Conformal Functionalization of Cotton Fibers via Isoreticular Expansion of UiO-66 Metal-Organic Frameworks
Source abstract
Abstract
We report on the growing of metal-organic frameworks that are isoreticular and isostructural to UiO-66, onto cotton fabrics via a solvothermal method. Four different metal-organic frameworks (MOFs) (UiO-66, UiO-66-NH2, UiO-66-NDC, and UiO-67) were chosen as a case study. The presence of the UiO-based MOFs was confirmed through X-ray diffraction and Scanning Electron Microscopy. We used thermogravimetric analysis to quantify the amount of the MOF loading, which ranged from 0.8% to 2.6% m/m. We also explored the role of ligand size, growth time, and reaction temperature on the conformal coating of cotton fibers with these Zr-based MOFs. Cotton fabrics coated with Zr-based MOFs can find applications as selective filters in aggressive environments due to their enhanced chemical and thermal stabilities.
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Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Advanced Nanomaterials in Catalysis · Nanoplatforms for cancer theranostics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Fiber Science, Cornell University, Ithaca, NY 14853, USA
Department of Chemistry and Materials, Faculty of Textile Science and Technology, Shinshu University, Ueda Campus, Nagano 386-0018, Japan
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