journal article·2019-05-25Open access

Gas Sensing with Nanoplasmonic Thin Films Composed of Nanoparticles (Au, Ag) Dispersed in a CuO Matrix

Manuela Proença, Marco S. Rodrigues, Joel Borges, Filipe Vaz

Coatings· Volume 9· Issue 5

Abstract

Magnetron sputtered nanocomposite thin films composed of monometallic Au and Ag, and bimetallic Au-Ag nanoparticles, dispersed in a CuO matrix, were prepared, characterized, and tested, which aimed to find suitable nano-plasmonic platforms capable of detecting the presence of gas molecules. The Localized Surface Plasmon Resonance phenomenon, LSPR, induced by the morphological changes of the nanoparticles (size, shape, and distribution), and promoted by the thermal annealing of the films, was used to tailor the sensitivity to the gas molecules. Results showed that the monometallic films, Au:CuO and Ag:CuO, present LSPR bands at ~719 and ~393 nm, respectively, while the bimetallic Au-Ag:CuO film has two LSPR bands, which suggests the presence of two noble metal phases. Through transmittance-LSPR measurements, the bimetallic films revealed to have the highest sensitivity to the refractive index changes, as well as high signal-to-noise ratios, respond consistently to the presence of a test gas.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Gas Sensing Nanomaterials and Sensors · Plasmonic and Surface Plasmon Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Centro de Física da Universidade do Minho, Campus de Gualtar, 4710-057 Braga, Portugal

Funding

Fundação para a Ciência e a Tecnologia · European Regional Development Fund

References (47)

Show source-provided references
1. Development of Au/CuO nanoplasmonic thin films for sensing applications10.1016/j.surfcoat.2017.08.033 ↗
2. Nanoplasmonic response of porous Au-TiO2 thin films prepared by oblique angle deposition10.1088/1361-6528/ab068e ↗
3. Thin films of Ag-Au nanoparticles dispersed in TiO2: Influence of composition and microstructure on the LSPR and SERS responses10.1088/1361-6463/aabc49 ↗
4. Microstructural evolution of Au/TiO2 nanocomposite films: The influence of Au concentration and thermal annealing10.1016/j.tsf.2015.03.024 ↗
5. Broadband optical absorption caused by the plasmonic response of coalesced Au nanoparticles embedded in a TiO2 matrix10.1021/acs.jpcc.6b03684 ↗
6. Interparticle coupling effect on the surface plasmon resonance of gold nanoparticles: From theory to applications10.1021/cr0680282 ↗
7. Exploitation of localized surface plasmon resonance10.1002/adma.200400271 ↗
8. Advanced optical effective medium modeling for a single layer of polydisperse ellipsoidal nanoparticles embedded in a homogeneous dielectric medium: Surface plasmon resonances10.1103/PhysRevB.86.045415 ↗
9. Dispersion and damping of gold surface plasmon10.1007/s11468-008-9070-2 ↗
10. Theory of surface plasmons and surface-plasmon polaritons10.1088/0034-4885/70/1/R01 ↗
11. Quantum plasmon resonances of individual metallic nanoparticles10.1038/nature10904 ↗
12. Fullerene-like CSx: A first-principles study of synthetic growth10.1016/j.cplett.2011.02.059 ↗
13. Functional behaviour of TiO2 films doped with noble metals10.1179/1743294415Y.0000000085 ↗
14. Functional and optical properties of Au:TiO2 nanocomposite films: The influence of thermal annealing10.1016/j.apsusc.2010.04.043 ↗
15. Electroactive Au@Ag nanoparticles driven electrochemical sensor for endogenous H2S detection10.1016/j.bios.2018.05.047 ↗
16. Synthesis and biosensor application of Ag@Au bimetallic nanoparticles based on localized surface plasmon resonance10.1016/j.apsusc.2014.02.050 ↗
17. Evolution of the surface plasmon resonance of Au:TiO2 nanocomposite thin films with annealing temperature10.1007/s11051-014-2790-7 ↗
18. Localized surface plasmon resonance: Nanostructures, bioassays and biosensing—A review10.1016/j.aca.2011.08.020 ↗
19. Bidimensional ordered plasmonic nanoarrays for nonlinear optics, nanophotonics and biosensing applications10.1016/j.mssp.2018.03.025 ↗
20. Polymer stabilized bimetallic alloy nanoparticles: Synthesis and catalytic application10.1016/j.colcom.2018.04.001 ↗
21. Au@Ag core/shell cuboids and dumbbells: Optical properties and SERS response10.1016/j.jqsrt.2015.07.024 ↗
22. The effect of Au/Ag ratios on surface composition and optical properties of co-sputtered alloy nanoparticles in Au-Ag:SiO2 thin films10.1016/j.jallcom.2009.06.201 ↗
23. rf reactive co-sputtered Au-Ag alloy nanoparticles in SiO2 thin films10.1016/j.apsusc.2007.03.050 ↗
24. Anchoring of Ag-Au alloy nanoparticles on reduced graphene oxide sheets for the reduction of 4-nitrophenol10.1016/j.apsusc.2016.08.034 ↗
25. Synthesis of large uniform gold and core–shell gold–silver nanoparticles: Effect of temperature control10.1134/S0036024416010301 ↗
26. AgAu bimetallic janus nanoparticles and their electrocatalytic activity for oxygen reduction in alkaline media10.1021/la303513x ↗
27. Plasmon absorption in nanospheres: A comparison of sodium, potassium, aluminium, silver and gold10.1016/j.physb.2006.12.011 ↗
28. Nanocomposite thin films based on Au-Ag nanoparticles embedded in a CuO matrix for localized surface plasmon resonance sensing10.1016/j.apsusc.2019.04.085 ↗
29. UV plasmonic device for sensing ethanol and acetone10.7567/APEX.11.012001 ↗
30. Metal-organic framework thin film for enhanced localized surface Plasmon resonance gas sensing10.1021/ac102127p ↗
31. Advances in localized surface plasmon resonance spectroscopy biosensing10.2217/nnm.11.117 ↗
32. Localized surface plasmon resonance as a biosensing platform for developing countries10.3390/bios4020172 ↗
33. Nanoscale optical biosensor: Short range distance dependence of the localized surface plasmon resonance of noble metal nanoparticles10.1021/jp036261n ↗
34. Van gas sensing with high-resolution localized surface plasmon resonance spectroscopy10.1021/ja1074272 ↗
35. Water adsorption by a sensitive calibrated gold plasmonic nanosensor10.1021/acs.langmuir.8b00040 ↗
36. Dispersion and shape engineered plasmonic nanosensors10.1038/ncomms11331 ↗
37. Curvature of the localized surface plasmon resonance peak10.1021/ac500883x ↗
38. Critical issues in localized plasmon sensing10.1021/jp409954s ↗
39. Quantitative interpretation of the response of surface plasmon resonance sensors to adsorbed films10.1021/la971228b ↗
40. Structural and optical properties of Ag-doped copper oxide thin films on polyethylene napthalate substrate prepared by low temperature microwave annealing10.1063/1.4812584 ↗
41. Gas-sensing performance of M-doped CuO-based thin films working at different temperatures upon exposure to propane10.3390/s150820069 ↗
42. Ag:TiN-coated polyurethane for dry biopotential electrodes: From polymer plasma interface activation to the first EEG measurements10.1002/ppap.201500063 ↗
43. Advanced physics and algorithms in the IBA DataFurnace10.1016/j.nimb.2007.10.044 ↗
44. Effects of annealing temperature on the properties of copper films prepared by magnetron sputtering10.1007/s11595-015-1106-9 ↗
45. Reactive magnetron sputtering of copper, silver, and gold10.1016/j.tsf.2004.10.043 ↗
46. Effect of post-annealing on the properties of copper oxide thin films obtained from the oxidation of evaporated metallic copper10.1016/j.apsusc.2007.12.019 ↗
47. Monitoring of the plasmon resonance of gold nanoparticles in Au/TiO2 catalyst under oxidative and reducing atmospheres10.1021/jp101248h ↗