journal article·2018-09-04Open access

Atmospheric Pressure Plasma Coating of Bismuth Oxide Circular Droplets

Robert Köhler, Gisela Ohms, Holger Militz, Wolfgang Viöl

Coatings· Volume 8· Issue 9

Abstract

In this study, bismuth oxide powder (Bi2O3) was deposited by an atmospheric pressure plasma jet onto borosilicate glass. The layer produced through this method is to be used as a photo catalyst in later applications. The deposited coating was analyzed by X-ray diffraction (XRD) to determine the crystal structure, and X-ray photoelectron spectroscopy (XPS) to analyze the chemical state. The results showed a change in crystal and chemical structure during the deposition process. The morphological properties of the layer were examined with scanning electron microscopy (SEM) and laser scanning microscopy (LSM). The band gap structure of the coating was investigated by UV-Vis spectroscopy. The layer produced by the plasma spraying process consisted of circular multi-phase bismuth oxide droplets (monoclinic Bi2O3 and tetragonal Bi2O2.33), showing a direct band gap of Eg = 2.72 eV, which allows their use as a photocatalyst.
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Research context

OpenAlex topics: Catalytic Processes in Materials Science · Catalysis and Oxidation Reactions · Electronic and Structural Properties of Oxides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Laboratory of Laser and Plasma Technologies, University of Applied Sciences and Arts, Von-Ossietzky-Str. 99, 37085 Göttingen, Germany

Wood Biology and Wood Products, Faculty of Forest Sciences, University of Goettingen, Büsgenweg 4, 37077 Göttingen, Germany

Funding

Bundesministerium für Bildung und Forschung

References (36)

Show source-provided references
1. Synthesis of bismuth oxide thin films deposited by reactive magnetron sputtering10.12693/APhysPolA.120.60 ↗
2. Preparation of α-Bi2O3 from bismuth powders through low-temperature oxidation10.1016/S1003-6326(11)61462-3 ↗
3. Synthesis, surface tension, optical and dielectric properties of bismuth oxide thin film10.1515/msp-2017-0020 ↗
4. In situ synthesis of α-β phase heterojunction on Bi2O3 nanowires with exceptional visible-light photocatalytic performance10.1016/j.apcatb.2013.05.050 ↗
5. Growth of Bi2O3 ultrathin films by atomic layer deposition10.1021/jp205180p ↗
6. Bismuth oxide thin film as new electrochromic material10.1016/S0167-2738(98)00388-9 ↗
7. Bismuth oxide thin films prepared by chemical bath deposition (CBD) method: Annealing effect10.1016/j.apsusc.2004.12.050 ↗
8. New ε-Bi2O3 metastable polymorph10.1021/ic0605221 ↗
9. A Transition phase in the transformation from α-, β- and ε- to δ-bismuth oxide10.1088/0256-307X/28/5/056101 ↗
10. Powder X-ray diffraction data for the new polymorphic compound ω-Bi2O310.1017/S0885715600009490 ↗
11. The polymorphism of bismuth sesquioxide10.1016/0040-6031(79)87011-2 ↗
12. From molecules to bismuth oxide-based materials: Potential homo- and heterometallic precursors and model compounds10.1016/j.ccr.2006.06.005 ↗
13. Thermal stability of Bi2O310.1134/S0036023607120030 ↗
14. Intrinsic stress of bismuth oxide thin films: Effect of vapour chopping and air ageing10.1088/1742-6596/114/1/012036 ↗
15. Synthesis of bismuth oxide nanostructures by an oxidative metal vapour phase deposition technique10.1088/0957-4484/18/29/295605 ↗
16. Microstructure characterization of δ-Bi2O3 thin film under atmospheric pressure by means of halide CVD on c-sapphire10.1016/j.jcrysgro.2004.11.433 ↗
17. Enhanced photocatalytic performance: A β-Bi2O3 thin film by nanoporous surface10.1088/0022-3727/46/3/035103 ↗
18. Ratova, M., Marcelino, R.B.P., de Souza, P.P., Amorim, C.C., and Kelly, P.J. (2017). Reactive Magnetron Sputter Deposition of Bismuth Tungstate Coatings for Water Treatment Applications under Natural Sunlight. Catalysts, 7.10.3390/catal7100283 ↗
19. Alfa-bismuth(III) oxide catalyzed biginelli reactions using experimentally designed optimized condition
20. Condurache-Bota, S., Constantinescu, C., Praisler, M., Tiron, V., Tigau, N., and Gheorghies, C. (2014, January 13–15). The influence of laser wavelength and pulses number on the structure and the optical properties of pulsed laser-deposited bismuth oxide thin films. Proceedings of the 2014 International Semiconductor Conference (CAS), Sinaia, Romania.10.1109/SMICND.2014.6966400 ↗
21. Structural and optical characterization of thermally oxidized bismuth films
22. Characterization of spray deposited bismuth oxide thin films from non-aqueous medium
23. Ag doped Bi2O2.33 microrods: Photocatalytic activity investigation10.1039/C5RA24503F ↗
24. Optical properties of Cauliflower-like Bi2O3 nanostructures by reactive pulsed laser deposition (PLD) technique10.1016/j.solener.2014.05.020 ↗
25. Ultraviolet-Emitting Bi2O2.33 Nanosheets Prepared by Electrolytic Corrosion of Metal Bi10.1021/jp909431w ↗
26. Epitaxial growth of Bi2O2.33 by halide CVD10.1002/cvde.19960020604 ↗
27. Facile preparation of orange-like Bi2O2.33 microspheres for high performance supercapacitor application10.1016/j.matlet.2012.09.019 ↗
28. Köhler, R., Sauerbier, P., Militz, H., and Viöl, W. (2017). Atmospheric pressure plasma coating of wood and MDF with polyester powder. Coatings, 7.10.3390/coatings7100171 ↗
29. X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems10.1002/sia.3026 ↗
30. Nature of the use of adventitious carbon as a binding energy standard10.1116/1.579868 ↗
31. Beamson, G., and Briggs, D. (1992). High Resolution XPS of Organic Polymers: The Scienta ESCA300 Database, Wiley.
32. Soft-chemical synthetic nonstoichiometric Bi2O2.33 nanoflower: A new room-temperature ferromagnetic semiconductor10.1021/jp509045d ↗
33. Optical properties of bismuth oxide nanoparticles synthesized by pulsed laser ablation in liquids10.1166/sam.2012.1310 ↗
34. Bismuth oxide photocatalytic nanostructures produced by magnetron sputtering deposition10.1016/j.tsf.2012.06.001 ↗
35. On the optical properties of bismuth oxide thin films prepared by pulsed laser deposition10.1016/j.tsf.2004.07.061 ↗
36. Synthesis, characterization and optical band gap of La2CuO4 nanoparticles10.1016/j.mssp.2013.05.005 ↗