High-Performance Adhesives Based on Maleic Anhydride-g-EPDM Rubbers and Polybutene for Laminating Cast Polypropylene Film and Aluminum Foil
Source abstract
Abstract
The adhesion between aluminum (Al) foil and cast polypropylene (CPP) film laminated with mixtures of amorphous- and crystalline-maleic anhydride-grafted ethylene-propylene-diene monomer (MAH-g-EPDM) rubbers and highly reactive polybutene (HRPB) as the adhesives was investigated. Specifically, the HRPB was used as an adhesion promoter of the MAH-g-EPDM rubbers and CPP as well as a compatibilizer of two kinds of MAH-g-EPDM rubbers having limited miscibility. To introduce strong chemical bonds between the MAH-g-EPDM rubbers and Al foil, the surface of Al foil was treated with 3-aminopropyl triethoxysilane (APTES). The weak adhesion between Al foil and MAH-g-EPDM rubbers was improved by imidization between the amine groups (–NH2) of APTES and the maleic anhydride groups (MAH) of MAH-g-EPDM rubbers. The effects of the composition of adhesives, tempering time and adhesive thickness were also studied to optimize the adhesion of the CPP/Al foil laminates. We concluded that MAH-g-EPDM rubber based adhesives containing HRPB can be applied for the lamination of Al foil and CPP films to satisfy the requirements of high-performance packaging materials for various purposes.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Polymer Nanocomposites and Properties · Polymer crystallization and properties · Silicone and Siloxane Chemistry
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Division of Semiconductor and Chemical Engineering, Chonbuk National University, 567 Baekjedaero, Jeonju 54896, Korea
LG Chem R & D Campus, 188 Moonji-ro, Yuseong-gu, Daejeon 34122, Korea
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