journal article·2023-02-10Open access

CMAS Corrosion Resistance Behavior and Mechanism of Hf6Ta2O17 Ceramic as Potential Material for Thermal Barrier Coatings

Sai Liu, Qing Liu, Xiaopeng Hu, Jinwei Guo, Wang Zhu, Fan Zhang, Jie Xia

Coatings· Volume 13· Issue 2

Abstract

Thermal barrier coatings (TBCs) have been seriously threatened by calcium-magnesium-alumina-silicate (CMAS) corrosion. The search for novel ceramic coatings for TBCs with excellent resistance to CMAS corrosion is ongoing. Herein, CMAS corrosion resistance behavior and the mechanism of a promising Hf6Ta2O17 ceramic coating for TBCs are investigated. The results show that temperature is the most important factor affecting the CMAS behavior and mechanism. At 1250 °C, the corrosion products are composed of dense reaction products (HfSiO4, CaXHf6−xTa2O17−x) and CMAS self-crystallization products. At 1300 and 1400 °C, the corrosion products are mainly dense CaTa2O6 and HfO2, which prevent further CMAS infiltration.
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Research context

OpenAlex topics: High-Temperature Coating Behaviors · Advanced ceramic materials synthesis · Magnesium Oxide Properties and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Key Film Materials & Application for Equipment (Hunan Province), School of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, China

Department of Mechanical Engineering, Hunan Institute of Technology, Hengyang 421002, China

Funding

Science and Technology Innovation Program of Hunan Province · Scientific Research Foundation of Hunan Provincial Education Department · National Natural Science Foundation of China · Natural Science Foundation of Hunan Province · Postgraduate Scientific Research Innovation Project of Hunan Province

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