ni-W-P alloys using nickel sulphamate bath10.1016/j.surfcoat.2005.11.131 ↗
25. Effect of oxyanions of phosphorus on the anodic behaviour of iron and iron + phosphorus alloy in borate solution10.1016/0022-0728(94)03371-4 ↗
26. Hardness and tensile properties of Fe–P based alloys made through powder forging technique10.1016/j.msea.2007.06.030 ↗
27. Kinetische und kristallografische Modellbetrachtungen zur Korrosion und Passivitat von Metallen10.1002/maco.19810321206 ↗
28. An ellipsometric study of anodic films formed on iron-phosphorous alloys in borate solution10.1016/0010-938X(88)90117-5 ↗
29. Effects of phosphorus on the stability of the passive state of Fe and Fe–Ni base glasses10.1002/maco.19880391003 ↗
30. Sawyer, D.T., and Sobkowiak, A. (1995). Electrochemistry for Chemists, Wiley. [2nd ed.].
31. Gamburg, Y.D., and Zangari, G. (2011). Theory and Practice of Metal Electrodeposition, Springer.10.1007/978-1-4419-9669-5 ↗
32. Bard, A.J., and Faulkner, L.R. (2015). Fundamentals and Fundamentals and Applications, A K Peters/CRC Press.
33. Influence of glycine on Co electrodeposition: IR spectroscopy and near-surface pH investigations10.1016/j.electacta.2017.12.032 ↗
34. Fe(III)-based ammonia-free bath for electrodeposition of Fe-W alloys10.1149/2.1001709jes ↗
35. An XPS investigation into the passivity of an amorphous Ni-20P alloy10.1149/1.2095880 ↗
36. Corrosion resistance of ternary Ni-P based alloys in sulfuric acid solutions10.1016/S0013-4686(02)00198-6 ↗
37. Measurement of hardness and elastic modulus by instrumented indentation: Advances in understanding and refinements to methodology10.1557/jmr.2004.19.1.3 ↗