journal article·2022-06-22Open access

Microstructure and Properties in Simulated Seawater of Copper-Doped Micro-arc Coatings on TC4 Alloy

Yong Zhang, Wei Yang, Sen Yu, Liqun Wang, Xiqun Ma, Wei Gao, Nan Lan, Wenting Shao, Jian Chen

Coatings· Volume 12· Issue 7

Abstract

Micro-arc oxidation (MAO) ceramic coatings were prepared on TC4 titanium alloys by adding CuSO4 to a (NaPO3)6 base solution. The microstructures of the MAO coatings were characterized by scanning electron microscopy (SEM), energy dispersive (EDS), and X-ray photoelectron spectroscopy (XPS). The corrosion resistance and wear resistance of these coatings were evaluated via hydrochloric acid immersion of weight deficit and friction tests. Those results indicated the presence of Cu in the MAO coating in the form of CuO and Cu2O. Incorporation of CuSO4 results in a thickness and roughness increase in the coating. The coating has a lower coefficient of friction (0.2) upon the addition of 4 g/L of CuSO4. The antibacterial properties of the MAO coatings were maximized at 6 g/L of CuSO4. However, the corrosion resistance of the copper-doped MAO coating did not exceed the undoped coating. This study shows that the addition of CuSO4 to the electrolyte successfully prepared copper-containing micro-arc oxidation coatings, which improved the wear resistance and antibacterial properties of the coating.
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Research context

OpenAlex topics: Titanium Alloys Microstructure and Properties · Metal and Thin Film Mechanics · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science and Chemical Engineering, Xi’an Technological University, Xi’an 710021, China

Shaanxi Key Laboratory of Biomedical Metal Materials, Northwest Institute for Non-ferrous Metal Research, Xi’an 710016, China

School of Materials Science and Engineering, Xi’an Jiaotong University, Xi’an 710049, China

Funding

National Natural Science Foundation of China · China Postdoctoral Science Foundation · Shaanxi Provincial Education Department · Key research and development plan of Shaanxi Province Industrial Project

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