journal article·2020-01-18Open access

Photocatalytic Properties of Copper Nitride/Molybdenum Disulfide Composite Films Prepared by Magnetron Sputtering

Liwen Zhu, Chenyang Gong, Jianrong Xiao, Zhiyong Wang

Coatings· Volume 10· Issue 1

Abstract

Cu3N/MoS2 composite films were prepared by magnetron sputtering under different preparation parameter, and their photocatalytic properties were investigated. Results showed that the composite films surface was uniform and had no evident cracks. When the sputtering power of MoS2 increased from 2 W to 8 W, the photocatalytic performance of the composite films showed a trend of increasing first and then decreasing. Among these films, the composite films with MoS2 sputtering power of 4 W showed the best photocatalytic degradation performance. The photocatalytic degradation rate of methyl orange at 30 min was 98.3%, because the MoS2 crystal in the films preferentially grew over the Cu3N crystal, thereby affecting the growth of the Cu3N crystal. The crystallinity of the copper nitride also increased. During photocatalytic degradation, the proper amount of MoS2 reduced the band gap of Cu3N, and the photogenerated electron hole pairs were easily separated. Thus, the films produces additional photogenerated electrons and promotes the degradation reaction of the composite films on methyl orange solution.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Copper-based nanomaterials and applications · 2D Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Science, Guilin University of Technology, Guilin 541004, China

Funding

Guangxi Natural Science Foundation · National Natural Science Foundation of China

References (56)

Show source-provided references
1. Tailored titanium dioxide photocatalysts for the degradation of organic dyes in wastewater treatment: A review10.1016/j.apcata.2009.02.043 ↗
2. In situ synthesis of C-TiO2/g-C3N4 heterojunction nanocomposite as highly visible light active photocatalyst originated from effective interfacial charge transfer10.1016/j.apcatb.2016.09.052 ↗
3. Degradation of methylene blue and methyl orange by palladium-doped tio2 photocatalysis for water reuse: Efficiency and degradation pathways10.1016/j.jclepro.2018.08.110 ↗
4. Mos 2 quantum dots decorated g-C3N4/Ag heterostructures for enhanced visible light photocatalytic activity10.1016/j.apsusc.2017.08.042 ↗
5. Sputtered bismuth oxide thin films as a potential photocatalytic material10.1016/j.cattod.2015.10.025 ↗
6. Construction of amorphous TiO/BiOBr heterojunctions via facets coupling for enhanced photocatalytic activity10.1016/j.jhazmat.2015.03.030 ↗
7. Supercritical fluid deposition of high-density nanoparticles of photocatalytic TiO2 on carbon nanowalls10.7567/APEX.6.045103 ↗
8. Hybrid nanostructures based on titanium dioxide for enhanced photocatalysis10.1016/j.apcata.2014.10.001 ↗
9. Localization of the photocatalytic reaction on the grain boundary of bicrystalline TiO210.1143/APEX.1.101201 ↗
10. Highly efficient visible-light-driven mesoporous graphitic carbon nitride/ZnO nanocomposite photocatalysts10.1016/j.apcatb.2016.07.027 ↗
11. Facilein situsynthesis of wurtzite zns/zno core/shell heterostructure with highly efficient visible-light photocatalytic activity and photostability10.1088/1361-6463/aaa28b ↗
12. Photoelectrocatalytic decolorization of azo dyes with nano-composite oxide layers of zno nanorods decorated with Ag nanoparticles10.1016/j.chemosphere.2018.12.003 ↗
13. Preparation of zno photocatalyst for the efficient and rapid photocatalytic degradation of Azo dyes10.1186/s11671-017-1904-4 ↗
14. ZnO/Ag/Mn2O3 nanocomposite for visible light-induced industrial textile effluent degradation, uric acid and ascorbic acid sensing and antimicrobial activity10.1039/C5RA02557E ↗
15. Cu2−xSe/CdS composite photocatalyst with enhanced visible light photocatalysis activity10.1016/j.apsusc.2019.02.010 ↗
16. Characterization and mechanism of MoS2/CdS composite photocatalyst used for hydrogen production from water splitting under visible light10.1016/j.cej.2014.07.046 ↗
17. Studies on facile synthesis and properties of mesoporous CdS/TiO2 composite for photocatalysis applications10.1016/j.jallcom.2016.09.039 ↗
18. Z-scheme BiOCl-Au-CdS heterostructure with enhanced sunlight-driven photocatalytic activity in degrading water dyes and antibiotics10.1021/acssuschemeng.7b01157 ↗
19. Enhanced visible light photocatalytic performance of zno nanowires integrated with CdS and Ag2S10.1039/C5DT04533A ↗
20. Morphology dependent photocatalytic activity of WO3 nanostructures10.1016/S2095-4956(15)60297-2 ↗
21. Photoelectrochemical properties and photocatalytic activity of fluorine-doped plate-like WO3 from hydrothermal radio-frequency (rf) sputtered tungsten thin films10.1142/S1793292017500412 ↗
22. Visible light catalysis of methyl orange using nanostructured WO3 thin films10.1016/j.ceramint.2015.08.178 ↗
23. Synthesis of mo-doped WO3 nanosheets with enhanced visible-light-driven photocatalytic properties10.1039/C5RA17098B ↗
24. 2d ultra-thin WO3 nanosheets with dominant {002} crystal facets for high-performance xylene sensing and methyl orange photocatalytic degradation10.1016/j.jallcom.2018.12.384 ↗
25. Mesoporous black TiO2-x/Ag nanospheres coupled with g-C3N4 nanosheets as 3D/2D ternary heterojunctions visible light photocatalysts10.1016/j.jhazmat.2017.09.031 ↗
26. Recent developments of zinc oxide based photocatalyst in water treatment technology: A review10.1016/j.watres.2015.09.045 ↗
27. ZnO/Ag/CdO nanocomposite for visible light-induced photocatalytic degradation of industrial textile effluents10.1016/j.jcis.2015.04.035 ↗
28. Conducting pani stimulated zno system for visible light photocatalytic degradation of coloured dyes10.1016/j.molliq.2016.06.074 ↗
29. ZnO/WO3 nanostructure as an efficient visible light catalyst10.1016/j.ceramint.2018.02.150 ↗
30. Enhanced photoinduced-stability and photocatalytic activity of CdS by dual amorphous cocatalysts: Synergistic effect of Ti(IV)-Hole cocatalyst and Ni(II)-Electron cocatalyst10.1021/acs.jpcc.6b00126 ↗
31. The enhancement of CdS photocatalytic activity for water splitting via antiphotocorrosion by coating Ni2P shell and removing nascent formed oxygen with artificial gill10.1016/j.apcatb.2017.09.024 ↗
32. Fullerene (C60)/CdS nanocomposite with enhanced photocatalytic activity and stability10.1016/j.apsusc.2017.01.135 ↗
33. Crystal structure and optical properties of silver-doped copper nitride films (Cu3N:Ag) prepared by magnetron sputtering10.1088/1361-6463/aaa478 ↗
34. Enhanced write-once optical storage capacity of Cu3N film by coupling with an Al2O3 protective layer10.1016/j.ceramint.2015.11.136 ↗
35. Synthesis of CuO and Cu3N nanoparticles in and on hollow silica spheres10.1002/ejic.201201442 ↗
36. Preparation, structure, properties, and application of copper nitride (Cu3N) thin films: A review10.1016/j.jmst.2018.02.025 ↗
37. Addition of silver in copper nitride films deposited by reactive magnetron sputtering10.1016/j.scriptamat.2007.11.016 ↗
38. Influences of nitrogen partial pressure on the optical properties of copper nitride films10.1039/C6RA03479A ↗
39. Birkett, M., Savory, C.N., Fioretti, A.N., Thompson, P., Muryn, C.A., Weerakkody, A.D., Mitrovic, I.Z., Hall, S., Treharne, R., and Dhanak, V.R. (2017). Atypically small temperature-dependence of the direct band gap in the metastable semiconductor copper nitrideCu3N. Phys. Rev. B, 95.10.1103/PhysRevB.95.115201 ↗
40. Structure and electrical transport properties of pb-doped copper nitride (Cu3N:Pb) films10.1016/j.vacuum.2019.03.008 ↗
41. P- to n-type conversion and nonmetal–metal transition of lithium-inserted Cu3N Films10.1021/acs.chemmater.5b03781 ↗
42. Exploring the tribophysics and tribochemistry of MoS2 by sliding mos2/ti composite coating under different humidity10.1007/s11249-017-0824-x ↗
43. Crystal structure and tribological properties of molybdenum disulfide films prepared by magnetron sputtering technology10.1016/j.cap.2019.08.017 ↗
44. Electronic structures and optical properties of p and cl atoms adsorbed/substitutionally doped monolayer MoS210.1016/j.ssc.2018.05.005 ↗
45. Gong, C., Xiao, J., Zhu, L., Wang, Z., and Ma, S. (2019). Effect of deposition pressure on the microstructure and optical band gap of molybdenum disulfide films prepared by magnetron sputtering. Coatings, 9.10.3390/coatings9090570 ↗
46. Growth and optical properties of large-scale MoS2 films with different thickness10.1016/j.ceramint.2019.04.248 ↗
47. Substrate induced anomalous electrostatic and photoluminescence propeties of monolayer MoS2 edges10.1016/j.ssc.2016.10.007 ↗
48. Atomic layer etching mechanism of MoS2 for nanodevices10.1021/acsami.6b15886 ↗
49. Probing the nanoscale light emission properties of cvd-grown MoS2 monolayer by tip-enhanced photoluminescence10.1039/C8NR02421A ↗
50. Magnetic field dependence of electronic properties of MoS2 quantum dots with different edges10.1103/PhysRevB.97.085437 ↗
51. Inner and outer ring states of MoS2 quantum rings: Energy spectrum, charge and spin currents10.1063/1.5094200 ↗
52. Reactive dc magnetron sputter deposited copper nitride nano-crystalline thin films: Growth and characterization10.1016/j.vacuum.2011.09.001 ↗
53. Copper nitride layers synthesized by pulsed magnetron sputtering10.1016/j.tsf.2017.10.042 ↗
54. Improving the thermal stability of cu3n films by addition of mn10.1016/j.jmst.2015.07.013 ↗
55. Thermal stability and optical properties of sc-doped copper nitride films10.1016/j.vacuum.2017.04.024 ↗
56. Microstructure and tribological properties of mos 2 +zr composite coatings in high humidity environment10.1016/j.apsusc.2016.01.163 ↗