journal article·2021-04-26Open access

Optical Constant and Conformality Analysis of SiO2 Thin Films Deposited on Linear Array Microstructure Substrate by PECVD

Yongqiang Pan, Huan Liu, Zhuoman Wang, Jinmei Jia, Jijie Zhao

Coatings· Volume 11· Issue 5

Abstract

SiO2 thin films are deposited by radio frequency (RF) plasma-enhanced chemical vapor deposition (PECVD) technique using SiH4 and N2O as precursor gases. The stoichiometry of SiO2 thin films is determined by the X-ray photoelectron spectroscopy (XPS), and the optical constant n and k are obtained by using variable angle spectroscopic ellipsometer (VASE) in the spectral range 380–1600 nm. The refractive index and extinction coefficient of the deposited SiO2 thin films at 500 nm are 1.464 and 0.0069, respectively. The deposition rate of SiO2 thin films is controlled by changing the reaction pressure. The effects of deposition rate, film thickness, and microstructure size on the conformality of SiO2 thin films are studied. The conformality of SiO2 thin films increases from 0.68 to 0.91, with the increase of deposition rate of the SiO2 thin film from 20.84 to 41.92 nm/min. The conformality of SiO2 thin films decreases with the increase of film thickness, and the higher the step height, the smaller the conformality of SiO2 thin films.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: ZnO doping and properties · Thin-Film Transistor Technologies · Semiconductor materials and devices

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Opto-Electronic Engineering, Xi’an Technological University, Xi’an 710021, China

Funding

Natural Science Foundation of Shaanxi Province · Scientific Research Program Funded by Shaanxi Provincial Education Department

References (28)

Show source-provided references
1. Low-temperature, high-growth-rate ALD of SiO2 using aminodisilane precursor10.1016/j.apsusc.2019.03.227 ↗
2. Effect of oxygen flow rate on microstructure properties of SiO2 thin films prepared by ion beam sputtering10.1016/j.jnoncrysol.2017.12.046 ↗
3. Study on SiO2 thin film modified by post hot isostatic pressing10.1016/j.vacuum.2017.11.018 ↗
4. Porous SiO2 films analyzed by transmission electron microscopy10.1016/S0040-6090(94)06497-0 ↗
5. Studies on optical, chemical, and electrical properties of rapid SiO2 atomic layer deposition using tris(tert-butoxy)silanol and trimethyl-aluminum10.1016/j.materresbull.2012.04.093 ↗
6. Optical properties and structrue of SiO2 films prepared by ion-beam sputtering10.1016/S0040-6090(96)08899-2 ↗
7. Highly conformal carbon-doped SiCN films by plasma-enhanced chemical vapor deposition with enhanced barrier properties10.1016/j.tsf.2018.04.042 ↗
8. Two deterministic approaches to topography evolution10.1016/j.surfcoat.2007.04.093 ↗
9. Thin polymer films with high step coverage in microtrenches by initiated CVD10.1002/cvde.200806713 ↗
10. Effect of substrate on the step coverage of plasma-enhanced chemical-vapor deposited tetraethylorthosilicate films10.1116/1.1574046 ↗
11. AVD and ALD as two complementary technology solutions for next generation dielectric and conductive thin-film processing10.1002/cvde.200500027 ↗
12. Applications of atomic layer deposition to nanofabrication and emerging nanodevices10.1016/j.tsf.2008.09.007 ↗
13. Low temperature nanoimprint lithography using silicon nitride molds10.1016/S0167-9317(01)00435-X ↗
14. Properties of SiO2-like barrier layers on polyethersulfone substrates by low-temperature plasma-enhanced chemical vapor deposition10.1016/j.tsf.2004.04.031 ↗
15. Deposition of SiO2 by plasma enhanced chemical vapor deposition as the diffusion barrier to polymer substrates10.1143/JJAP.44.1022 ↗
16. Deposition of SiO2 films with high laser damage thresholds by ion-assisted electron-beam evaporation10.1364/AO.38.001237 ↗
17. Thermal and plasma enhanced atomic layer deposition of SiO2 using commercial silicon precursors10.1016/j.tsf.2014.02.087 ↗
18. Step coverage simulation and measurement in a dc planar magnetron sputtering system10.1063/1.332414 ↗
19. Step coverage study of indium-tin-oxide thin films by spray CVD on non-flat substrates at different temperatures10.1016/j.tsf.2007.10.040 ↗
20. The step coverage of CVD SiO2 glass films10.1016/0167-577X(82)90035-0 ↗
21. Effects of precursors and substrate materials on microstructure, dielectric properties, and step coverage of (Ba, Sr)TiO3 films grown by metalorganic chemical vapor deposition10.1063/1.371833 ↗
22. SiO2 planarization technology with biasing and electron cyclotron resonance plasma deposition for submicron interconnections10.1116/1.583518 ↗
23. Characterization of step coverage change in ultraviolet-transparent plasma enhanced chemical vapor deposition silicon nitride films10.1116/1.1314394 ↗
24. Özkol, E., Procel, P., Zhao, Y., Mazzarella, L., Medlin, R., Šutta, P., Isabella, O., and Zeman, M. (2019). Effective passivation of black silicon surfaces via plasma-enhanced chemical vapor deposition grown conformal hydrogenated amorphous silicon layer. Phys. Status Solidi (RRL) Rapid Res. Lett., 14.10.1002/pssr.201900087 ↗
25. Conformality investigation of titanium dioxide thin films on 3-D micrometer- and nanometer-scale features by pulsed-pressure metal-organic CVD10.1002/cvde.201106912 ↗
26. Step coverage of thin titania films on patterned silicon substrate by pulsed-pressure MOCVD10.1016/j.surfcoat.2007.03.051 ↗
27. PECVD SiO2 and SiON films dependant on the rf bias power for low-loss silica waveguide10.1016/j.tsf.2004.07.044 ↗
28. Fabrication and evaluation of protective SiOx layers using plasma-enhanced chemical vapor deposition10.1016/j.surfcoat.2017.09.074 ↗