Naproxen-Based Hydrazones as Effective Corrosion Inhibitors for Mild Steel in 1.0 M HCl
Source abstract
Abstract
The corrosion-inhibiting performance of (E)-N’-(4-bromobenzylidene)-2-(6-methoxynaphthalen-2-yl) propanehydrazide (BPH) and (E)-N’-(4-(dimethylamino) benzylidene)-2-(6-methoxynaphthalen-2-yl) propanehydrazide (MPH) for mild steel (MS) in 1.0 M HCl was investigated using electrochemical methods, weight loss measurements, and scanning electron microscope (SEM) coupled with energy dispersive X-ray spectroscope (EDX) analysis. Raising the concentration of both inhibitors towards an optimal value of 5 × 10−3 M reduced the corrosion current density (icorr) and the corrosion rate of mild steel. The inhibitory effect of MPH, which showed the highest inhibition efficiency, was explored under a range of temperatures between 303 and 333 K. The inhibitory performance of both compounds significantly improved when the inhibitor concentration increased. The main result that flowed from potentiodynamic polarization (PDP) tests was that both compounds acted as mixed-type inhibitors, with a predominance cathodic effect. The adsorption of both compounds follows the Langmuir isotherm. SEM/EDX confirmed the excellent inhibition performance of tested compounds.
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Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Concrete Corrosion and Durability · Hydrogen embrittlement and corrosion behaviors in metals
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Laboratory of Applied Chemistry and Environment, ENSA, University Ibn Zohr, P.O. Box 1136, Agadir 80000, Morocco
Department of Chemistry, College of Education, Kirkuk University, Kirkuk 36001, Iraq
Department of Chemistry, College of Science, King Khalid University, P.O. Box 9004, Abha 61413, Saudi Arabia
Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M15 6BH, UK
Chemistry Department, Faculty of Science, Minia University, El-Minia 61519, Egypt
Department of Materials Sciences, Laghouat University, P.O. Box 37, Laghouat 03000, Algeria
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