Synthesis and Formation Mechanism of Metal Oxide Compounds
Source abstract
Abstract
In this work, the influence of the technological parameters of the detonation method on the formation of metal oxide compounds on the basis of titanium was investigated. The aim of the work was to investigate the method of the effective control of the phase composition and microstructure of titanium-based coatings during detonation spraying. The main parameters that varied in detonation spraying were the volume of filling the detonation barrel with explosive mixture and the oxygen/fuel ratio. The mechanism of formation of the gradient structure of coatings based on metal oxide compounds depending on the technological parameters of detonation spraying was considered. The structural-phase states and tribological properties of detonation coatings were investigated by the following methods: X-ray phase analysis (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDX-mapping), profilometry, and the test for wear-resistance according to the “ball-disk” scheme. It is shown that the phase composition of coatings may significantly change relative to the initial titanium powder during the detonation spraying due to the interaction of particles of powders with components of the gas atmosphere. Varying the spraying parameters may control the chemical reaction and provide conditions for the synthesis of the desired phases in the coatings (titanium oxide TiO2 and Ti2O3).
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Research context
OpenAlex topics: Advanced materials and composites · Material Properties and Applications · Surface Treatment and Coatings
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Research Center «Surface Engineering and Tribology», Sarsen Amanzholov East Kazakhstan University, Ust-Kamenogorsk 070000, Kazakhstan
Institute for Composite Materials, Ust-Kamenogorsk 070010, Kazakhstan
PlasmaScience LLP, Ust-Kamenogorsk 070010, Kazakhstan
Shakarim University, Semey 071412, Kazakhstan
The Faculty of Earth and Environmental Sciences, Daulet Serikbaev East Kazakhstan Technical University, Ust-Kamenogorsk 070002, Kazakhstan
Funding
Science Committee of the Ministry of Education and Science of the Republic of Kazakhstan
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